the following specification taken in conjunction with the drawings sets forth the preferred embodiments of the present inventions in such a manner that any person skilled in the art can make and use the inventions . the embodiments of the inventions disclosed herein are the best modes contemplated by the inventor for carrying out the inventions in a commercial environment , although it should be understood that various modifications can be accomplished within the parameters of the present inventions . the apparatus and methods of the present inventions improve the production of ions and give improved control and redundancy in ion delivery systems . one or more aspects of these methods and apparatus may also provide for ion production that can be linear in proportion to flow rate . additionally , micro - miniaturization and micro - fabrication techniques can be used to advantage with these methods and apparatus . the following discussion will focus primarily on electro - spray ion delivery systems for use with mass spectrometers , with particular emphasis on those that can be made using micro - electronic fabrication techniques . it is believed that one or more aspects of the present inventions can be easily implemented in any number of different analyzers while still achieving the results obtained with the configurations of the ion delivery systems described herein . however , it should be understood that this specification focuses on preferred applications of the inventions as they may be implemented as an electro - spray ion delivery system for mass spectrometers . in accordance with one aspect of the inventions , an ion delivery system 30 ( fig1 ) is provided which improves production of ions from bulk liquids and other materials and which provides more flexibility in the control and ongoing supply of liquid for producing ions . the ion delivery systems described herein can be used with any number of devices , but will be described herein in conjunction with an analyzer 32 , which may be a mass spectrometer such as an ion trap , quadrupole mass filter , time - of - flight , magnetic sector and mobility mass spectrometers , or the like . the 10 analyzer may include a trap , filter or other discrimination element 34 for separating the ions of interest from the remaining particles . the ions of interest are then collected , detected or otherwise analyzed in a detector 36 , which sends signals to and is controlled by a controller and power supply assembly 38 , which also may have any number of configurations . the controller and power supply assembly 38 provides through an interface 39 whatever power and control signals are necessary for operating the analyzer 32 , as well as the ion delivery system 30 . the assembly 38 also may receive signals representing the ongoing status of the ion delivery system and the analyzer , and can be configured to respond accordingly . the analyzer is maintained within an enclosure 40 preferably at sub atmosphere pressure by a suitable pump or other vacuum source 42 . typical pressures in the analyzer may be in the range of 10 − 3 to 10 31 9 torr ( one torr equals { fraction ( 1 / 760 )} atmosphere ). the ion delivery system 30 is also preferably housed within its own enclosure 44 , preferably above the pressure of the analyzer 32 , and preferably at ambient pressure , as indicated at 43 . in other configurations , the ion delivery system 30 can be maintained at about 0 . 1 atmospheres to about 1 . 5 atmospheres , while operation could occur outside this range depending on design . typical operation would be at about one atmosphere . the enclosure 44 can be maintained above the pressure of the analyzer 32 because the ion delivery system is preferably holding and operating on liquids instead of gases . consequently , the ion delivery system is easier and less expensive to manufacture and easier to use with the analyzer 32 . the interface between the ion delivery system 30 and the analyzer 32 can take any number of forms , depending on the type of analyzer being used . the ion delivery system 30 preferably includes an electro - spray droplet source 46 and a counter electrode or counter electrode assembly 48 maintained at an electric potential delta v relative to the droplet source 46 . the droplet source 46 can be maintained at ground , but it should be understood that the potential difference between the droplet source and the counter electrode 48 can be maintained in any number of ways . for example , the counter electrode can be grounded , or both the droplet source and counter electrode can be at different potentials other than ground . the voltage difference delta v can be any number of values from a few volts to thousands of volts . in one embodiment , the voltage can be between 700 to 800 volts and possibly as high as 1400 volts , but preferably still avoiding any electric break down between the tips of the ion source and the counter electrode assembly 48 . as will be apparent from some of the dimensions provided herein , the electric field experienced by a droplet produced by the droplet source 46 relative to the counter electrode can be relatively high given the surface areas of the nozzle tips . consequently , significant latitude in selecting the voltage differences is possible . the droplet source 46 is preferably oriented so as to eject droplets in a direction 50 approximately perpendicular to a central axis 52 of the analyzer 32 . the preferred angle can range from about 70 and 115 degrees , for example , while other angles can be used as well . the benefits of a perpendicular orientation are described in u . s . pat . no . 5 , 495 , 108 , the description and drawings of which are incorporated herein by reference . in one preferred embodiment , the droplet source 46 includes a liquid source and a droplet emission system in the form of a reservoir and nozzle array 54 ( fig2 ) for containing liquid and passing the liquid to outlets such as tips for ejecting droplets from the liquid . the array 54 can have one or more reservoirs , such as reservoirs 56 , 58 , 60 , 62 , and 64 for containing or holding liquid analyte to be analyzed by the analyzer 32 . the reservoirs can be any shape , size or configuration but typically may be circular in plan view and have a depth as may be determined by the particular application or the analyte or analyte samples under consideration . additionally , in the case of more than one reservoir , the relative positions of the reservoirs can vary according to their size , shapes and according to the size of the array , and also according to their functions or use . however , it is preferred that the positions and configurations of the reservoirs are such as to optimize the delivery of liquid to the outlets or tips while still maintaining adequate control over the flow of liquid and still allowing access to the reservoirs . the array also preferably includes one or more nozzle elements or assemblies 66 for receiving liquid from one or more of the reservoirs and ejecting the liquid as droplets into an electric field created between the nozzle elements and the counter electrode . each nozzle can receive liquid from one or more of the reservoirs through any number of flow channel configurations , conduits or the like , as may be determined by the layout of the array , the material from which the array is formed or constructed and the dimensions of the flow channels . as with the size and orientations of the reservoirs , the layout , configurations and dimensions of the flow channels may be determined in part by the desire to optimize the control and the ease of flow of liquid from the reservoir to the nozzle or nozzles . in the embodiment shown in ( fig2 ), the flow channels include a first flow channel 68 having a first end 70 coupled to the first reservoir 56 and a second end 72 opening into a manifold 74 for passing liquid from the first reservoir 56 to the nozzles 66 . preferably , the channel is a straight line between the reservoir 56 and the manifold 74 . the second end 72 opens out into the manifold 74 preferably at a location which optimizes the flow of liquid from the reservoir 56 to the desired nozzle or nozzles without being affected by and without affecting other channels . in a preferred embodiment , the manifold 74 is sufficiently small to minimize excess volume or dead volume while still permitting sufficient flow of liquid to the nozzles . the manifold may include a first wall 76 at which the second end 72 of the channel 68 opens out , along with any other channels coming from respective reservoirs . the wall 76 may be flush or co - linear with a forward wall 78 of the array or may be slightly arcuate or partly circular . also in the preferred embodiment , the nozzles 66 are formed on , mounted to or extend from a manifold forward wall 80 . the depth of the manifold may be defined by the spacing between the wall 76 and the manifold forward wall 80 . the length of the manifold is defined by a first manifold side wall 82 and a second manifold side wall 84 , and the width is defined by a top wall and a bottom wall . a second channel 86 includes a first end 88 opening into the reservoir 58 and a second end 90 opening into the manifold for allowing liquid to flow from the reservoir 58 to the manifold . likewise , a third channel 92 may include a first end 94 opening into the reservoir 60 and a second end 96 opening into the manifold . a fourth channel 98 includes a first end 100 and a second end 102 for allowing liquid to flow from the reservoir 62 to the manifold . a fifth channel 104 includes a first end 106 and a second end 108 for allowing liquid to flow from the reservoir 64 to the manifold . one or more contacts , conductors or conductive regions 110 are associated with respective reservoirs so that an electric potential delta v x can be generated between the respective reservoir and the counter electrode so that fluid flows from the reservoir to and out of one or more of the nozzles 66 . each reservoir can then be controlled by appropriate respective voltages v a , v b , v c , v d and v e to induce liquid flow from the selected reservoir through electrophoresis , where the variable “ x ” in v x represents “ a ”, “ b ”, “ c ”, “ d ” or “ e ”, respectively . liquids from the appropriate reservoirs can then be selectively caused to flow down the respective channel , into the manifold 74 to be ejected as droplets from the nozzles 66 and into the region between the nozzles 66 and the counter electrode 48 . the array 46 can be constructed or formed in any number of ways . in one approach , the array can be formed from one or more plates of glass or quartz appropriately bonded together . other non - conductive materials can be used as well . for example , the array can be formed by a first plate substantially square or rectangular along with a projection to form the manifold and nozzles . a second plate having the same outline is formed , cut or etched to include holes to form the reservoirs and a bottom surface is also formed , cut or etched to form respective channels in the bottom surface of the plate . channels or reservoirs can also be formed in other ways as well , to provide the desired configurations . the first plate then becomes the bottom for the reservoirs and a bottom portion of the channels . the second plate is also formed , cut or etched in the bottom surface thereof to form the manifold and to form channels or openings to form the nozzles . alternatively , the array can be formed through microelectronic machining or fabrication such as lithography on non - conductive surfaces . the nozzle 66 ( fig3 ) preferably includes a wall 112 defining a channel 114 extending from the manifold 74 to a nozzle manifold 116 for passing liquid from the manifold 74 to one or more outlets , ports or tips 118 at the far or distal end 120 of the nozzle . the channel 114 can be a single channel or multiple channels extending from the manifold 74 to the manifold 116 for supplying liquid to the tips 118 . the tips 118 can be arranged linearly with respect to each other , as depicted in the sectional view of fig3 they may be arranged spaced apart from each other in all directions from a center 122 ( fig5 ), or they may be arranged to have any number of other configurations . preferably , each tip 118 is spaced apart from each adjacent tip an equal amount so as to minimize the effects produced on a given tip by adjacent tips . other configurations are possible as well for distributing or positioning the tips over the surface of the nozzle , including symmetrical and / or asymmetrical . the dimensions and configurations of the tips are preferably such as to minimize the restriction to flow of liquid to the tip , minimize the size of the droplets ejected from the tips and to minimize the depositing of residue on the surface on the nozzle . the tips can take any number of forms , and may be substantially straight with a constant wall thickness or they may have a varying wall thickness , but they preferably have a volcano shape ( fig4 ) or a converging tip end . each tip preferably includes an outer surface 124 sloping inwardly toward a central axis 126 and outwardly away from the manifold 116 ( fig3 ) generally in the direction of the counter electrode . the outer surface 124 converges to a substantially cylindrical wall 128 , which is substantially circular in cross - section . the cylindrical wall 128 preferably terminates at a flat or squared - offend face 130 and has a thickness “ t ” ( fig4 ) preferably as small as possible to minimize the surface area defined by the end face 130 and to minimize obstructions to uniform flow . the interior wall of the tip 132 preferably has a diameter d of an appropriate size to minimize the size of the droplets ejected from the tip . the diameter d may be constant throughout much of the length of the channel to the tip or may be converging to a similar extent as the outside of the tip , in other words the thickness “ t ” is relatively constant near the face 130 . the diameter of the channel 114 ( fig3 ) may be about 20 micrometers , or other dimensions producing an approximately similar cross sectional area . the height “ h ” of each tip is preferably sufficient to properly form and eject droplets while minimizing spread or flow of liquid across the surface of the nozzle or depositing of liquid on the nozzle . the height may be approximately similar to or greater than the inside diameter of the tip , and is preferably about or greater than one and one - half times the diameter d . the spacing s between each tip is preferably sufficient to allow formation and ejection of droplets from each tip without interference from the formation and ejection of droplets from adjacent tips , and so that each tip has its own electric field point . the spacing s may be about or greater than one and one - half times the diameter d , to take into account the relationship between the dynamics of the formation of the spherical droplet as it leaves the tip , which droplet diameter depends on the diameter d , and the spacings for adjacent droplets if droplets formed simultaneously . in one aspect of the preferred embodiments , the tips are spaced from the counter electrode a distance sufficient to allow ions to be ejected from the droplets or for the droplets to evaporate . the counter electrode is preferably positioned closer to the analyzer than to the tips and is preferably spaced in a direction from the tips that is at least partly in the same direction as the line of flight of the droplets , and preferably at least partly in a direction coaxial with the tips . the spacing between the tips and the counter electrode is preferably about one to five mm , and may be more depending on the mode of operation , the temperature and similar parameters . in operation , liquid analyte is placed in one or more of the reservoirs 56 - 64 and the array 46 placed in the ion generator 30 . voltages are applied to the counter electrode and the array , and to one of the reservoirs , such as reservoir 56 , to cause liquid to flow from the reservoir along the channel 68 to the manifold 74 and to the nozzles 66 . liquid flows through the channel 114 in the appropriate nozzle out to the manifold 116 and to the tips 118 . droplets are formed through each tip and ejected under the influence of the voltage difference v x created between the end face 130 and into the droplets and the relative voltage on the counter electrode . ionized portions of the analyte are then ejected from the droplet and taken into the analyzer . the remainder of the droplet passes the counter electrode and is either deposited or leaves the assembly 30 . exemplary dimensions can be given for the preferred embodiments , but other dimensions can be used for the same or different configurations while still achieving one or more of the benefits of the present inventions . in one example , the inside diameter of the tip is between about 0 . 1 and one micro - meter and the outside diameter is about 2 micro - meters . however , the outside diameter is preferably as close to the inside diameter as possible . the center to center distance between tips can be as small as two micro - meters or less , but is preferably more . for example , the center to center spacing can be twice or three times or more that of the outside diameter of a tip . the channels to each of the manifolds can be about 20 micro - meters in diameter . in a further form of one aspect of the present inventions , a source of ions 134 ( fig6 ) includes a liquid source 136 such as a reservoir and pump for containing a liquid and transporting the liquid to a manifold 138 . the source of ions also includes droplet emission assembly 140 having a plurality of tips 142 , 144 , and 146 for producing droplets 148 and ejecting the droplets into an electric field between the tips and a collector 150 , which generically may be considered the analyzer , well known to those skilled in the art , but where the analyzer is used simply to measure the flow of ions from the tips , it may take the form of an ammeter 151 . the collector may include a power supply , source or generator 152 for producing the electric field between the collector 150 and the tips 142 , 144 and 146 . in the example shown in fig6 the tips are placed at a potential different from the collector 150 through a copper wire 154 or other conductor to complete the circuit . the wire 154 preferably encircles and electrically contacts tips 142 , 144 and 146 , such as by way of respective tubes 156 . in this aspect of the inventions , the tips 142 , 144 and 146 can be formed by a well - known drawing process such as is known to those skilled in the art of manufacturing small tubes . the drawing process is carried out on a plurality of quartz tubes in a bundle to produce a plurality of tubes 156 that are cut at one end 158 and convergent or necked down to the tips 142 , 144 and 146 at the other . the tubes are then made somewhat conductive by application of a conductive coating on the outer surfaces of the tubes , such as through a conductive paint or electro - deposition of a suitable conductive material . the wider - diameter ends 158 are press fit into an elastomeric disk 160 , such as a teflon disk , to form a suitable seal between the disk and the tubes . the teflon disk 160 is then fit into a tube 162 made of plastic or other material to serve as a channel and manifold for liquid before entering the quartz tubes 156 . in this embodiment , the outer diameter of the each of the tips were about two micro - meters and the inside diameter of the tip was about one micro - meter . the inlet diameter of the tube was about 200 micro - meters . the tips were separated from each other by a distance of about 1230 micro - meters , and the distance ratio between tips was between 600 and 1200 ; however , a ratio of separation of about 100 may be preferred between the tips . the particles produced ranged in size from sub - micro - meters in diameter to about two micro - meters . the separation ratio provided a large distance between aerosol particles to reduce their ability to coalesce prior to the ions being collected at the collector . the tube array was separated from the collector by a distance of between three and 9 mm , with a suitable distance being about 8 mm . in this configuration , the tubes and the collector were oriented with respect to each other to be coaxial . a voltage as applied to the tube array of between 1000 and 1400 volts . with this arrangement , ion detection as measured by observed current was found to have a direct correlation to the number of tubes . in a further form of the present inventions , a source of ions may include tubes 163 having tips 164 similar to the tips 142 , 144 and 146 , having opposite ends 166 in fluid communication with a manifold 168 for supplying liquid to the tips 164 . the tubes 163 pass through respective openings in a lower housing 170 and are sealed and held in place by respective o - rings 172 . the ends 166 of the tubes are pressed or otherwise fit into respective openings in a seal plate 174 , which is then preferably pressed or otherwise placed against the o - rings 172 to help seal the tubes and hold them in place . an upper housing 176 seals with and covers the lower housing 170 to form the manifold 168 . a fitting 178 couples with a tube or other liquid supply for supplying liquid analyte to the manifold . the o - rings may also take the form of gaskets , and they are preferably formed from conductive polymers , such as graphite or silver impregnated polymer , such as polyimide . the conductive o - rings or gaskets are preferably about 1 . 2 mm inside diameter . having thus described several exemplary implementations of the invention , it will be apparent that various alterations and modifications can be made without departing from the inventions or the concepts discussed herein . such operations and modifications , though not expressly described above , are nonetheless intended and implied to be within the spirit and scope of the inventions . accordingly , the foregoing description is intended to be illustrative only .