the compositions of the present invention which impart to a given substrate a low coefficient of friction and wear - resistant properties , the compositions comprising a solution of a fluoroalkyl ester in a carrier or solvent therefor . in general , the fluoroalkyl esters may be esters of monocarboxylic acid , viz ., the fluoroalkyl monoesters ; the esters of dicarboxylic acid , viz ., the fluoroalkyl diesters ; esters of tricarboxylic acid , viz ., the fluoroalkyl triesters ; and esters of tetracarboxylic acid , viz ., the fluoroalkyl tetraesters . herein the fluoroalkyl esters are compounds derived from carboxylic acids by replacing the ionizable hydrogen atom by a fluoroalkyl radical . the fluoroalkyl portion of the molecule is the alcohol moiety thereof and has generally from about two to about twenty carbon atoms . the preferred fluoroalkyl monocarboxylic acid esters are fluoroalkyl acetate , fluoroalkyl laurate and fluoroalkyl stearate ; the preferred fluoroalkyl dicarboxylic acid esters are fluoroalkyl malonate and fluoroalkyl azelate ; and the preferred fluoroalkyl tricarboxylic acid ester is fluoroalkyl citrate . these fluoroalkyl esters can be readily prepared by conventional chemical techniques known in the art . in general , the fluoroalkyl monoesters may be produced by condensation of fluoroalcohols with aliphatic monocarboxylic acids . further , fluoroalkyl polyesters may also be readily produced by the reaction of fluoroalcohols with polycarboxylic acids , either of the aliphatic or aromatic type . mixed esters are also readily produced such as those formed from the condensation products of pyromellitic anhydride with a mixture of fluoroalcohols . the esters herein contemplated embrace those esters of terminally fluorinated alcohols in which a bridge containing an alkylene group is interposed between the fully fluorinated portion and the ester linkage . it is understood that the fluorinated alcohol may be a branched as well as a straight chain moiety . in particular , the fluoroalkyl esters used in accordance with this invention may be readily prepared from the perfluoroalkyl aliphatic alcohols ( viz ., 2 - perfluoroalkyl alkanols ) of the formula c n f 2n + 1 ( ch 2 ) m oh where n is from about 3 to 14 and m is 1 to 3 and the corresponding carboxylic acid by art - known procedures . for example , esterification reaction may be readily carried out by using para - toluenesulfonic acid or sulfuric acid as a catalyst with the alcohol and carboxylic acid in benzene and heating these ingredients , removing the water of reaction by codistilling with the benzene and thereafter removing any residual by distillation to isolate the given esters . the perfluoroalkylethanols may be prepared by hydrolysis of fluoroalkyl hydrogen sulfates which in turn are produced from the reactions of perfluoroalkylethyl iodides with oleum , these reactions being described in u . s . pat . no . 3 , 283 , 012 . also , the perfluoroalkylethyl iodides may be prepared by known reactions of perfluoroalkyl iodide with ethylene as described in j . chem . soc . 2856 ( 1949 ) and j . chem . soc . 2789 ( 1950 ) as well as by known telomerization reactions described in u . s . pat . nos . 3 , 132 , 185 and 3 , 234 , 294 . conventional separation technique may be employed to isolate selected fractions as , for example , the corresponding iodides having the perfluoroalkyl moiety in the range of 6 to 14 carbon atoms may be separated by distillation as set forth in u . s . pat . no . 3 , 716 , 401 . the fluoroalkyl esters may generally be mixtures which can , if desired , be further refined by fractional distillation or chromatographic techniques . nonetheless , the esters may cover a somewhat broad range , for example , a common fluoroalkyl ester such as fluoroalkyl malonate may generally be a mixture of esters having an average of about 70 % to 80 % perfluorohexyl to perfluoroheptyl - containing esters , with esters having a perfluorobutyl moiety and lower , less than about 5 % and a perfluorodecyl moiety and higher , making up the balance . the monocarboxylic or polycarboxylic acids herein contemplated that form the acid portion of the ester may contain from about 2 to 30 carbon atoms . examples of such acids include citric acid , azelaic acid , stearic acid , adipic acid , malonic acid and acetic acid . the carriers utilized with the compositions of the present invention are essentially organic and are generally halogenated . the penetrating ability or penetration coefficient of a given carrier is critical for proper and effective distribution of lubricant within the fine grooves and tiny crevices of a phonograph record , media , substrate or the like having dynamic presentations thereon . for example , record grooves are generally closely spaced , v - shaped crevices having an opening of about 0 . 003 inch ( 7 . 6 microns ) with a bottom radius of often equal to or less than 0 . 002 inch ( 5 . 1 microns ). in order to get within the grooves of the sound track the carrier itself must exhibit a high penetration ability , a property apparently depending on a number of factors including surface tension , viscosity , volatility , etc . seemingly , carriers found most effective for this purpose are those that have surface tensions of less than about 20 dynes per centimeter ( 20 ° c .). while certain carriers are useful , provided there is no adverse effect upon the substrate , trichlorotrifluoroethane is particularly desirable carrier as having a high penetration coefficient , suitable organic dissolution powers , high volatility , and essentially no physical or chemical effect on the substrate . the trichlorotrifluoroethane can be either isomer , i . e ., it may be 1 , 1 , 1 - trichloro - 2 , 2 , 2 - trifluoroethane or 1 , 1 , 2 - trichloro - 1 , 2 , 2 - trifluoroethane . certain other organic carriers or cocarriers may also be incorporated with the preferred carrier of trichlorotrifluoroethane to the extent that the combination has no more adverse effect on the aforementioned properties as well as the substrate than does trichlorotrifluoroethane alone . suitable cocarriers that may be incorporated with the trichlorotrifluoroethane include , for example , 1 , 1 , 1 - trichloroethane , benzotrifluoride , perfluorodimethylcyclobutane , acetone , hexane , chloroform , tetrachloroethylene , trichloroethylene , methyl ethyl ketone , methylene chloride , carbon tetrachloride , trichloroethylene , dichloroethylene , dichloroethane , and mixtures thereof . the esters herein contemplated are those that are soluble in the aforementioned organic carriers and for the most part do not exist in the compositions hereindescribed as particles or as colloidal suspensions . in effect , the compositions of the present invention are generally essentially clear , homogeneous solutions , that is , each exhibits a uniform composition throughout its entire volume without any turbidity . a preferred composition of the present invention is one comprising fluoroalkyl stearate wherein the fluoroalcohol portion of the ester has from four to seventeen carbon atoms . the preferred carrier is trichlorotrifluoroethane . lubrication of substrates herein contemplated can be accomplished by applying the herein - described composition wherein the fluoroalkyl esters are generally present in an amount less than three weight percent to a given substrate , evaporating the solvent therefrom , and lightly buffing , if desired , the thus - coated substrate to provide a clear dry coating . application of the composition can be accomplished by numerous means including spraying , dipping , brushing , swabbing , flowing and doctoring . for most purposes , spraying and swabbing are preferred because of the complete and uniform coverage these methods afford . there may be added to the compositions of the present invention minor amounts of various conventional components including antistatic agents , antioxidants , fungicides , germicides , pigments , hardeners , fillers , binders , odorants , dyes and the like if there is need to do so and to the extent that such ingredients are soluble or dispersible in the carrier and do no degrade the performance characteristic of the present invention . the fluoroalkyl esters herein contemplated and disclosed may be employed in amounts ranging from about 3 . 0 to about 0 . 001 weight percent based on the total weight of the mixture , prefereably from about 0 . 2 to about 0 . 01 weight percent and especially from about 0 . 1 to about 0 . 03 weight percent . the resulting treated article which also forms a part of this invention is made by applying the compositions to the surface and removing the carrier therefrom whereby there is deposited thereon a coating of said fluoroalkyl ester ranging from about 0 . 3 to 3 micrograms per square centimeter . treatment of the various substrates herein contemplated can be accomplished by applying the above - described compositions in a concentration generally less about three weight percent , evaporating the carrier therefrom to provide a coating or film thereon which comprises essentially the non - volatile fluoroalkyl ester . in practice a concentration of between about 0 . 1 and 0 . 03 weight percent has been found to be satisfactory for treating phonograph records . further , it has been found advantageous to buff or polish after treatment to impart a good luster to the playing surface thereof . there will be illustrated herein preferred examples of the lubricating compositions of this invention and method of using the same . the specific illustrations , however , are not intended to be a limitation upon the breadth of the invention . generally , the invention taught herein is one in which a volatile but effective carrier transports therein an essentially non - volatile material , viz ., a fluoroalkyl ester , the latter forming a film upon a given substrate after the carrier has volatilized . a solution was prepared comprising 99 . 96 percent by weight of trichlorotrifluoroethane ( freon tf ) and 0 . 04 percent by weight of perfluoroalkyl citrate ( this triester is available under the trademark zonyl tbc from e . i . du pont de nemours & amp ; co ., wilmington , de . ), the average perfluoroalkyl moiety thereof ranging from heptyl to octyl . a clear homogeneous solution resulted and was sprayed onto a clean phonograph test record , national association of broadcasters ( nab ) test record no . 12 - 5 - 98 , the trichlorotrifluoroethane was allowed to evaporate , and the playing surface was lightly buffed to leave a thin coating of said ester thereon . a stylus / groove coefficient of friction test was conducted on the phonograph record before and after the treatment described by measuring the change in the deceleration rate of the freely rotating phonograph record on a turntable , the deceleration change being caused by the engagement of the tone arm stylus with the record groove . this change in deceleration is converted to stylus / groove coefficient of friction by the following formula : ## equ1 ## f = coefficient of friction . i t = moment of inertia of total rotating system . a t = angular deceleration for the total effects of stylus and turntable bearings . a b = angular deceleration for the effect of the turntable bearings alone . using the above formula the coefficient of friction before coating with the aforementioned citrate composition was 0 . 35 and after application of said composition the coefficient of friction was reduced to 0 . 18 . another composition was prepared as above with the exception that 0 . 04 weight percent fluoroalkyl stearate was used in place of the aforementioned citrate , this monoester being available from e . i . du pont de nemours & amp ; co ., wilmington , de . the average perfluoroalkyl moiety of said monester ranged from heptyl to octyl . the coefficient of friction of the untreated record was 0 . 33 where the treated record with the fluoroalkyl stearate gave a coefficient of friction of 0 . 11 . accelerated phonograph record wear tests were conducted on nab test records which had been treated with the compositions hereinafter disclosed . the results achieved from cleaned and treated records were compared with the results of the wear test conducted on a cleaned test record which had not been treated in accordance with the present invention . a graduated scale was established ranging from a rating of zero for a clean , mint condition appearance to a rating of 100 for a surface heavily covered with wear debris . the test utilized a standard type automatic record turntable rotating at 331 / 3 rpm with the stylus on the tone arm adjusted to 9 . 5 grams load on the record surface . this high stylus load was used in order to accelerate the wear process and thereby provide better discrimination among record treatments . various compositions of the present invention were applied to the record surfaces in accordance with the procedure described in example i . test results after 125 to 127 playing cycles are presented in the tabulation below : ______________________________________phono - graph record surfacetest appearance atrecord composition of record treating test termina - identifi - solution : trichlorotrifluoro - tion and relativecation ethane plus the following ( wt .%) rating______________________________________a 0 . 04 wt . % fluoroalkyl citrate relatively ( average perfluoroalkyl portion clean surface 7 to 8 carbon atoms ) scattered fine wear particles : rating = 15b 0 . 04 wt . % fluoroalkyl stearate quite clean : ( average perfluoroalkyl portion scattered very 7 to 8 carbon atoms ) fine particles : rating = 7c control record heavily covered ( record cleaned via mild with various sizes detergent ) particles of wear debris : rating = 100______________________________________ examples i and ii show that compositions of the subject invention effectively prevent phonograph record groove wear as well as reduce the stylus groove friction . the compositions have been found to significantly retard wear over a large number of actual playings . a solution was prepared comprising 99 . 96 % by weight of trichlorotrifluoroethane ( freon tf ) and 0 . 04 % by weight of perfluoroalkyl malonate , the perfluoroalkyl moiety average thereof ranging from heptyl to octyl . a clear , homogeneous solution resulted and was sprayed onto a clean phonograph test record , national association of broadcasters ( nab ) test record no . 12 - 5 - 98 , the trichlorotrifluoroethane was allowed to evaporate and the playing surface of the record was lightly buffed to leave a thin coating of diester thereon . the stylus / groove coefficient of friction test was conducted in accordance with example i . the stylus / groove coefficient of friction determined on the treated record was 0 . 18 . in comparison , the coefficient of friction as determined on untreated nab records averaged about 0 . 32 . the accelerated record wear test was also conducted on the treated record in accordance with example ii and resulted in the record having a very clean surface appearance indicating very little record wear and gave a relative rating of 1 . 0 . there has been disclosed herein a method of and a composition for lubricating surfaces , and in particular those surfaces which are capable of having or have dynamic presentations thereon . in view of this specification , those skilled in the art will have many modifications which fall within the true spirit and scope of this invention . it is intended that all such modifications be within the scope of the appended claims .