a silicone - based scintillator composition for the detection of radiation according to the present invention comprises a carborane containing rubber having a heat resistance to 200 ° c . and robust in a high radiation field . the rubber can be in any suitable shape the rubber is constructed from a carborane bound organosilicone rubber which contains a large number of phenyl groups . the scintillator composition also includes an organic phosphor for absorbing energy from the phenyl groups of the silicone rubber after neutron absorption to produce photons of light which can be detected by a photosensor . there are ten boron atoms per carborane unit to effectively interact with neutrons or other radiation . in general , the effectiveness of the scintillator composition increases with an increase in the boron content and an increase of the phenyl content of the composition . the organic phosphor is generally compatible with the phenylsilicone . preferred phosphor are 2 , 5 - diphenyloxazole ( ppo ) which emits at 360 - 380 nm , 1 , 3 , 5 - triphenyl - 2 - pyrazoline ( tpp ) which emits at 410 nm , and 1 , 4 - bis ( 4 - methyl - 5 - phenyloxazol - 2 - yl ) benzene dimethyl ( popop ) which emits at 427 nm . the structure of these phosphors are given below as structures ( 1 ) through ( 3 ). the phosphor can be used in combination where one is the primary phosphor , for example ppo , to accept energy from the phenyl groups of the silicone and a secondary scintillator , for example dimethyl popop , to shift the wavelength of the photons from that of the primary phosphor to photons which more closely match that detected by the photo multiplier tube or other detector and move the wavelength away from the smaller wavelengths where absorption by the phenyl groups occur . the carborane unit can be incorporated in the silicone in at least two manners . one is by the inclusion of carborane molecules into phenylsilicone network precursor by the use of a compatibilizing agent . this is illustrated in a non - limiting embodiment , example 1 , below . the other method is by incorporation of carborane units into the silicone rubber where the carborane unit is covalently bound within the silicone polymer . one method of incorporating carborane units into a siloxane polymer is disclosed in keller et al . u . s . pat . no . 5 , 969 , 072 , which is incorporated by reference . this method is illustrated in a non - limiting embodiment , example 2 , below . other methods of preparing a carborane containing silicone monomer which can be incorporated as a repeating unit into a silicone can be used to produce the composition of the invention . though more limited with respect to the maximum loading of boron that can be achieved compared to the bonding a carborane group in a silicone rubber precursor , the inclusion of carborane with a compatabilization agent can overcome solubility problems of carboranes in siloxanes . compatabilization agent are co - solvents for the silicones and carboranes that enhance the mixing but also have sufficient thermal and radiation stability to be included in the scintillator . an efficient compatabilization agent is tributylphosphate which is stable to 200 ° c . in the silicone rubber domain . an alternate method to achieve a carborane bound phenylsilicone rubber according to the invention begins by the formation of a lithiocarborane by the reaction of carborane with butyllithium . the resulting dilithiocarborane is mixed with about two equivalents of methylphenyldichlorosilane to yield 1 , 7 - bis -( methylphenylchlorosilyl ) carborane . this monomer can then be polymerized by the addition of water to form silanol terminated polymers with a relatively low degree of polymerization . the silanol terminated polymer can then be capped by the addition of an appropriate capping agent to yield hydro or vinyl terminated polymers as shown in equation 1 . upon mixing of one or both of the hydro or vinyl terminated polymers with a required amount of a tri or poly hydro and / or vinyl containing silane or siloxane , such as methylhydrosiloxane - phenylmethylsiloxane copolymer - hydride terminated , at approximately a 1 : 1 vinyl to hydride ratio , or any other ratio where gelation can occur , a cured rubber can be achieved with a boron level of up to about 37 % by weight . other methods of preparing the carborane containing polymers and curing the rubbers can be carried out . these methods can exploit well known methods of preparing precursors containing chloro , alkylcarboxy , alkoxy , amino , or amido functionality on silicon and their subsequent condensation with water or silanol groups to achieve the desired carborane containing phenylsilicone rubbers . although , some details of the detailed microstructure of the rubber will differ from the embodiments demonstrated in examples , the necessary features of the rubber of the carborane to capture the neutrons and the phenyl groups to harvest the kinetic energy , which can then be transferred to the organic wave shifters , the scintillators , to give a light output at a higher wavelength . the effectiveness of a scintillator of the present invention is illustrated by the neutron signature given by a pulse height analysis . fig1 shows the effect of a second phosphor to the silicone . the boron capture reaction results in the emission of an alpha particle and li - 7 ion sharing 2 . 31 or 2 . 78 mev of energy as li nucleus may be created in its ground state or its first excited state . for neutron energies up to approximately 100 kev , the two reactions occur in the ratio of 15 : 1 , with the 2 . 31 mev reaction being the dominant one . since both ions stop in the scintillator , this entire energy is available to generate light . fig1 show pulse height spectra obtained with silicone samples mounted on photomultipier tubes . the scintillator was exposed to the gamma rays from am - 241 ( 59 . 5 kev ) and to thermal neutrons . gamma rays interact primarily via the photoelectric effect ( ejecting electrons with energy essentially that of the gamma ray ) and by the compton effect ( ejecting electrons having a continuum of energies rather than a single energy ). the spectra each show a structure characteristic of the 59 . 5 kev am - 241 gamma , and this structure is identified . the spectra also show a peak at approximately twice the pulse height ( i . e . approximately 110 kev ), demonstrating that it is caused by neutrons . the thickness of the samples was too small for true 110 kev gamma rays to produce a peak . fig1 also show the effects of adding a small amount (& lt ; 0 . 1 %) dimethyl popop to the silicone . the position of each peak is indicative of the amount of light reaching the photomultiplier . in the figure on the left the neutron peak is near channel 80 . this is a consequence of the scintillator ppo producing light in a band centered near 375 nm , a wavelength that is not near those wavelengths most efficiently converted by the photomultiplier and which are slightly absorbed by silicone . dimethylpopop absorbs light with wavelengths between 360 and 380 nm and re - emits it in a band centered at 415 nm . the intimate mixture of ppo and dimethylpopop in the silicone permits efficient conversion from 375 nm to 415 mm , with an increase in the amount of light reaching the photomultiplier and efficiency of the conversion from light to electrical signal . the right - hand figure shows that the overall process is about 40 % more efficient with the addition of dimethylpopop . fig2 shows spectra obtained by mounting a silicone disk , 2 . 5 cm in diameter and 3 mm thick , containing 18 % natural boron by weight on a photomultiplier tube . the photomultiplier converts light quanta to electrical current . the photomultiplier was connected to an amplifier that converted the current pulses corresponding to scintillation events to voltages whose amplitudes were proportional to the number light quanta emitted by the scintillator in response to ionization events in the scintillator . the voltage was converted to a digital value by an analog - to - digital converter ( adc ) interfaced to a computer . the computer &# 39 ; s software accumulated a histogram of the number of times each adc value was observed and produced the graph shown in fig2 . the x - axis represents the amplitude of the light pulses , the y - axis represents the number of pulses at each x - value . the two spectra are overlayed in fig2 for comparison . in the one marked “ cadmium cup ” the scintillator / photomultiplier was inserted into a thin metallic cadmium cup and the entire assembly was inserted into the moderator of an amli neutron source . cadmium is an efficient absorber of thermal neutrons and prevents them from reaching the scintillator to interact with the boron . consequently , only fast neutrons and those thermal neutrons that manage to avoid the cadmium ( the cup is open at the back to accommodate the scintillator and photomultiplier ) are able to reach the scintillator . the unmarked spectrum with the prominent peak was obtained from the same sample , using the same electronics as the “ cadmium cup ” spectrum , with the only difference being the removal of the cup . since there was no neutron shield , the flux of thermal neutrons was able to reach the scintillator and produce the peak . this figure demonstrates that the scintillator is sensitive to neutrons . it should be understood that the examples described below are provided for illustrative purposes only and do not in any way define the scope of the invention . tributylphosphate was dried over magnesium sulfate and 1 . 1 g was used to dissolve 0 . 5 g of m - carborane to give a clear solution that contained 23 . 4 % boron by weight . a 970 mg portion of the solution was added to a mixture of 75 mg of 2 , 5 - diphenyloxazole ( ppo ), 5 mg of 1 , 3 , 5 - triphenyl - 2 - pyrazoline ( tpp ), 4 . 6 g of 92 % vinyl terminated ( 75 - 78 %) dimethyl ( 22 - 25 %) diphenylsiloxane copolymer and 0 . 4 g of hydride terminated ( 45 - 50 %) methylhydro ( 55 - 55 %) phenylmethylsiloxane copolymer . upon addition of 2 microliters of a platinum divinylsiloxane catalyst the mixture slowly cured into a rubber with 5 . 4 % boron by weight . a 2 . 1 g portion of 1 , 7 - bis -( 3 - chloro - 1 , 1 , 3 , 3 - tetramethyldisiloxan - yl ) carborane , dexsil 400 monomer , was diluted to give a 10 ml solution in dry tetrahydrofurane and cooled in an ice bath . to this stirred mixture was added dropwise 9 . 0 ml of a 1 . 0 m vinylmagnesium bromide solution in tetrahydrofuran . after warming to room temperature stirring was stopped after 2 hours . upon standing overnight a crystalline precipitate formed . diethyl ether was added to the suspension and the suspension washed with saturated ammonium chloride solution ad subsequently dried with sodium sulfate . the mixture was then filtered through a silica column . the product was washed from the column with hexane to give a colorless oil which upon evaporation of the solvent yielded 1 . 65 g of the desired 1 , 7 - bis -( 3 - vinyl - 1 , 1 , 3 , 3 - tetramethyldisiloxan - yl ) carborane whose structure was verified by an ir spectrum . a 2 . 0 g portion of 1 , 7 - bis -( 3 - chloro - 1 , 1 , 3 , 3 - tetramethyldisiloxan - yl ) carborane , dexsil 400 monomer , was placed in one side of a fritted glass filter in a two - compartment flask . to the other side of the flask was added 263 mg of lithium borohydride . to the side of the flask with the dexsil monomer was added 10 ml of diethylether and to the side containing the lithium borohydride was added 10 ml of diethylether and 5 ml of dry tetrahydrofuran . the contents of the flask were frozen using a liquid nitrogen bath and the flask was evacuated . upon warming to room temperature the lithium borohydride solution was filtered into the carborane solution . the mixture was stirred for one hour producing a precipitate . the solution was then filtered to the compartment that originally contained the lithium borohydride to dissolve any remaining lithium borohydride . the mixture was again filtered to the other compartment and the volume of the solution was reduced to approximately two thirds of the original volume to remove any b 2 h 6 . water was carefully added to destroy any remaining boron hydride compounds and the resulting solution was filtered over bentonite which was washed with hexane . the solvents were removed at reduced pressure to produce 1 . 43 g of 1 , 7 - bis -( 3 - hydro - 1 , 1 , 3 , 3 - tetramethyldisiloxan - yl ) carborane whose structure was verified by an ir spectrum . the two carborane monomers 1 , 7 - bis -( 3 - hydro - 1 , 1 , 3 , 3 - tetramethyldisiloxan - yl ) carborane and 1 , 7 - bis -( 3 - vinyl - 1 , 1 , 3 , 3 - tetramethyldisiloxan - yl ) carborane were then combined with various quantities of commercially available methylhydrosiloxane - phenylmethylsiloxane copolymer - hydride terminated and dimethylsiloxane - diphenylsiloxane copolymer - divinyl terminated to yield siloxane mixtures with boron contents of 5 to 18 % by weight . typically , ppo ( 1 . 5 % by weight ) and tpp ( 0 . 1 % by weight ) were added to form a pre - cured scintillator . as needed the mixture could be warmed to 60 ° c . to facilitate dissolution of the ppo and tpp in the mixture . upon addition of platinum divinylsiloxane catalyst at room temperature the mixture solidified into a rubber . while the preferred embodiments of the invention have been illustrated and described , it will be clear that the invention is not so limited . numerous modifications , changes , variations , substitutions and equivalents will occur to those skilled in the art without departing from the spirit and scope of the present invention as described in the claims .