the letters , abbreviation or terms used to express bleaching and / or other embodiments are described as follows : as / aq — alkaline sulfite - anthraquinone ; as / aq wheat straw pulp used for this invention was prepared under conditions described in table i : table i as / aq pulping conditions chemical doses on oven dried pulp pressure temp . time 14 . 0 % sodium sulphite 145 - 160 psi 180 - 185 ° c . 45 min . 0 . 05 % anthraquinone 0 . 025 % surfactant consistency — concentration of pulp suspensions in water calculated as : [ percent consistency ={( weight of oven - dried pulp specimen / net weight of original pulp specimen )× 100 }] ced viscosity — viscosity of 0 . 5 % cellulose solution , using 0 . 5 m cupriethylenediamine as a solvent kappa number — determination of the relative hardness , bleachability , or degree of delignification of the pulp whiteness — extent to which paper reflects light of all wavelengths throughout the visible spectrum opacity — property of the paper which governs the extent to which one sheet of paper visually obscures printed matter on the underlying sheet of similar paper bulk — flexibility of printing paper and is the physical thickness of the piece of a paper in relation to its weight tear index — tearing resistance of a paper sheet divided by its grammage tensile index — rupturing of test paper piece stretched at constant rate of elongation with respect to its grammage burst index — maximum hydrostatic pressure required to produce rupture in a test specimen with respect to its grammage porosity — measure of total circulating air voids in a sheet structure . it is highly important in determining the printability on a paper sheet . standard methods used throughout the process are cited in table ii . this invention provides bleaching sequences comprised of environmentally benign total chlorine free oxidative and / or reductive reagents . as / aq wheat straw pulp cooked at the conditions described in the table 1 showed the values iso brightness : 43 . 9 %, kappa number : 12 . 4 , ced viscosity : 13 . 1 cp , acid insoluble lignin : 7 . 6 %, α - cellulose : 76 . 6 % and burst index : 2 . 8 kpa · m 2 g − 1 . shives are fibrous bundles in straw pulp , which are responsible for reducing the strength and runnability of unbleached pulp and appear as dust particles in bleached paper . to prepare the unbleached as / aq pulp , it was screened through 0 . 15 mm slot screen reduce the shive contents as much as possible . dewatering the pulp to medium consistency and then acidification thereafter followed the de - shiving . acidification of the wheat straw pulp comprised the doses of 0 . 5 % to 2 . 0 % of 4 . 0 n sulfuric acid on oven dried pulp basis , preferably 2 . 0 % on oven dried pulp ; consistency may range from 10 . 0 to 30 . 0 % ( 15 . 0 % optimized due to increased in % iso brightness ) while the treatment was selected to be carried out at ambient temperature for 10 - 15 minutes . the effects of temperature rage 25 ° c . to 75 ° c . and time 10 to 30 minutes were investigated on straw pulp . any increase in ambient temperature and delay in treatment time period decreased the pulp brightness , which is set forth as primary target to decide on the preferred condition for the entire processes involved in bleaching sequences ( table ii ). acid solubilized the sequestered metals of wheat straw pulp helped reduce the kappa number and lignin . along with this , the pulp brightness also increased during acid treatment . the presence of metal ions catalyses the cellulose degradation and discolors the pulp . fig2 describes that the mild pre - treatment of wheat straw pulp with sulfuric acid resulting in more selectivity towards delignification when oxygen treated , by retarding cellulose degradation as compared to conventional edta chelation ( q ). metal removal also preserves the pulp strength properties during oxygen delignification . acid is a preferred pre - treatment method for this invention over edta because of its ability of removing 90 % iron from as / aq wheat straw pulp as compared to chelating agent that removes only 25 % iron . both the a and q treated as / aq wheat straw pulps were washed with distilled water to neutral ph to avoid any further addition of metal ions from fresh / washed water . the water - washed pulp was pressed to medium consistency preferably & gt ; 10 . 0 %. in this treatment , the pulp is directed to a revolving digester for oxygen delignification , where the process is carried out at 10 . 0 % consistency and comprised of the addition and homogenous distribution of aqueous solution of mgco 3 to pulp fiber followed by the addition and homogenous mixing of aqueous solution of naoh . oxygen was then fed after about 5 to 10 minutes at 70 to 75 psi gauge pressure and the process was then continued for 60 minutes in continuous circulating closed loop digester ( table iv ). fig3 describes the addition of mgco 3 solution to as / aq pulp fiber before naoh solution addition and it was found more effective for delignification during o - treatment and protection of other pulp properties such as viscosity , strength etc . the selection of either mgco 3 or mgso 4 for delignification process does not necessarily affect the pulp properties as that the brightness is increased by only 1 unit % iso when mgco 3 is preferred for the process . by following the presented method up to this stage in this invention , kappa number of the pulp was reduced to approximately 38 % with reference to a - treated pulp (˜ 46 % overall reduction in kappa number ) with essentially no damage to cellulose component of pulp which is also evident from the ced viscosity results ( table ix ). the delignified pulp is washed to remove the solubilized lignin contents due to oxygen treatment and pressed to consistency & gt ; 10 %. this step of invention comprises of extended delignification and bleaching of ao treated as / aq pulp with commercially available product : oxone ( ps ) in which peroxymonosulphate is an active agent for the reaction . oxone treatment comprises of the addition of 0 . 5 - 10 . 0 % alkali and 3 . 0 - 7 . 0 % oxone charge . increasing the alkali dose from 0 . 5 - 1 . 0 - 1 . 5 % dose slightly effects the brightness from 64 . 5 % to 64 . 8 % to 65 . 1 % iso respectively . further alkali addition reduces the brightness percent iso . no significant brightness jump is observed beyond this alkali consumption ; thus the dose preferred for this stage is 0 . 5 %. absence of alkali in ps - stage shows & gt ; 7 . 0 units decreased brightness level ( 57 . 2 % iso ) as compared to ps - stage with 0 . 5 % alkali . oxone charge for the ps - treatment may range from 3 . 0 to 10 . 0 % on oven dried pulp ; but increasing the charge in the presence of 0 . 5 % alkali from 3 . 0 to 5 . 0 % aqueous oxone solution on oven dried pulp increases the brightness by two units while further increase from 5 . 0 %- 10 . 0 % oxone charge on oven dried pulp increases the brightness by only about & lt ; 0 . 4 units of iso brightness . ali et al . patent ( u . s . pat . no . 5 , 656 , 130 ) describes the use of peroxyacid salts at temperature (˜ 20 ° c . to 50 ° c .) to pulp bleaching mill after conventional bleaching stages to further increase the brightness without substantial loss in pulp fiber strength . while practicing the present invention an elevated temperature of 65 ° c . is preferred to increase the selectivity of oxone towards lignin removal . the ps - treatment can be carried out at fairly flexible temp . ( ambient - 95 ° c . ), time ( 30 - 180 min .) and consistency ( 5 %- 35 %) ranges . preferred ps - treatment conditions are mention herein as table v : a further 23 . 3 % decrease in acid insoluble lignin contents was found with ced viscosity 12 . 90 cp ( further loss of 0 . 76 %) without α - cellulose degradation and brightness level of 64 . 5 % iso . ps - treated pulp was again washed and pressed by conventional method to increase the consistency & gt ; 10 . 0 %. ps - treated pulp aops - staged pulp was then bleached further by following the sequence routes mentioned herewith : yp 0 - treatment comprises of two stages each followed by washing to remove soluble products and extractives formed during bleaching . sodium dithionite ( y ) is used as reductive reaction step in one of the bleaching sequences aopsyp 0 of this invention . the sensitive embodiments of this step are the temperature and time . temperature range ( 60 ° c .- 70 ° c .) is the more crucial towards brightness increase . lower temperature range practically leave no impact on pulp optical properties ; while 70 ° c .- 80 ° c . does not results in considerable brightness increase ( fig4 ). increasing the temperature beyond 80 ° c . starts degrading dithionite which does not show any practical advantage in terms of brightness rather yellowing of paper starts . likewise , the increased time of pulp exposure to dithionite also leads to its coloration ( fig4 ). preferred reaction time for this stage is opted to be 30 minutes after which the pulp is immediately washed to avoid any loss in stability of dithionite and pulp coloration . y - stage increases the brightness by only 2 . 3 units with reference to the aops stage - treated pulp ( 66 . 8 % iso ); but fig5 describes this y - treatment prior to peroxide reduces the consumption of costly hydrogen peroxide for pulp bleaching as well as increases the pulp final brightness . air contact may lead to the poor dithionite performance ; even then the conventional bleaching equipment performs well by the use of low consistency pulp as low consistency itself minimizes the air mixing with pulp . the p 0 - stage ( table vii ) herein comprises of the addition aqueous solution of alkali and stabilizer u followed by hydrogen peroxide addition . stabilizer u is a silicate free commercial product ( peroxide stabilizer : universal chemical industries , karachi , pakistan ), having its application in textiles to bleach fabrics with peroxide . its use in this invention is to scavenge active oxygen of hydrogen peroxide and to make it available for pulp only ; thus lowering the consumption of hydrogen peroxide during bleaching ( fig6 ). while optimizing alkali dose in the p - stage in the presence of stabilizer u and peroxide , brightness values preferred the selection of 1 . 5 % alkali for this p 0 - stage . any further increase beyond this dose does not significantly increase pulp brightness . conventionally used temperature ( 90 ° c .) and time ( 1 . 0 hr .) are effective and used for this stage bleaching . ep 0 - treatment also comprises of two stages : alkaline extraction ( e ) and oxidative / hydrogen peroxide ( p 0 ) stage , each followed by washing . like y - stage in yp 0 - treatment incorporation of e - stage in replacement to y - stage is another option to improve the final stage brightness of aops treated pulp and to reduce the load of hydrogen peroxide consumption on pulp . e - stage utilizes conventional conditions of extraction only ( table viii ). alkaline extracted washed pulp follows hydrogen peroxide bleaching at conditions described in table vii and then washing where [ aopsep 0 ] shows the targeted brightness of 80 +( 82 . 5 % iso ). p 0 p 1 - treatment is a two - stage hydrogen peroxide treatment each stage followed by washing . single stage hydrogen peroxide treatment is not found to be effective to achieve 80 +% iso brightness . multiple peroxide stages not only reduce the consumption load of chemical but also help to increase the brightness . conditions for peroxide stages are the same as mentioned in table vii with only difference that p 1 - stage uses only 2 . 0 % hydrogen peroxide as compared to p 0 which uses 3 . 0 % hydrogen peroxide on oven dried pulp basis . table ix shows the selectivity of the sequences throughout the bleaching stages of aopsyp 0 , aopsep 0 and aopsp 0 p 1 sequences as protectors to the celluloses in as / aq wheat straw pulp where acid soluble lignin gradually washes away to negligible level which is also supported by the kappa number values of each sequence ; and the α - cellulose (%) contents surprisingly enhanced to some extent as compared to the conventional approaches where bleaching process degrades the cellulose contents . other physical data of as / aq wheat straw bleached pulp samples are also described ( table x ). all the physical properties of bleached as / aq wheat straw pulp results in values that are highly demanding to make business / office paper . every stage in each sequence comprises of totally chlorine free chemicals . mild bleaching conditions are preferred through out of the processes . bod of each final sequence is negligible . cod also shows considerable reduction as compared to hypo bleach pulp . adsorbable organically bound halogens ( aox ) which are the most crucial for any pulp and paper mill are kept at zero by using non - halogenated agents for bleaching throughout the processes of this invention as compared to hypo - bleaching ( h ) which imports huge carcinogenic load into pulp and paper mill effluents in the form of aox . thus all the three sequences of this invention for bleaching process are environmentally benign ( fig7 ) and will also help to reduce the cost on effluent treatment plant processes .