as a typical composition in accordance with the present invention , the waxy substance in the aqueous emulsion thereof may constitute approximately 50 % of the emulsion , and the amount of emulsion employed calculated to be about 0 . 5 %- 20 % of waxy substance , for example wax , to the total amount of water in the water , cement and aggregate mixture . in the following example , except for the control which did not contain any aqueous emulsion of a waxy substance , the aqueous emulsion of waxy substance was microlube ® c marketed by hercules incorporated , which contained 48 % microcrystalline wax . samples of composition in accordance with the process of the present invention and of a control , were prepared by weighing and storing separately under sealed conditions , portions of 375 grams of cement , and 675 grams of sand which had been oven dried to remove moisture . the amount of water needed to obtain a flowable composition , i . e ., a composition which is workable for molding , troweling or paving purposes was determined by placing a 375 gram portion of cement and a 675 gram portion of dried sand in a mixing bowl , and adding thereto and mixing water until a dry mixture having the consistency of mortar was obtained . the amount of water required was 180 grams . mixing of the mixture was continued for approximately 3 - 4 minutes until the mixture was uniform in consistency . samples containing 5 %, 10 %, 15 % and 20 % wax as described above of the total amount of water in the composition , via the aqueous wax emulsion , were prepared by substituting an appropriate amount of emulsion , i . e ., the amount of water in the emulsion , for the equivalent amount of the 180 grams of the water in the mixture to maintain the same water to cement ratio in the mixture . thus , the following samples , including the control noted above , using the above noted amounts of cement and sand , with all ingredients stated in grams , were prepared using the above procedure : * as described above . the amount of emulsion was calculated by determining the amount of wax to water required , e . g ., 5 % of 180 g = 9 g wax , times the amount of solids in the emulsion , e . g ., 48 %, to calculate amount of emulsion , e . q ., 18 . 75 grams , and the amount of water to be deducted from 180 grams , i . e ., 9 . 75 g ( 18 . 75 g ) in sample s - 5 . the samples noted above were placed into polypropylene tubes , and rodded and tamped successively 20 times , filled over the top of the tubes and again rodded to form a compact sample . excess material was removed from the top of the tubes with a screed . the addition of the emulsion , in all of the composition samples containing the aqueous emulsion of a waxy substance , caused the composition of emulsion , water , cement and sand to be substantially “ looser ”, i . e ., more flowable than usually desired , compared to the controls without emulsion . the looser ( increased slump ) condition of the emulsion containing mixtures indicated that the amount of water required is less than the amount expected from the calculated substitution of the water in the emulsion for an equivalent amount of the water required for the non - emulsion containing controls to achieve the same slump . improvement in the resistance to water penetration of the product of the tamped and rodded samples of the compositions in example 1 was first determined by observing the rising of wax from the emulsion to the surface of the samples s5 - s20 . next , after the samples were allowed to cure for 8 days . upon stripping of the emulsion - containing samples from the polypropylene tubes , it was noted that no loss of adhesion was apparent , indicating that the presence of the emulsion had no adverse effect on the adhesive properties of the product . a preliminary water penetration test was performed by placing a drop of water on top of each of the control samples , which was immediately absorbed , whereas a drop placed on the 5 % emulsion - containing samples s - 5 remained on top of the samples for one - half hour when the test ended . a similar test was conducted on the bottom of the samples . two drops of water on the control samples were absorbed within 52 minutes , whereas the water drops never fully penetrated the bottom surface of the emulsion - containing samples . measurements of properties as noted below were obtained by an independent testing laboratory . presented below are the results of water permeability tests for 7 days , unit weight and water absorption tests over 24 hours , and compressive strength tests after 28 days : the emulsion containing samples were cut with a diamond saw , polished , and were studied under magnification to determine the homogeneity of the emulsified wax particles in the samples . it was found that the particles had relatively uniform distribution in the admixture . it was also observed that the entrapped voids were non - uniform in size , but uniformly distributed in the samples . in this example a lower amount of emulsion of a waxy substance , namely 2 . 5 % waxy substance by weight of the total water in the composition , was utilized and compared to control samples and the composition of s - 5 in example 1 , using the preparation procedures of that example . the samples utilized 375 grams of portland cement and 675 grams of sand and the following in grams : the samples following mixing and placing in polypropylene tubes were tamped and rodded as in example 1 , and tested for compression , unit weight , and water permeability with the following results ; the above tests demonstrated that the strengths of the samples containing aqueous emulsions of a waxy substance were slightly higher than the control samples without the waxy substance , that the unit weights of the emulsion containing samples were lower than the unit weight of the control samples , and that the water permeability of the emulsion containing samples , whether containing 2 . 5 % waxy substance or 5 . 0 % waxy substance , was substantially identical and substantially improved over the permeability of the control sample not containing aqueous emulsion of a waxy substance . the amount of water required in a water , cement and aggregate composition can be decreased by utilizing an aqueous emulsion of a waxy substance to a greater extent than might be expected from a substitution of the water content in the emulsion for an equivalent amount of water as present the composition not having the emulsion . to demonstrate this discovery , samples were prepared using the procedures and the composition and amounts of water , cement and sand specified for the control samples in example 1 , and samples ( s - 5 / 3 ) of a 5 % waxy substance in aqueous emulsion as described in example 1 to water ( assuming 180 grams of water ) using only 166 . 3 grams of water rather than 170 . 25 grams as in samples s - 5 in example 1 , and having the same consistency ( slump ) as the control samples . the samples ( 2 each ) were tested for compressive strength with the following results : thus , the water content was reduced by 7 . 6 % by using an aqueous emulsion of a waxy substance , while the same workable composition , i . e ., having the same slump , was achieved and the average compressive strength of the cementritious product was maintained . even greater reduction in the water to cement ratio can be obtained with other surfactant systems . for example , use of paracol 802n emulsion enabled a reduction in the water to cement ratio by 16 . 8 %. it is known to those skilled in the art that the lower the water to cement ratio , the better the stronger and less porous concrete product . the improvement in the ability of the composition of the present invention to withstand alternate periods of freezing and thawing cycle was demonstrated as noted below . samples of concrete were prepared according to the procedure of example 1 , with the samples each containing 375 grams of cement and 675 grams of sand , and the following in grams : the slump of both the control and s - 5 / 4 samples was approximately the same . the samples were placed in polypropylene tubes and rodded and tamped and excess material removed from the top of the tube with a screed as in example 1 . the relative durability of the concrete samples was determined by allowing the specimens to cure for at least two weeks to insure full hydration , and then determining their weight loss following cycles of freezing and thawing . this was accomplished by submerging the samples in a 10 % solution of salt water for one day , removing the samples , toweling the samples dry , obtaining their initial weight , placing them in a freezer until completely frozen , and then allowing them to thaw . the freezing and thawing cycles were repeated and the weight of each sample determined after every 5 cycles . the results of the test are as follows , with the weight measured in grams : it was observed that the control sample visibly lost material after only 6 cycles and lost measurable weight after 10 cycles , whereas the emulsion - containing sample gained weight after each cycle and did not show any difference in appearance after each cycle . in addition , the control sample was aged longer than the s - 5 / 4 sample , which should have made the control sample more durable , which it was not . the presence of the aqueous emulsion of a waxy substance in the composition of the present invention substantially improved the product against the deterioration expected to be caused by freezing and thawing as occurred in the control sample . such unexpected improvement is believed to be due to the substantial improved ability of the emulsion - containing product to withstand water penetration , or to the particles of the waxy substance acting in the same manner that microscopic air particles enhance freeze - thaw durability by allowing water reduction and acting as “ shock absorbers ”. the slight increase in weight of the s - 5 / 4 sample was unexpected . a possible explanation is that the wax radically decreased the water penetration , and , as time elapsed , a small amount of water penetrated the sample causing a slight increase in its weight . however , there was no evidence of spalling in the sample , whereas significant spalling occured in the control sample . the significant improvement in the freeze - thaw durability of the products and composition of the present invention was unexpected in view of studies published by the portland cement association which in part states that concrete experiences less deterioration when the water to cement ratio of less than 0 . 50 . water entering the concrete freezes and expands and deteriorates the concrete . while both the control samples and the emulsion - containing samples each had a water - cement ratio of less than 0 . 5 , the control sample deteriorated during freezing and thawing , while the emulsion - containing sample did not . the fact of the lack of deterioration of the emulsion - containing sample could only be explained by the presence of the waxy substance . in this example , an aqueous emulsion of a slack wax was utilized to demonstrate the substantial improvement in the resistance against water penetration achieved by the use of aqueous emulsions of other waxy substances in the process and compositions of the present invention . in addition , two different surfactants were present in the emulsions demonstrating the favorable results achieved with each . samples of concrete were prepared as in example 1 , each containing 375 grams of cement and 675 grams of sand of coarser particles than in example 1 . in addition , the samples contained the following ingredients in grams : it was observed that the samples s - 5n were very sloppy such that no tamping or tapping was necessary to fill the propylene tube since the composition easily flowed , whereas the samples s - 5m were less flowable than samples 5n . the samples cured for two weeks , and then tested for water absorption , unit weight and compressive strength following the procedure of example 1 , with the following results : one specimen from each of the s - 5n samples and the s - 5m samples were viewed under magnification , and the wax particles were found to be well distributed in each case . in addition , when a drop of water was placed onto the surface of the s - 5n and s - 5m samples , the water remained on the surface until it evaporated , and thus was found not to be absorbed into the sample . it was noted that the control sample turned white and lost weight faster than the s - 5n and s - 5m samples . this unexpected occurrence could be explained by the waxes slowing the rate of evaporation of the excess water found inside the concrete masses . it is believed that these crystalline or slack wax - containing samples retained excess water , whereas excess water evaporated from the control samples , and consequently the necessity to cover freshly placed concrete pavement which is produced in accordance with the present invention with tarpaulins , watered salt grass , or other water - retaining aids to retard the evaporation of water may be eliminated . several different combinations of aqueous emulsions of waxy substances and surfactants were incorporated into compositions in accordance with the present invention and several properties tested . samples were prepared in the same manner following the same procedures , and with the same amount of cement and sand as in example 1 , and except for the control sample , 18 . 75 grams of aqueous emulsion of a waxy substance identified as follows : the results indicate the substantial improvement in the resistance to water penetration provided by the composition of the present invention , with little difference between the waxy substance employed in the emulsion or surfactant used . in this example still lower amounts of emulsion of a waxy substance were utilized to demonstrate the small amount of emulsion which may be employed in accordance with the present invention to achieve the desired results described herein . in this example , as little as 0 . 5 % and 1 % waxy substance by weight of the total water in the composition , were utilized and compared to control samples and samples with 2 . 5 % waxy substance of the compositions of example 1 and 16 ounces and 32 ounces per 100 pounds of cement of calcium stearate suspension , using the procedures of example 1 . the calcium stearate suspension utilized was dry block ® marketed by w . r . grace & amp ; co ., and obtained from a local masonry block outlet . the samples utilized 375 grams of portland cement and 675 grams of sand , 180 grams of water in the control samples , and only enough water in the other samples to achieve the same slump as in the control sample . the water to cement ratio of all samples was kept the same , i . e ., 0 . 48 lbs ./ lb . the samples following mixing and placing in polypropylene tubes were tamped and rodded as in example 1 , aged 28 days , and tested for compression , unit weight , and water permeability by an independent laboratory with the following results : the above tests demonstrated that the compressive strengths of the samples containing aqueous emulsions of a waxy substance and of solutions of calcium stearate were similar to the strength of the control samples , that there was only a slight reduction in the unit weights of the waxy substance emulsion containing samples and the calcium stearates containing samples as compared to the unit weight of the control samples , and that the water permeability of the waxy substance emulsion containing samples and the calcium stearate containing samples were slower than the water permeability of the control samples . it is noted that the water permeability of the 0 . 5 % waxy substance containing sample and of the 16 ounce calcium stearate containing samples were approximately equal , the permeability of the 32 ounce calcium stearate containing sample was approximately equal to that of the 5 % waxy substance emulsion containing sample , and that the resistance to permeability of all of the treated samples were better by a factor of 10 than that of the control sample . while particular embodiments of the process and compositions of the invention have been described , it will be appreciated by those skilled in the art that changes and modifications may be made thereto without departing from the invention in its broader aspects and as set forth in the following claims .