the invention is specifically described by referring to the following examples . basic chemical adsorption methods include the procedure mentioned , for example , in j . sagiv , journal of american chemical society , 102 : 92 ( 1980 ) and in k . ogawa et al ., langmuir , 6 : 851 ( 1990 ). in these methods , a chemically adsorbed film is manufactured by a dehydrochlorination reaction of molecules comprising chlorosilyl groups ( chemical adsorbent ) to a substrate surface comprising hydroxyl groups or the like , thus fixing the groups to the substrate surface via covalent bonds . in forming a chemically adsorbed film , a functional group , which bonds a molecule to a substrate , is at least one functional group selected from the group consisting of a functional group of formula 1 set forth above , a functional group of formula 2 set forth above , a halogenated sulfinyl group of formula 3 set forth above , a halogenated sulfinyl group of formula 4 set forth above and a cyano group (-- cn ). however , the functional group applicable to the invention is not limited to the above - noted groups . as a halogen of the invention , cl , br or i can be included . in terms of reactivity , however , it is preferable to use cl . the substrates useful in this invention have on the surface at least one functional group selected from the group consisting of a hydroxyl group , a carboxyl group , a sulfonic acid group , a sulfinic acid group , a phosphoric acid group , a phosphorous acid group , a quaternary ammonium group , a quaternary phosphonium group , a thiol group and an amino group ; and / or at least one functional group , in which an alkali metal or alkaline earth metal is substituted for h of the group , selected from the group consisting of a hydroxyl group , a carboxyl group , a sulfonic acid group , a sulfinic acid group , a phosphoric acid group , a phosphorous acid group , a quaternary ammonium group , a quaternary phosphonium group , a thiol group and an amino group . the chemically adsorbed film of the invention is not limited to films which include the above - mentioned functional groups , and is fixed to the substrate surface comprising the functional group . when the substrate surface has none or only a few of the functional groups mentioned above , a uv irradiation or oxidizing agent treatment should be applied to the surface , thus effectively creating or increasing the functional groups on the surface . the method of fixing the chemically adsorbed film to the substrate surface includes but is not limited to methods of contacting a substrate to a liquid and / or gaseous chemical adsorbent , and / or to a solution dissolving the chemical adsorbent . in the case of using the above - mentioned solution dissolving the chemical adsorbent , it is preferable to use a solvent comprised of molecules with no active hydrogens . for instance , if the chemical adsorbent comprises long - chain alkyl groups , a mixed solvent of hydrocarbon and halogenated hydrocarbon can be employed . in addition , it is appropriate to use halogenated hydrocarbon solvent , aromatic solvent or the like for the chemical adsorbent comprising carbonyl groups . however , the solvent applicable in the invention is not limited to the solvents mentioned above . after fixing the chemically adsorbed film to the substrate , it is preferable to remove unreacted molecules ; as a result , a monomolecular film and a multilayer film can be easily formed on the substrate . it is preferable to use an aprotic solvent to remove the unreacted molecules ; for instance , halogenated carbon , ether , lactone , ester , nitrile , amide or the like are included as such solvents . however , the solvent is not limited to those solvents . the invention will now be explained specifically in the following examples . an adsorption solution a was prepared by dissolving about 1 % by weight of ( 3 - dicyclopentadienylpropyl ) trichlorosilane into a mixed solvent of hexadecane , carbon tetrachloride and chloroform at a weight ratio of 80 : 12 : 8 , respectively . a glass substrate 1 ( hydrophilic substrate ) as shown in fig1 was prepared . after being washed with an organic solvent , glass substrate 1 was dipped and held in adsorption solution a for three hours . due to this treatment , bonds of the following formulas 5 were formed on glass substrate 1 . ## str5 ## ( wherein c 10 h 11 represents a dicyclopentadienyl group ) after washing glass substrate 1 with chloroform ( nonaqueous solvent ) for 15 minutes and with water for another 15 minutes , a chemically adsorbed monomolecular film 2 of fig2 was formed on the substrate surface . chemically adsorbed monomolecular film 2 was firmly bonded to glass substrate 1 , and had excellent water - repelling properties . the formation of the film was confirmed by obtaining particular signals for this structure at 2925 , 2855 ( attribute of -- ch 2 --), 1650 ( attribute of c ═ c ), 1465 ( attribute of -- ch 2 --), and 1080 ( attribute of si -- o ) cm - 1 by fourier transform infrared absorption spectral ( ftir ) measurement . then , glass substrate 1 formed with chemically adsorbed monomolecular film 2 was dipped and held in decalin . after heating a section of the film with an infrared laser at around 190 ° c . for one hour , nah and then anhydrous fecl 2 were added to the decalin . after the above - noted procedure , glass substrate 1 was washed with hexane for 10 minutes and then with water for another 10 minutes ; as a result , the skeleton , which had been irradiated with the infrared laser , was changed to a ferrocene skeleton , thus forming a chemically adsorbed monomolecular film 3 ( fig3 ). chemically adsorbed monomolecular film 3 was firmly connected to the substrate and had excellent water - repelling properties . the creation of an additional particular signal at 815 ( attribute of a ferrocene skeleton ) cm - 1 and also the disappearance of the signal at 1650 cm - 1 were confirmed by ftir measurement . chemically adsorbed monomolecular 3 was proved to have fe atoms by x - ray photoelectric spectroscopic ( xps ) measurement . the above - noted results indicate that a signal can be recorded as a ferrocene in the section irradiated with the laser . glass substrate 1 formed with chemically adsorbed monomolecular film 3 of example 1 was dipped and held in decalin . after heating only the dicyclopentadiene skeleton , which had not been changed to the ferrocene skeleton , with an infrared laser at about 190 ° c . for one hour , nah and then anhydrous rucl 2 were added to the decalin . after that , glass substrate 1 was washed with hexane for 10 minutes and then with water for another 10 minutes , thereby forming a chemically adsorbed monomolecular film 4 , in which a ferrocene skeleton and a ruthenocene skeleton are intermingled , as shown in fig4 . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . the creation of an additional signal at 821 cm - 1 was confirmed by ftir measurement . in addition to the fe atom , a ru atom was also found in chemically adsorbed monomolecular film 4 by xps measurement . the results indicate that the information recorded with light of 821 cm - 1 and 815 cm - 1 can be recognized and read . the surface of chemically adsorbed monomolecular film 4 including ferrocene and ruthenocene was observed in ethanol with an interatomic force microscope ( afm ), a type of scanning probe electron microscope . in observing the sections of the film which had been irradiated with the infrared laser in examples 1 and 2 , convex and concave surfaces with three different heights were clearly found . in other words , there were two kinds of metallocene skeletons which had been formed as a result of the above - described reactions , and an unreacted dicyclopentadiene skeleton in chemically adsorbed monomolecular film 4 . an adsorption solution b was prepared by dissolving about 1 % by weight of 14 - iodotetradecyltrichlorosilane into a mixed solvent of hexadecane , carbon tetrachloride and chloroform at a weight ratio of 80 : 12 : 8 , respectively . as shown in fig1 a glass substrate 1 was used as a hydrophilic substrate . after washing glass substrate 1 with an organic solvent , the substrate was dipped and held in adsorption solution b for three hours . due to this treatment , bonds of the following formula 6 were formed on glass substrate 1 . ## str6 ## glass substrate 1 was washed with chloroform ( nonaqueous solvent ) for 15 minutes and then with water for another 15 minutes , thus forming a chemically adsorbed monomolecular film 5 . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . signals were obtained for this structure at 2925 , 2855 ( attribute of -- ch 2 --), 1465 ( attribute of -- ch 2 --), and 1080 ( attribute of si -- o ) cm - 1 by ftir measurement , thereby confirming the formation of the film . glass substrate 1 formed with chemically adsorbed monomolecular film 5 was dipped and held in dry tetrahydrofuran ( thf ) under a nitrogen atmosphere . hexapentadienide sodium was then added and reacted for 30 minutes , thus forming cyclopentadiene skeletons . dicyclopentadiene skeletons were soon formed by the cycloaddition of two neighboring cyclopentadiene skeletons , thus forming a chemically adsorbed monomolecular film 6 as shown in fig6 . an additional signal was obtained for this structure at 1650 ( attribute of c ═ c ) cm - 1 by ftir measurement , thereby confirming the formation of the film . in other words , the information recorded with light of 1650 cm - 1 can be read . glass substrate 1 having chemically adsorbed monomolecular film 6 on its surface was dipped and held in decalin . after heating only one section of the film with an infrared laser at about 190 ° c . for one hour , nah and then anhydrous fecl 2 were added to the decalin . after that , glass substrate 1 was washed with hexane for 10 minutes and then with water for another 10 minutes . as a result , the chemically adsorbed monomolecular film 7 of fig7 in which only the section irradiated with the infrared laser was changed to a ferrocene skeleton , was formed . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . a particular signal was obtained for this structure at 815 ( attribute of a ferrocene skeleton ) cm - 1 by ftir measurement . according to xps measurement , it was proved that chemically adsorbed monomolecular film 7 comprised fe atoms . these results indicate the information recorded with light of 815 cm - 1 can be read . an adsorption solution c was prepared by dissolving about 1 % by weight of 6 - dicyclopentadienyl - 1 , 8 - di ( trichlorosilyl ) octane into a mixed solvent of hexadecane , carbon tetrachloride and chloroform at a weight ratio of 80 : 12 : 8 , respectively . as shown in fig1 a glass substrate 1 was used as a hydrophilic substrate . after being washed with organic solvent , glass substrate 1 was dipped and held in adsorption solution c for three hours . as a result , bonds of the following formula 7 were formed on glass substrate 1 . ## str7 ## ( wherein c 10 h 11 represents a dicyclopentadienyl skeleton ) glass substrate 1 was washed with chloroform for 15 minutes and then with water for another 15 minutes , thus forming a chemically adsorbed monomolecular film 8 as shown in fig8 . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . distinctive signals were obtained for this structure at 2925 , 2855 ( attribute of -- ch 2 --), 1650 ( attribute of c ═ c ), 1465 ( attribute of -- ch 2 --), 1080 ( attribute of si -- o ) cm - 1 by ftir measurement , thus confirming formation of the film . glass substrate 1 formed with chemically adsorbed monomolecular film 8 was dipped and held in decalin , and only a section of the film was heated with an infrared laser at about 190 ° c . for one hour . nah and then fecl 2 were added to the decalin . glass substrate 1 , moreover , was washed with hexane for 10 minutes and then with water for another 10 minutes . as shown in fig9 a chemically adsorbed monomolecular film 9 comprising a ferrocene skeleton was formed . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . an additional distinctive signal for this structure at 815 ( attribute of a ferrocene skeleton ) cm . sup . - 1 was confirmed by ftir measurement while the signal at 1650 cm - 1 disappeared . according to xps measurement , it was confirmed that the film comprised fe atoms , thus indicating the formation of a ferrocene skeleton . glass substrate 1 having chemically adsorbed monomolecular film 9 on its surface was then dipped and held in adsorption solution c for three hours . after washing glass substrate 1 , a chemically adsorbed monomolecular film 10 was formed , thus forming a chemically adsorbed multilayer film of fig1 on the substrate . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . the signals obtained by ftir measurement at 2925 , 2855 ( attribute of -- ch 2 --), 1465 ( attribute of -- ch 2 --), 1080 ( attribute of si -- o ) cm - 1 were doubled , thus confirming the formation of the multilayer film . glass substrate 1 , which had the chemically adsorbed multilayer film comprised of chemically adsorbed monomolecular films 9 and 10 on its surface , was dipped and held in decalin . then , a section of chemically adsorbed monomolecular film 10 was heated with an infrared laser at about 190 ° c . for one hour . nah and then rucl 2 were added to the decalin . after washing glass substrate 1 with hexane for 10 minutes and then with water for another 10 minutes , a chemically adsorbed monomolecular film 11 comprising ruthenocene skeletons was formed as shown in fig1 . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . an additional distinctive signal was found at 821 ( attribute of a ruthenocene skeleton ) cm - 1 by ftir measurement while the signal at 1650 cm - 1 disappeared . it was confirmed by xps measurement that chemically adsorbed monomolecular film 11 comprised ru atoms , thus indicating the formation of ruthenocene skeletons . according to the above - noted results , the information recorded with light of 821 cm - 1 and 815 cm - 1 can be read . glass substrate 1 having chemically adsorbed monomolecular film 7 of example 4 on its surface was dipped and held in frozen methylene chloride . ethylamine was then added to the solution . after three minutes , lithium powder was also added to the methylene chloride , and then glass substrate 1 was left for an extra 10 minutes . after being quenched with methanol , glass substrate 1 was washed with chloroform for 10 minutes and then with water for another 10 minutes . as a result , a chemically adsorbed monomolecular film 12 was formed as shown in fig1 . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . ftir measurement showed that the signal at 815 cm - 1 dissapeared . xps measurement , in addition , showed that chemically adsorbed monomolecular film 12 did not comprise fe atoms , thereby confirming the disappearance of ferrocene skeletons in the film . in other words , both readout and erasure of recorded information can be achieved with light of 815 cm - 1 in the invention . an adsorption solution d was prepared by dissolving about 1 % by weight of ( 3 - cyclopentadienylpropyl ) trichlorosilane into a mixed solvent of hexadecane , carbon tetrachloride and chloroform at a weight ratio of 80 : 12 : 8 , respectively . as shown in fig1 a glass substrate 1 was used as a hydrophilic substrate . after being washed with organic solvent , glass substrate 1 was dipped and held in adsorption solution d for three hours . as a result , bonds of the following formula 8 were formed on glass substrate 1 . ## str8 ## ( wherein c 5 h 5 represents a cyclopentadienyl group ) glass substrate 1 was first washed - with chloroform for 15 minutes and then with water for another 15 minutes , thus forming a chemically adsorbed monomolecular film 13 as shown in fig1 . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . distinctive signals were obtained for this structure at 2925 , 2855 ( attribute of -- ch 2 --), 1650 ( attribute of c ═ c ), 1465 ( attribute of -- ch 2 --) and 1080 ( attribute of si -- o ) cm - 1 by ftir measurement , thereby confirming the formation of the film . glass substrate 1 having chemically adsorbed monomolecular film 13 on its surface was dipped and held in decalin . nah and then anhydrous fecl 2 were added to the decalin . thereafter , glass substrate 1 was washed with hexane for 10 minutes and then with water for another 10 minutes , thus forming a chemically adsorbed monomolecular film 14 comprising a ferrocene skeleton as shown in fig1 . the monomolecular film was firmly connected to the substrate , and possessed good water - repelling properties . ftir measurement showed the disappearance of the signal at 1650 cm - 1 and the creation of an additional distinctive signal at 815 ( attribute of a ferrocene skeleton ) cm - 1 . xps measurement indicated that chemically adsorbed monomolecular film 14 comprised fe atoms . the results show that the information recorded with light of 815 cm - 1 can be read . an adsorption solution e was prepared by dissolving about 1 % by weight of ( 8 - dicyclopentadienyloctyl ) trichlorosilane into a mixed solvent of hexadecane , carbon tetrachloride and chloroform at a weight ratio of 80 : 12 : 8 , respectively . a glass substrate 1 ( hydrophilic substrate ) as shown in fig1 was prepared . after being washed with an organic solvent , glass substrate 1 was dipped and held in adsorption solution e for three hours . after being washed with chloroform ( nonaqeous solvent ) for 15 minutes and then with water for another 15 minutes , glass substrate 1 was annealed at 100 ° c . in a nitrogen atmosphere for 20 minutes . as a result , a chemically adsorbed monomolecular film 15 of fig1 was formed on the substrate surface . chemically adsorbed monomolecular film 15 was firmly bonded to glass substrate 1 , and had excellent water - repelling properties . the formation of the film was confirmed by obtaining particular signals for this structure at 2925 , 2855 ( attribute of -- ch 2 --), 1650 ( attribute of c ═ c ), 1465 ( attribute of -- ch 2 --), and 1080 ( attribute of si -- o ) cm - 1 by ftir measurement . the half of glass substrate 1 formed with chemically adsorbed monomolecular film 15 was then irradiated with an infrared laser at about 190 ° c . for five minutes . signals attributed to the vibration of the aromatic skeleton were found at 1660 and 1610 cm - 1 by ftir measurement , and the measurement also showed that the signal at 1650 cm - 1 decreased to 45 % of the signal obtained immediately after the formation of chemically adsorbed monomolecular film 15 . these results indicate that the rings of dicyclopentadiene skeletons were opened by the irradiation , and that cyclopentadiene skeletons were formed . in other words , a chemically adsorbed monomolecular film 16 of fig1 was formed on the surface of glass substrate 1 . the signals from glass substrate 1 were observed by ftir measurement after 5 , 10 , 30 and 60 days , but there was no sign of a change in the signals . following that , glass substrate 1 was again irradiated with an infrared laser at 70 ° c . for two minutes . according to ftir measurement , the signals at 1660 and 1610 cm - 1 disappeared , and the intensity of the signal at 1650 cm - 1 returned to the same intensity of the initial signal obtained immediately after the formation of chemically adsorbed monomolecular film 15 , thereby confirming the formation of dicyclopentaidene skeletons . even when functional groups other than the ones used in examples 1 - 8 were applied , similar information recording layers were formed . the invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof . the embodiments disclosed in this application are to be considered in all respects as illustrative and not restrictive , the scope of the invention being indicated by the appended claims rather than by the foregoing description , and all changes which come within the meaning and range of equivalency of the claims are intended to be embraced therein .