the boron - doped carbon microspheres of the present invention are microspheres having a diameter of less than about 700 nm and generally less than 500 nm , or less than 100 nm down to about 50 nm . the microspheres are further considered to be nanoporous wherein the spheres include pores having a diameter generally in the range of 0 . 6 nm to about 2 nm these microspheres are formed from a combination of carbon and boron . the major component of the microspheres is carbon . the boron - doped carbon microspheres of the present invention are formed by chemical vapor deposition . in the chemical vapor deposition process , the reactants are injected into a flowing gas stream and are vaporized . the flowing gas stream , including the reactants , is heated further and impacted against a substrate and the carbon microspheres deposit on the substrate . the reactants include a carbon source gas , a boron source , as well as a catalyst . generally , any typical catalyst suitable for use in forming carbon microspheres can be employed . iron , nickel and cobalt catalysts can be used . one typical catalyst is ferrocene . the carbon source can be any hydrocarbon , either saturated or unsaturated and may be aromatic . in particular , compounds such as benzene and xylene are particularly suitable for use in the present invention as a carbon source . the boron source must be a compound that can be formed into a vapor at reaction temperatures without decomposing . generally , a vapor is formed by dissolving a boron containing compound into an appropriate solvent , preferably a hydrocarbon solvent , and then injecting this into the chemical vapor deposition reactor . as is described below , it is convenient to dissolve the boron source into the carbon source . suitable boron containing compounds include the halides , such as boron triflouride and boron trichloride , as well as other compounds that can be dissolved in an appropriate solvent such as nitrates , and the like . generally , the stoichiometric ratio of boron to carbon will be 1 to 20 to 1 . 5 to 10 generally 1 to 9 to 1 to 10 . the reaction is conducted in a chemical vapor deposition reactor with a suitable deposition substrate . the deposition substrate must be inert under reaction conditions . suitable substrates include magnesium oxide , aluminum oxide , indium tin oxide , as well as quartz . chemical vapor deposition reactors include a heating zone and a reaction zone . to form the microspheres , the heating zone is maintained at a temperature sufficient to vaporize the reactants , typically about 200 ° c . the reaction zone is maintained at a much higher temperature , generally above 650 ° c . for this reaction , typically about 850 - 1000 ° c . the reaction is conducted by forming a solution of the reactants , including the catalyst , carbon source and boron source , in the desired stoichiometric relation . this is injected into the heating zone into a flowing gas stream . the flowing gas stream can be a variety of inert gases , but typically are nitrogen or argon , or mixtures thereof . hydrogen may also be included to avoid soot formation , if needed . further , a nitrogen source gas such as ammonia may be added to facilitate boron inclusion into the microspheres . if ammonia is added , it will generally comprise about 10 % of the partial pressure of the gas stream . hydrogen will comprise 0 - 20 % of the partial pressure of the gas stream . generally , the ratio of ammonia to hydrogen to inert gas ( ar ) will vary from 1 : 1 : 1 : to 1 : 4 : 4 by volume . the flowing gas stream draws the reactants from the heating zone where they are vaporized into the reaction zone where they form the boron - doped carbon microspheres on the selected substrate , typically quartz . when the nitrogen source gas , ammonia , is added , it is believed that the nitrogen bonds to carbon and bonds to the boron . if ammonia is not present , the boron bonds directly to the carbon . this latter reaction is not as thermodynamically favored as the nitrogen carbide formation . thus , the addition of ammonia increases the incorporation of boron into the microspheres . typically , the reactor is purged with an inert gas to remove all oxygen from the system prior to the reaction . after purging , the flow of gas is started . the reactants are then introduced in the desired ratio into the flowing gas stream . after an appropriate period of time , generally 5 minutes to 1 hour , the injection of the reactants is discontinued and the furnace cooled down to room temperature under argon and hydrogen . the formed microspheres can be subjected to a mild oxidation in order to open the porous structure . in order to do so , the preheating zone is heated to a temperature of about 500 ° c ., and the reaction zone to about 850 ° c . deionized water is simply injected into the preheating zone and evaporated and transported into the reaction zone in flowing argon . this is continued again for about 30 minutes . the furnace is then cooled down to room temperature under flowing argon . the invention will be further appreciated in light of the following detailed examples . boron - doped carbon microspheres ( bcms ) were prepared by a chemical vapor deposition process inside a quartz tube inserted through a low - temperature heating section ( zone i , 200 ° c .) and a high - temperature heating section ( zone ii , 950 ° c .). 0 . 34 g ferrocene was dissolved in 23 . 63 g boron trichloride solution 1 . 0 m in p - xylene ( both from sigma - aldrich ) and used as precursor for bcms synthesis . the solution was injected and vaporized in zone i . a hydrogen and argon mixture ( 60 ml / min and 90 ml / min , respectively ) was used to transport the vapor from zone i to zone ii . the bcms were formed over a polished quartz plate inside zone ii . after 30 minutes , the solution injection was stopped and the furnaces were cooled down to room temperature with the argon and hydrogen flowing . the boron - doped carbon microspheres ( bcms ) formed in example 1 were activated in steam to open the pore structure . for this purpose , zone i and zone ii were heated and kept at 500 ° c . and 850 ° c ., respectively . deionized water was injected into and evaporated inside the quartz tube in the middle of zone i at the rate of 0 . 225 ml / min . flowing argon ( 140 ml / min ) was used to carry the steam to zone ii and react with bcms , which were synthesized as disclosed in example 1 . the injection of water lasted for 30 minutes . after stopping the injection of water and turning off the temperature controller , the furnace was cooled down to room temperature with flowing argon . the boron - doped carbon microspheres formed from the above examples were spherical particles with uniform particle size . tem images reveal that the microspheres have an onion structure , and x - ray photon electron spectrum indicated they are comprised of carbon , boron and oxygen an impurity . generally , the boron to carbon ratio is approximately from 1 : 4 - 1 : 12 . the microspheres are high purity uniform spheres of about 700 nanometers or less in diameter , and reasonably high surface area of about 220 m 2 / g measured via nitrogen absorption . further , thermogravimetric analysis demonstrates that the oxidation stability is comparable to pure multiwall nanotubes . the activated microspheres contain a large number of mesopores and the bet surface area is about 213 m 2 / g , which is the same range as standard carbon black , but higher than multiwall carbon nanotubes . the sheet resistance of the microspheres is lower than that formed from multiwalled carbon nanotubes . the micropore surface area was 107 m 2 / g and the total pore volume was 0 . 163 cm 3 / g . the micropore volume was 0 . 054 cm 3 / g and the median micropore diameter was 0 . 62 nm . fig1 shows the pore size distribution of the activated mircospheres . the activated microspheres clearly contain a large number of mesospheres . 0 . 5 g ferrocene was dissolved in 28 . 0 g boron trichloride solution in 1 . 0 m p - xylene ( both from sigma - aldrich ) and used as precursor for bcms synthesis . the solution was injected into the same reactor as in example 1 and fully vaporized in the low - temperature zone i ( 200 ° c .). a carrier gas mixture containing ammonia , hydrogen and argon with pre - set volume ratio ( volume ratio nh 3 / h 2 / ar = 1 / 1 . 33 / 4 and total flow rate of 190 ml / min ) was added through upstream of zone i . bcms formed on the surface of a quartz substrate positioned in the high - temperature zone at 900 ° c . the growth process lasted for 30 minutes until the liquid precursor injection stopped . the carrier gas continued to flow for another 20 minutes before the reactor was cooled down . the boron - doped carbon microspheres of the present invention can be used in a variety of different applications . in particular , these can be used in fuel cells , which are devices that convert chemical energy of fuels , such as hydrogen , directly into electrical energy . the proton exchange membrane fuel cell is one type of fuel cell that can utilize the boron - doped carbon microspheres of the present invention . the boron - doped carbon microspheres can be used in any fuel cell operating at less than 500 ° c . these can be combined with an electron conducting resin or used on other supports . also , the boron - doped carbon microspheres of the present invention can provide a durable catalyst support . the uniform pore size of the microspheres allow the microspheres to carry gases through their porous structure . in particular , the unique spherical structure and high thermal stability and oxidation resistance of the boron - doped carbon microspheres compared to carbon black , carbon fibers or carbon nanotubes , enable this product to be used as a catalyst support in which its uniform rate of gas transport does not degrade . thus , the microspheres can be used as supports for electrolytic cell cathodes or anodes . these would be used in the electrolysis of water , ammonia or dissolved organic material . the catalyst support can take the configuration shown in fig2 in which a porous conductive support layer 11 is coated with a layer 12 of the boron - doped carbon nanospheres . this layer is in turn coated with a catalyst 13 such as a noble metal . the catalyst can be deposited by well known methods such as vapor deposition , electrochemical deposition and chemical deposition . exemplary catalysts include platinum , iridium , ruthenium , rhenium , palladium , gold , silver , nickel , iron , lanthanides and alloys of these . basically , any catalyst can be supported by these microspheres , including nonmetallic catalysts as well as metallic catalysts . the boron - doped carbon microspheres of the present invention can also be used as an adsorbant to store gases such as hydrogen . in this application , hydrogen is typically stored under elevated pressure , and frequently at reduced temperatures , causing the hydrogen to migrate into the boron - doped carbon microspheres . the boron , in particular , enhances the hydrogen absorption via a non - classical chemical binding mechanism in which the two undissociated h atoms in the molecule and the b form a 3 - body center sharing two common electrons . further the high surface area increase h 2 absorption . also , due to the ability of the microspheres to absorb organic compounds , the microspheres of the present invention can be used as a drug delivery system , absorbing pharmacologically active organic compounds , and gradually releasing them subsequent to administration . in another application , the boron - doped carbon microspheres of the present invention can be used as adsorbants in a wide variety of different applications , and , in particular , in hemoperfusion applications . the uniform size of these spheres , along with their porous structure , both facilitate in use in hemoperfusion in place of activated carbon . as shown in fig2 , the hemoperfusion filter 20 would include a porous support layer 22 coated with a layer of the boron - doped carbon microspheres 24 . blood or other fluid would flow through the filter 20 in the direction of arrow 26 . organic molecules will tend to bond to the microspheres thereby filtering the fluid . the boron - doped carbon microspheres possess a much higher electrical conductivity than carbon nanotubes while being stable at higher temperatures . for that reason , the microspheres can be used in a variety of different applications . these microspheres are particularly useful in batteries as a conductive surface and / or support . the microspheres can form conductive surfaces in metal ion batteries as well as metal hydride batteries and other batteries such as metal / air batteries . these microspheres can also replace carbon in the cathodes and anodes in batteries , fuel cells and electrolytic cells . they can also comprise nonometer size conductors or nano wiring for micro circuits . the boron - doped carbon microspheres can be used in any application requiring electrical conductivity , and , in particular can be used to replace indium tin oxide in a variety of different applications , including solar panels , and the like . in particular , the boron - doped carbon microspheres can be added to photoactive compositions and used to form thin layer solar panels . thus , the boron - doped carbon microspheres of the present invention can be used in a wide variety of different applications because of their enhanced support stability through boron doping , enhanced catalyst support interaction providing improved stability , high electronic conductivity , spherical particle shape permitting uniform packing density . this has been a description of the present invention along with the preferred method of practicing the present invention . however , the invention itself should only be defined by the appended claims , wherein we claim :