transesterified organosilicon compounds , including ionic organosilicon compounds and coupling agents , and aqueous - based compositions including transesterified organosilicon compounds are provided . compositions comprising at least one transesterified organosilicon are suitable for application to various inorganic , organic and cullulosic surfaces for imparting water repellency and improved wetting . compositions comprising transesterified organosilicon compounds exhibit reduced flammability , improved hydrolytic stability , reduced gloss and improved water repellency while maintaining reactivity with various substrates .