disclosed is a graphite / dsa assembled electrode for a redox flow battery , obtained by assembling a graphite electrode made of micro - sized graphite and a dsa electrode using rolling thus improving cell performance including electrode durability , corrosion resistance , power density , energy efficiency and cycle properties . a method of manufacturing the graphite / dsa assembled electrode is also provided , which includes preparing a mixture composed of a graphite active material , a conductive material and a binder into a slurry using an alcohol , evaporating the alcohol from the slurry thus preparing a paste , thinly spreading the paste into an electrode sheet , and rolling the electrode sheet along with a dsa electrode thus obtaining the assembled electrode . a redox flow battery including the electrode thus obtained is also provided , which has increased electrode durability and corrosion resistance and enhanced power properties , energy efficiency and cycle performance .