a photoluminescent exit sign includes a generally planar faceplate comprising a plurality of openings defining the word “ exit ” and optional chevrons . at least some of the periphery of said openings comprises an angle relative to the surface of the faceplate . a backplate has a photoluminescent material and is disposed adjacent to the faceplate so as to result in the illuminated letters defining the work “ exit ” and optional chevrons . methods for forming photoluminescent exit signs are also disclosed .