a method for measuring surface property parameters of a material comprises : performing saturation processing on a surface of a material ; mixing the material which has been processed by saturation with an indicating electrolyte solution ; after the mixture solution achieves an balance by ion exchange , measuring the balanced concentration values of positive ions of the indicating electrolyte and h + in the mixture solution ; according to the balanced concentration values of positive ions of the indicating electrolyte , calculating surface potential of the material ; and according to the surface potential of the material , calculating specific surface area and surface charge density of the material ; according to surface charge density of the material , calculating surface electric field intensity ; according to surface charge density and specific surface area of the material , calculating total surface charge of the material . a system for measuring surface property parameters of a material can be based on the method .