West Midlands Police said they faced charges including preparing to travel to Syria to engage in terrorism and helping others to travel.
The five, all from Walsall in the West Midlands, are expected to appear at Westminster Magistrates' Court.
Three of the group were arrested last week while the others were originally held in February.
Those charged are Alex Nash, 21, and his wife Yousma Jan, 20, of Bentley Road, and Ayman Shaukat, 27, of Pargetter Street, who were arrested on 9 June.
Lorna Moore, 34, of Glebe Street, and Kerry Thomason, 23, of an undisclosed address, were detained in February before being released on bail.
Two men and three women accused of Syria-related terrorism offences are due to appear at a London court later.