what is the importance of calculating the change in free energy (δg) explain
Gibbs free energy A quantitative measure of the favorability of a given reaction at constant temperature and pressure is the change ΔG (sometimes written "delta G" or "dG") in Gibbs free energy that is (or would be) caused by the reaction. As a necessary condition for the reaction to occur at constant temperature and pressure, ΔG must be smaller than the non-PV (e.g. electrical) work, which is often equal to zero (hence ΔG must be negative). ΔG equals the maximum amount of non-PV work that can be performed as a result of the chemical reaction for the case of reversible process. If the analysis indicated a positive ΔG for the reaction, then energy — in the form of electrical or other non-PV work — would have to be added to the reacting system for ΔG to be smaller than the non-PV work and make it possible for the reaction to occur.[4]:298–299
Van der Waals equation is the volume of the container occupied by each particle (not the velocity of a particle), and k is the Boltzmann constant. It introduces two new parameters: a', a measure of the average attraction between particles, and b', the volume excluded from v by one particle.
Rate equation k is the first order rate constant, which has units of 1/s or sâˆ’1.
Algorithm As an effective method, an algorithm can be expressed within a finite amount of space and time[1] and in a well-defined formal language[2] for calculating a function.[3] Starting from an initial state and initial input (perhaps empty),[4] the instructions describe a computation that, when executed, proceeds through a finite[5] number of well-defined successive states, eventually producing "output"[6] and terminating at a final ending state. The transition from one state to the next is not necessarily deterministic; some algorithms, known as randomized algorithms, incorporate random input.[7]