what is meant by positive and negative deviation from raoult law
Raoult's law Comparing measured vapor pressures to predicted values from Raoult's law provides information about the true relative strength of intermolecular forces. If the vapor pressure is less than predicted (a negative deviation), fewer molecules of each component than expected have left the solution in the presence of the other component, indicating that the forces between unlike molecules are stronger. The converse is true for positive deviations.
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Standard deviation Let X be a random variable with mean value Î¼:
Standard deviation This means that the standard deviation is equal to the square root of the difference between the average of the squares of the values and the square of the average value. See computational formula for the variance for proof, and for an analogous result for the sample standard deviation.