AbstractIntroductionDetrended fluctuation analysis (DFA) is a well‐established method to evaluate scaling indices of time series, which categorize the dynamics of complex systems. In the literature, DFA has been used to study the fluctuations of reaction timeY(n) time series, wherenis the trial number.MethodsHerein we propose treating each reaction time as a duration time that changes the representation from operational (trial number) timento event (temporal) timet, orX(t). The DFA algorithm was then applied to theX(t) time series to evaluate scaling indices. The dataset analyzed is based on a Go–NoGo shooting task that was performed by 30 participants under low and high time‐stress conditions in each of six repeated sessions over a 3‐week period.ResultsThis new perspective leads to quantitatively better results in (1) differentiating scaling indices between low versus high time‐stress conditions and (2) predicting task performance outcomes.ConclusionWe show that by changing from operational time to event time, the DFA allows discrimination of time‐stress conditions and predicts performance outcomes.