The shape of superelastic Nickel-Titanium (NiTi) archwires can be adjusted with thermal treatments using devices such as the Memory-MakerTM(Forestadent), which potentially affects their mechanical properties. The effect of such treatments on these mechanical properties was simulated by means of a laboratory furnace. Fourteen commercially available NiTi wires (0.018″ × 0.025″) were selected from the manufacturers American Orthodontics, Dentaurum, Forestadent, GAC, Ormco, Rocky Mountain Orthodontics and 3M Unitek. Specimens were heat treated using different combinations of annealing duration (1/5/10 min) and annealing temperature (250–800 °C) and investigated using angle measurements and three-point bending tests. Complete shape adaptation was found at distinct annealing durations/temperatures for each wire ranging between ~650–750 °C (1 min), ~550–700 °C (5 min) and ~450–650 °C (10 min), followed by a loss of superelastic properties shortly afterwards at ~750 °C (1 min), ~600–650 °C (5 min) and ~550–600 °C (10 min). Wire-specific working ranges (complete shaping without loss of superelasticity) were defined and a numerical score (e.g., stable forces) was developed for the three-point bending test. Overall, the wires Titanol Superelastic (Forestadent), Tensic (Dentaurum), FLI CuNiTi27(Rocky Mountain Orthodontics) and Nitinol Classic (3M Unitek) proved to be the most user-friendly. Thermal shape adjustment requires wire-specific working ranges to allow complete shape acceptance and high scores in bending test performance to ensure permanence of the superelastic behaviour.