The construction industry is facing increased demand for adopting sustainable ‘green’ building materials to minimise the carbon footprint of the infrastructure sector to meet the United Nations 2030 Sustainability Goals. Natural bio-composite materials such as timber and bamboo have been widely used in construction for centuries. Hemp has also been used in different forms in the construction sector for decades for its thermal and acoustic insulation capability owing to its moisture buffering capacity and thermal conductivity. The current research aims to explore the possible application of hydrophilic hemp shives for assisting the internal curing of concrete materials as a biodegradable alternative to currently used chemical products. The properties of hemp have been assessed based on their water absorption and desorption properties associated with their characteristic sizes. It was observed that, in addition to its excellent moisture absorption capacity, hemp released most of its absorbed moisture into the surroundings under a high relative humidity (>93%); the best outcome was observed for smaller hemp particles (<2.36 mm). Furthermore, when compared to typical internal curing agents such as lightweight aggregates, hemp showed a similar behaviour in releasing its absorbed moisture to the surroundings indicating its potential application as a natural internal curing agent for concrete materials. An estimate of the volume of hemp shives required to provide a similar curing response to traditional internal curing techniques has been proposed.