Indoor environment quality is currently a hot research topic. In this study, composite air filter materials were synthesized using different impregnated porous medium materials, and their filtration performance and structural parameters were analyzed. The results showed that composite filter materials’ structures changed at the fibers’ surfaces when synthesized using different porous medium material layers. The filtration efficiency of composite filter materials synthesized using different porous media reached a maximum 0.8 m/s filtration velocity, and PM10, PM2.5, and PM1.0increased by 1.67~26.07, 1.19~26.96, and 1.10~21.98%, respectively. The filtration efficiencies of reduced graphene oxide composite for PM10, PM2.5, and PM1.0were 21.26, 20.22, and 18.50% higher, respectively, than those of carbon black composite. In addition, the filtration efficiency of the composite material synthesized by reducing graphene oxide improved for 0 to 1.0 μm particulates and was more effective by comparison. Filtration efficiency and resistance were comprehensively considered during air filter use to provide useful values for the selection and preparation of composite filter materials in the future.