The strong wind pre-cooling (SWPC), ice water pre-cooling (IWPC), vacuum pre-cooling (VPC), natural convection pre-cooling (NCPC), and slurry ice pre-cooling (SIPC) techniques were used to pre-cool the fresh sweet corn (Zea maysL.), and then the pre-cooling treated sweet corn samples were stored at 4 °C for 28 days. During refrigeration, quality indicators, such as hardness, water loss, color, soluble solids content, and soluble sugar, were determined. In addition, oxidation indicators, such as peroxidase, catalase, ascorbic acid-peroxidase activity, and carotene content, were also measured. The results showed that the main problems of sweet corn during cold storage were water loss and respiration. The pre-cooling speed of SWPC is the fastest, and the latent heat of sweet corn can be removed in only 31 min. SWPC and IWPC could reduce the loss of fruit quality, maintain good color and hardness, inhibit the decrease of water, soluble solids, soluble sugars, and carotenoid contents, maintain balance between POD, APX, and CAT, and extend the shelf life of sweet corn. The shelf life of SWPC and IWPC corn reached 28 days, 14 days longer than SIPC and VPC treated samples, and 7 days longer than NCPC treated samples. Therefore, SWPC and IWPC are the appropriate methods to pre-cool the sweet corn before cold storage.