Barite sulfate (BaSO4) is considered a very important mineral material employed as a weighting agent for all types of drilling fluids. Meanwhile, crushers used for the grinding step during barite crushing are affected by catastrophic wear damage located in the hammer parts made from high chromium white cast iron (HCWCI). In the present study, a comparison of the tribological performance between HCWCI and heat-treated steel AISI P20 was conducted to investigate the possible substitution of HCWCI. The tribological test was performed under normal loads between 5 and 10 N for different durations (60, 120, 180, and 240 min). The wear response analysis for both materials showed that the friction coefficient increases as the applied load increases. Moreover, AISI P20 presented the lowest value compared to that attributed to HCWCI in all conditions. Furthermore, the analysis of the wear track obtained by means of scanning electron microscopy (SEM) revealed that the damage was an abrasive wear phenomenon for HCWCI with detection of a crack network throughout the carbide phase, which was more pronounced under the highest load. Regarding AISI P20, an abrasive wear mechanism was detected, characterized by several grooves and ploughing phenomena. Further, the analysis of the wear track using 2D profilometry revealed that for both loads, the maximum wear depth of the HCWCI wear track was significantly greater than that of AISI P20. As a result, when compared to HCWCI, AISI P20 exhibits the best wear resistance. Furthermore, as the load increases, the wear depth and the worn area increase as well. Also, the wear rate analysis supports the previous findings, which showed that under both loads, AISI P20 was more robust than HCWCI.