Polymer flooding has drawn more and more attention in the world for its high incremental oil recovery factor and relative low costs compared with water flooding and other chemically enhanced oil recovery techniques. However, for many oilfields, such as Daqing Oilfield, China, that have already been flooded with polymers, how to further improve recovery remains a big problem. Traditional intralayer, interlayer and plane heterogeneity studies cannot accurately characterize the remaining oil distribution after polymer flooding. To solve this problem, we established a method to quantitatively describe the reservoir’s architecture. Then, the architecture elements were dissected hierarchically and the interface of each architecture level in Daqing Oilfield was identified. The distribution pattern and development potential of the remaining oil after polymer flooding under the influence of reservoir architecture was analyzed. The results show that, regarding the sedimentary process from north to south in Daqing Oilfield, the channel becomes narrower, the thickness decreases, the point bar’s width increases and the thickness of the meandering river decreases. The braided bar scale becomes larger and the thickness becomes smaller in the braided river. According to the reservoir’s architecture, the remaining oil was divided into four categories of plane remaining oil (abandoned channel occlusion type, interfluvial sand body occlusion type, inter-well retention type and well pattern uncontrollable type) and three types of vertical remaining oil (in-layer interlayer occlusion type, rhythm type and gravity type). About 40% of the original oil in place (OOIP) of Daqing Oilfield has not yet been produced, which indicates that there is great potential for development. This study is important for improving oil recovery in polymer-flooded reservoirs.