AbstractMechanical sensors execute multi‐mode response to external force, which are cornerstones for applications in human–machine interactions and smart wearable equipments. Nevertheless, an integrated sensor responding to mechanical stimulation variables and providing the information of the corresponding signals, as velocity, direction, and stress distribution, remains a challenge. Herein, a Nafion@Ag@ZnS/polydimethylsiloxanes (PDMS) composite sensor is explored, which realizes the description of mechanical action via optics and electronics signals simultaneously. Combined with the mechano‐luminescence (ML) originated from ZnS/PDMS and the flexoelectric‐like effect of Nafion@Ag, the corresponding explored sensor achieves the detection of magnitude, direction, velocity, mode of mechanical stimulation, and the visualization of the stress distribution. Moreover, the outstanding cyclic stability, linearity response character, and rapid response time are demonstrated. Accordingly, the intelligent recognition and manipulation of a target are realized, which indicate a smarter human–machine interface sensing applied for wearable devices and mechanical arms can be expected.