The Vehicular ad-Hoc Network (VANET) is envisioned to ensure wireless transmission with ultra-high reliability. In the presence of fading and mobility of vehicles, error-free information between Vehicle to Vehicle (V2V) and Vehicle to Infrastructure (V2I) requires extensive investigation. The current literature lacks in designing an ultra-reliable comprehensive tractable model for VANET using millimeter wave. Ultra-reliable communication is needed to support autonomous vehicular communication. This article aims to provide a comprehensive tractable model for VANET over millimeter waves using Space-Time-Block-Coding (STBC) concatenated with Reed Solomon (RS) coding. The designed model provides the fastest way of designing and analyzing VANET networks on 60 GHz. By using the derived BER expressions and Reed Solomon coded doppler expression ultra-reliable vehicular networks can be build meeting the demands of massive growing volume of traffic. The performance of the model is compared with previous BER computational techniques and existing VANET communication systems,i.e., IEEE 802.11bd and 3rd generation partnership project vehicle to everything (3GPP V2X). The findings show that our proposed approach outperforms IEEE 802.11bd and the results are comparable with V2X NR. Packet Error Rate (PER), Packet Reception Ratio (PRR) and throughput are used as performance metrics. We have also evaluated the model on higher velocities of vehicles. Further, the simulation and numerical findings show that the proposed system surpass the existing BER results comprising of various modulation and coding techniques. The simulation results are verified by the numerical results there-by, showing the accuracy of our derived expressions.