In this study,Clitoria ternatea(CT) was incorporated into the structure of sodium montmorillonite (Na+-MMT), then these new nanoparticles (CT-MMT) were added to sol-gel-based hybrid silanol coatings (SGC). The results of the CT-MMT investigation using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscope (TEM) confirmed the presence of CT in the structure. The results of polarization and electrochemical impedance spectroscopy (EIS) tests showed that the presence of CT-MMT in the matrix improves corrosion resistance. The EIS results showed that the coating resistance (Rf) of the sample containing 3 wt.% CT-MMT after immersion was 687 Ω·cm2, while this value was 218 Ω·cm2for pure coating. CT and MMT compounds improve corrosion resistance by blocking anodic and cathodic regions, respectively. Additionally, the presence of CT in the structure created antimicrobial properties. CT contains phenolic compounds that have the ability to suppress by membrane perturbation, reduction of host ligands adhesion, and neutralizing bacterial toxins. Therefore, CT-MMT showed inhibitory effects and killing ofStaphylococcus aureus(gram-positive bacteria) andSalmonella paratyphi-A serotype(gram-negative bacteria), and also improved corrosion resistance.