In computational photography, high dynamic range (HDR) imaging refers to the family of techniques used to recover a wider range of intensity values compared to the limited range provided by standard sensors. Classical techniques consist of acquiring a scene-varying exposure to compensate for saturated and underexposed regions, followed by a non-linear compression of intensity values called tone mapping. Recently, there has been a growing interest in estimating HDR images from a single exposure. Some methods exploit data-driven models trained to estimate values outside the camera’s visible intensity levels. Others make use of polarimetric cameras to reconstruct HDR information without exposure bracketing. In this paper, we present a novel HDR reconstruction method that employs a single PFA (polarimetric filter array) camera with an additional external polarizer to increase the scene’s dynamic range across the acquired channels and to mimic different exposures. Our contribution consists of a pipeline that effectively combines standard HDR algorithms based on bracketing and data-driven solutions designed to work with polarimetric images. In this regard, we present a novel CNN (convolutional neural network) model that exploits the underlying mosaiced pattern of the PFA in combination with the external polarizer to estimate the original scene properties, and a second model designed to further improve the final tone mapping step. The combination of such techniques enables us to take advantage of the light attenuation given by the filters while producing an accurate reconstruction. We present an extensive experimental section in which we validate the proposed method on both synthetic and real-world datasets specifically acquired for the task. Quantitative and qualitative results show the effectiveness of the approach when compared to state-of-the-art methods. In particular, our technique exhibits a PSNR (peak signal-to-noise ratio) on the whole test set equal to 23 dB, which is18%better with respect to the second-best alternative.