Fe-based sulfides are a promising type of anode material for sodium-ion batteries (SIBs) due to their high theoretical capacities and affordability. However, these materials often suffer from issues such as capacity deterioration and poor conductivity during practical application. To address these challenges, an N-doped Fe7S8anode with an N, S co-doped porous carbon framework (PPF-800) was synthesized using a template-assisted method. When serving as an anode for SIBs, it delivers a robust and ultrafast sodium storage performance, with a discharge capacity of 489 mAh g−1after 500 cycles at 5 A g−1and 371 mAh g−1after 1000 cycles at 30 A g−1in the ether-based electrolyte. This impressive performance is attributed to the combined influence of heteroatomic doping and adjustable interface engineering. The N, S co-doped carbon framework embedded with Fe7S8nanoparticles effectively addresses the issues of volumetric expansion, reduces the impact of sodium polysulfides, improves intrinsic conductivity, and stimulates the dominant pseudocapacitive contribution (90.3% at 2 mV s−1). Moreover, the formation of a stable solid electrolyte interface (SEI) film by the effect of uniform pore structure in ether-based electrolyte produces a lower transfer resistance during the charge–discharge process, thereby boosting the rate performance of the electrode material. This work expands a facile strategy to optimize the electrochemical performance of other metal sulfides.