Kollum: "Winsemius" | Omrop Fryslân\n31 maaie 2017 - 08:43\n"In pear moanne lyn hie ik al foarsein dat Arno Brok der as kommissaris foar soargje sil dat der allerhande ferneamde lju nei Fryslân ta komme sille. De Paus is noch net bekaam fan Trump, dat duorret noch efkes. Ik wik jim dat kening Willem-Alexander hjir fan ’t jier noch komt. Dan moat hy wol wat aveseare, want yn novimber komt Sinteklaas al nei Dokkum. Dokkum sit mei syn ferline yn 'e tizen. Yn 754 ha se dêr nammentlik de hillige Bonifatius deakneppele. En se wolle dat no goed meitsje mei it wolkom hjitten fan in oare hillige, út namme fan alle bern fan Nederlân. It hat wol kans dat de Bonifatiusbron dêre dan ek omdoopt wurde sil ta Swarte-Pite-Plaske. Leve het duo Blok-Brok.\nEn dochs hiene we Arno Brok net ha moatten. Ja, it is in poerbêste man. Mar ferline wike hâlde hjir in oaren in ferhaal dat sta sei. Wat binne wy kloaten. Dat ferhaal toande oan dat we hím ha moatten hiene. Fansels, Pieter Winsemius. De meast on-VVD-eftige VVD-er. As Rutte en Zijlstra ris wat mear nei him harke hiene, dan hienen se Klaver yn de earms sletten en wienen oerrûn nei GrienLinks. Sa’n man is dy Winsemius.\nHy hâlde de Rede van Fryslân. Dêr is Fryslân mei de iepening fan it nije provinsjehûs yn 2012 mei begûn. Immen in oerke sa mar wat lulle litte. Teulings fan it CPB wie de earste. Fryslân seach der o sa moai út en dat moast mar sa bliuwe. Wientjes, de meast VVD-eftige VVD-er, hie gjin oplossing foar ús sosjale problemen. Gerdi Verbeet fertelde in jier letter dat Fryslân bestjoerlik in ûnderdiel fan Nederlân is. Dernei spruts de sjoernalist Olaf Koens; in beskamsum ferhaal, benammen oer himsels. En ferline jier wie hjir in Carlos de Bourbon dy’t fertelde dat we útkoarre promtabak wer brûke kinne, as it wat bedrûge is. Hy neamde soks sirkulêre ekonomy.\nMar no, Winsemius. En Winsemius hie ’t oer ús. Hy hâldt fan ús, der sit ek noch wol wat Frysk yn syn famylje. Mar hy prate net oer himsels. Hy prate oer ús bestjoerders, dy’t fierstente min mei ús prate. En as se it wol dogge dan harkje se net nei wat wy sizze. As se dat no, lykas eartiids, wol wer dwaan soenen, soe it wurd mienskip echt wer betsjutting krije kinne. Mar it moaiste wat hy sei wie, en dat die hy twa dagen earder ek al foar de lanlike radio, dat Fryslân noch de iennige mienskip is weryn't de mienskipssin wer stal krije kinne soe. En sjoch dan nei it ferhaal fan mienskipskenner Klaas Sietse Spoelstra, moandei yn de Ljouwerter Krante, dat it Kulturele Haadstêd gedoch eins de boaiem wêze moat foar de wei nei in iepen mienskip yn 2030. Dan wit je dat de bestjoerders, en wy ek, no daliks oan de slach moatte.\nNo ha ik inkeld noch mar wat ôfstanliks sein. Ik fertaal. Jim kenne dat ferhaal fan dat âlde lampehúske op it dykseintsje fan de Lemster Fjoertoerwei. Gemeentebestjoerders woene dat ôfbrekke. In pear dagen letter stie hiel De Lemmer al op dy dyk te sjongen fan bliuw mei de poaten fan ús rommel ôf. De gemeente gie fansels wol omlizzen, mar it blykt dat sokke bestjoerders noait ris troch De Lemmer kuiere, en dan prate mei of harkje nei minsken. Dy gemeente hâldt him no dwaande mei it útjaan fan biobakjes en fia de mail te melden dat as dat it dekseltsje kapot giet, en dat gean se allegear, dat je dan fanút Bakhuzen nei De Jouwer moatte om in nij dekseltsje. Begryp jim it ferskil?\nPrate en harkje. We binne it ferleard yn dit lân. Deasonde. Mar dan komt Pieter Winsemius en dy leit op in gewoane toan út dat fanwege de folksaard en de noch net alhiel fertutearze struktuer it inkel noch yn Fryslân kinne soe. En wat dogge we dan, we litte him gewoan wer nei hûs ride. Mar we hienen him op de skouders nimme moatten en yn triomftocht troch Fryslân ferfiere moatten as in soart krusing fan Marijke Meu, Grutte Pier en Pieter Jelles Troelstra. Mar nee, elk gie gewoan wer syn eigen paad. En dat rint nei in lân sûnder mienskipsgefoel."\nEnkête oer ynfolling fan nij swimbad yn Drachten\nHarm Zeinstra net langer keeper fan Cambuur


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American Idol Concert Tour Stops at Nearby Gwinnett Arena - Entertainment - Kennesaw, GA Patch\nAmerican Idol Concert Tour Stops at Nearby Gwinnett Arena\nThe tour stops in the metro Atlanta entertainment venue on August 4. Tickets go on sale May 3.\nThe tour gives fans the unique opportunity to see Season 12 finalists: Amber Holcomb, Angie Miller, Burnell Taylor, Candice Glover, Curtis Finch Jr, Devin Velez, Janelle Arthur, Kree Harrison, Lazaro Arbos, and Paul Jolley.\n(For the latest tour and ticketing information visit:americanidol.com/tour. Event time and date are subject to change.)


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Pope | Joann Nelander Studio\nPosted in: Uncategorized.\tTagged: Catholic, Christian, God, Pope, Pope's intentions, prayer, Religion, video.\tLeave a comment\nPosted by Be Holy on November 8, 2014


Strike the Blood – 02 – RABUJOI – An Anime Blog\nAuthor rabujoistaffPosted on Sun, 13 Oct 2013 Mon, 14 Oct 2013 Categories Anime Reviews, Fall 2013, Strike the BloodTags akatsuki kojou, akatsuki nagisa, astarte, fourth primogenitor, himeragi yukina, home depot, lion king organization, minamiya natsuki, rudolf eustach, sword shaman, vampire\nOne thought on “Strike the Blood – 02”\nSat, 19 Oct 2013 at 18:59\nThis episode was a nice watch, a little bit of relaxed comedy with some more intense fighting at the end. Too early to say how it’ll all go but I’m enjoying it so far and I’m looking forward to the rest.\nPrevious Previous post: Kyousougiga – 01\nNext Next post: Yozakura Quartet: Hana no Uta – 02


Microsoft Dynamics Sure Step Online – Content Updates – AXPulse\nMicrosoft Dynamics Sure Step Online – Content Updates\nHome Blog Microsoft Dynamics Sure Step Online – Content Updates\nJuly 1, 2013 Imran Mahmood\nMicrosoft Dynamics AX 2012Microsoft Dynamics Sure Step0\nMicrosoft has released a set of updated implementation content for Microsoft Dynamics Sure Step Online. Besides the updates for other Dynamics products, it has updated business process flow Visio files to reflect AX 2012.\nYou can get more information from https://mbs.microsoft.com/partnersource/partneressentials/serviceplans/surestep/.


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Enjoyed stay at Funny farm - Review of Funny Farm Hotel, Interlaken, Switzerland - TripAdvisor\nEnjoyed stay at Funny farm - Funny Farm Hotel\nEurope Switzerland Canton of Bern Bernese Oberland Interlaken Interlaken Specialty Lodging Hostels in Interlaken Funny Farm Hotel\nLevel 2 Contributor 8 reviews 3 helpful votes “Decent hostel not very busy”\nThis review is the subjective opinion of a TripAdvisor member and not of TripAdvisor LLC. Gopalakrishnan H\n37 helpful votes “good option for low budget”\n#1 of 3 in Matten bei Interlaken 333 reviews\n#19 of 46 in Interlaken 128 reviews\nTripAdvisor is proud to partner with Booking.com, HostelWorld, Priceline and Agoda so you can book your Funny Farm Hotel reservations with confidence. We help millions of travelers each month to find the perfect hotel for both vacation and business trips, always with the best discounts and special offers.\nExplore similar hotels Waldhotel Unspunnen54 ReviewsShow Prices 0.6 miles Hotel de la Paix173 ReviewsShow Prices 0.5 miles Hotel Beausite667 ReviewsShow Prices 0.9 miles See all Interlaken hotels Browse nearby


Snitsers pakt nei fernielings | Omrop Fryslân (advertinsje)\nSnitsers pakt nei fernielings 12 sep 2010 - 14:43\n0 reaksjes De plysje hat yn de nacht fan sneon op snein fjouwer manlju oanhâlden op fertinking fan fandalisme. In tsjûge melde de plysje sneintemoarn betiid dat er seach dat de manlju autoruten fernielden. Mei help fan oanwizings fan de tsjûge koene de manlju justjes letter oanhâlden wurde. It gie om trije Snitsers fan 16, 21 en 22 jier en om in man út Balk fan 23 jier. De manlju waarden oerbrocht nei it plysjeburo en ynsletten foar neier ûndersyk.\nKorreksje meldeTrefwurden: argyfLês foarView the discussion thread.Diel dit berjocht op: 12-09Brûns Llargues op EK keatsen 12-09Winst en kopposysje Cambuur Besjoch ek...


10-dingen dy't jo witte wolle oer R, Python, en Hadoop | ITS\n10-dingen dy't jo witte wolle oer R, Python, en Hadoop\n10-redenen moatte jo R, Python, en Hadoop leare\nInformatie Analytics Domain houdt over uw beoordelingen op Software als Service, of SaaS-organisieën, zoals we zien geweldig. Eltsenien moat ynbrekke Big Data en se hawwe in ton fan iepenings foar wurk op 'e opstân. Lykwols, it meitsjen fan nei foaren yn Data Sciences is basysk om te begripen wat it is en wat de Data Science Certification op set. Dit is it plak R, Python en Hadoop Kom yn en hjir binne tsien grutte motivaasjes om se te kennen. Dizze binne yn essinsjele programma-dialekten dy't leard wurde om te brekken yn 'e yndieling fan wittenskippen, wêrby't beatnammen lykas Google, Bank of America en The New York Times befetsje.\nTagonklikheid:Hoe wurdt in oare klant ferwachte dat se leare? R, bygelyks, kin tagelyk ynlade en útfiere en dat jout de kliïnt de autonomy om te sitten en te finen oer elkoar. Python, dan wer, is minder ferlet fan te learen en guon sizze dat it it maklikste is fan programming-dialekten. Hadoop, is ien kear tagelyk, tagonklik op iepen boarnesystemen, wêrtroch it maklik tagonklik makket. Yn oanmerking fan jo akkommodaasje kin de kliïnt ien fan harren brûke. Ienfâldich\nUpgrades: Wat de ynformaasjeûndersyk oanbelanget, binne dizze trije open-source programmierdialekten de meast haadstream. Ynformaasjebewenning, MapReduce en Parallel Processing kinne it bêste mei har opnommen wurde, as in neikommende effekt dêr't de yntegreare ûndersyksstasjon kontinulearre werynrjocht wurde moat, wat wer minder ferlet is fan har.\nCross Platform: De programmierdialekten kinne allegear brûkt wurde oer ferskillende stasjons, lykas Windows, Mac OS X, Linux en in pear fan 'e mear, wêrmei de kliïnten har wurk op elk gadjet ferfolje kinne. R en Python-ûntwerpers tinke no op oanwêzigen om gruttere ynformaasjegrutte yn 'e grins oer gruttere stappen te beheinen en in skot op sawol SQL- en NoSQL-databases te nimmen.\nUnfoarspelberheid makke maklik: Dizze trije programmierdialekten wurde brûkt foar soarch foar grutte en komplekse ynformaasje, ek wol Big Data neamd. Swierder en komplekse rekreaasjes moatte mooglik wêze yn relatyf ienfâldigens troch it brûken fan dy dialekten, yn elite groepen of mei in soad prosesjes. Python peruses ynformaasje oer it each op R, mar beide besjogge goed mei Hadoop, de kliïnten de kar te meitsjen fan ôfhinklikens fan ferskillende komponinten om te selektearjen wêr't men mei kin.\nAwesome Acceptability: Mei sa'n grut oantal foardielen binne de dialekten oer de board erkenning ferhege en om 2 miljoen kliïnten brûke se wrâldwiid by it behearen fan de ynformaasjewittenskip. Fanôf no is R oer it bestjoer ferheven mei Oracle, SAP, Netezza en Teredata hawwe begon makke om ynterfaces te meitsjen dy't utilisaasjes R as wittenskiplike stipe hawwe.\nMeasireare foardielen: Elke nije ferbetterings fan programmearring werynrjochting rinne foldwaande yn ien fan dizze trije dialekten, omdat se de meast ûntwikkele en oanpasber binne. Mei nije foardielen lykas ff en bigmemory, is it tinkbyldberik dat de datasetten grutter binne as it ûnthâld. Python peruses ynformaasje in protte effektiver en syngronisaasje mei Hadoop is in bysûndere belibjen.\nEinfalt fan it publisearjen: Sûnt de programmearringskealen binne goed ynsetten mei rekkenferdieling, se binne de toplist fan 'e distributer. Smoarige oplossing mei LaTeX-rakontearren fan it kader en it bestân fan it ynstallearjen yn wurdearring rapporten is in gigantysk neist it punt. Elke ien fan 'e dialekten hat heule substansjele biologyske systemen, wêrtroch it makliker is om wiidweidige dielen fan ynformaasje te ferwurkjen en te behanneljen.\nMaklik te brûken: R, Hadoop en Python binne maklik te begripen en ûnderpins it ymportearjen fan ynformaasje fan Microsoft Excel, Access, MySQL, SQLite en Oracle, wêr't elke client mei elk produkt tagong makket om sûnder hinderjen te wurkjen. Python is súksesfol brûkt foar natuerlike taalferwurking en Apache Spark hat de ynformaasje fûn makke Hadoop bûnten effektiver iepen.\nOrganisearje: Mienskiplike ferbiningen en bestjoeringsbehearen is in ymperatyfpart fan alle wrâldferienigingsferienings en entûsjaste kliïnten stean kontinuze oer struktueren om oer dizze dialekten mear as wat oars te praten, en garandearje in konsekwint handel fan positive gegevens. De lêsten dy't Anaconda lien hawwe, hat mear as 300 of mear bundels dy't raversûndersiken fan kliïnten wrâldwiid yn har diskusje sammele hawwe, har op te meitsjen foar takomstige bondels.\nSimple Debugging: Scannen en ûndersyksjen is minder fermindere mei dizze dialekten as oaren yn ljocht fan it feit dat de measte troubleshooting apparaten yn konsekwins mei dizze dialekten binne, wêrtroch kliïnten de ideeën fan ideaal mei mear opmerklikens te setten. Elk dialekt hat syn eigen bepaalde foardielen en neidielen, mar men kin dat sizze R, Python en Hadoop Arranzjeminten binne en kinne ferwachte wurde brûke om jo kaders safolle te hâlden en it bêste alternatyf yn it barren dat jo nedich hawwe foar in folsleine kaderûntwikkeling.\nPython Training Guide foar Beginners\nHoe kinne in karriêre begjinne mei grutte data en Hadoop sertifikaasje trening


Un sujet brûlant | 11:11 Les Anges 1111\nOregon, USA, le 8 mai 2021.\nSujet : « Un sujet brûlant ».\n[Jésus] s’interrompait rarement pour corriger des malentendus ou pour s’offenser d’une présentation erronée des faits. [LU, 141:7.12]


Begryp de nije fariant fan Covid-19 -omicron: Pas op foar de grutte sensasjonele media! – JucelinoLuz\nBegryp de nije fariant fan Covid-19 -omicron: Pas op foar de grutte sensasjonele media!\nPublicado porJUCELINO NOBREGA DA LUZ 1 de dezembro de 2021 Publicado emSem categoria\n“It ienige firus dat deadet is ferkearde ynformaasje …”\nLiegt immen tsjin de wrâldbefolking?\nÁguas de Lindoia, 25 novimber 2021\nDe dreamen litte sjen dat dizze seldsume nije stam net bestiet, en it kin net heul oerdraachber wurde, om’t it in heech oantal mutaasjes hat, tagelyk, de oare kant toant grutte fertinking (oanwizings) fan it brûken fan dizze nije welle, om minsken twinge om te faksinearjen – wat se it meast wolle is om net-sykte minsken te faksinearjen – generearre in grutte frjemdens yn ‘e operante modus – lykas per de brief skreaun yn 2020, dy’t wy hjirûnder sille sjen litte. De B.1.1.529-fariant fan it coronavirus, dy’t nuver ûntdutsen waard troch Súdafrikaanske ûndersikers, komt lykwols op in tiid dat faksinaasjekampanjes tsjin Covid-19 wrâldwiid begûnen te ûntstean, mei grutte protesten en demonstraasjes. mei de minne resultaten, en deaden troch side-effekten dy’t binne waarnommen troch ûnôfhinklike saakkundigen en wittenskippers, dat is, net keppele oan wrâldregearingen en autoriteiten, en komt ek oerien mei de grutte propaganda fan ‘e sensasjonele media fan it begjin fan’ e 5e welle fan ‘e pandemy yn ferskate Europeeske lannen. Amearika en Azië.\nBegryp wat wittenskippers al witte oer dizze nije foarm fan it firus … teminsten, wat se sizze – wy respektearje, mar wy leauwe net.\nWêr komt de omicron fariant wei?\n“In geweldich teater organisearre troch guon hearskers en wrâldautoriteiten om jo te dominearjen en jo macht te behâlden! “\nDe offisjele namme fan de nije fariant is B.1.1.529. Mar lykas de oare stammen (alfa, beta of delta), waard it al gau neamd mei in letter fan it Grykske alfabet, en waard sadwaande wrâldwiid bekend, yn mar in pear oeren, as de “omicron” fariant. Wat is de namme brûkt troch autoriteiten en saakkundigen keppele oan wrâld hearskers.\nDer besteane grutte fermoedens dat amtners (in part fan har) oandielhâlders binne fan grutte laboratoaria en dêrom minsken twinge wolle om alles te ynintsjen. 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Rinne as fee om dy eksperimintele, needfaksinen te krijen dy’t gefaarlik binne foar minsken. Minder dan in wike is ferrûn sûnt de fariant waard ûntdutsen, en it fleach troch supersonyske jet en sil fluch ferspriede oer de hiele wrâld! Myn God, genôch hypokrisy? As d’r echt in fariant is, dy’t ik net leau, (oanwizings dat…) wurdt it ferspraat troch minsken dy’t ynhierd binne troch laboratoaria of guon kweade regearingsamtners.\nDe gefallen binne allinich tanommen, om redenen fan unkonstitúsjonele dekreten en wetten dy’t troch har makke binne, dy’t in rappe tanimming mooglik meitsje en ek oare deaden út ferskate histoarjes kinne wurde taskreaun as covid19 – en om ûndersyk te foarkommen, wurde de measte lichems kremearre.\nHjir yn Brazylje is it firus heul yntelligint, slacht karnaval oer, nimt gjin politisy op, of guon autoriteiten, nimt gjin bussen, metro’s en oerfolle treinstasjons, giet net út yn ferkiezings en nimt fekânsje mei Kryst , Nijjier en yn gearkomsten, geheime partijen fan politisy en autoriteiten.(sûnder generalisearjen).\nIk freegje jo freonlik om dizze ynformaasje fluch troch te jaan, te dielen mei freonen, minsken dy’t jo leuk fine en hâlde – om’t se de keppeling altyd blokkearje, of sizze: – “Unfeilige keppeling” om te foarkommen dat it goede minsken berikt. (dyjingen dy’t skea wurde sille). Misdie tsjin it minskdom! It sil ien dei in skandaal wurde!\nSorry foar de faksineare, mar as it oant no ta net wurke hat, wêrom sil it dan yn ‘e heine takomst wurkje – alle autoriteiten hawwe dit al talitten, oan it publyk!\nDit is gjin beskuldiging, mar weardefolle ynformaasje. Wy hawwe gjin politike bannen mei ien en folle minder binne tsjin faksinaasje – salang’t it wirklik foar it goede fan ‘e minskheid is. Wy fernimme dizze geweldige beweging foar it faksin net.\nMei God jo allegearre beskermje en segenje!\nProf. Jucelino Luz – Skriuwer, ûndersiker, miljeukundige, aktivist en geastlike gids\nUnawain ang bagong variant ng Covid-19 -omicron: Mag-ingat sa malaki media sensational!\nTuig an caochladh ùr de Covid-19 – omicron: Bi faiceallach mu na meadhanan mòra a tha a ’faireachdainn!


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Paz perfecta - Comentarios del Screel Lodge, Colvend, Reino Unido - Opiniones en TripAdvisor\nPaz perfecta - Comentarios del Screel Lodge\nOpinión sobre: Screel Lodge\nThank you for your feedback - it is a lovely location with lots of local wildlife on the doorstep\nThank you for your positive feedback about Screel Lodge. We hope to be able to welcome you back in the future .\nEscribió una opinión el 14 de febrero de 2016 para una estancia en septiembre de 2015


Gimme! Gimme! Gimme! (A Man After Midnight) - A*Teens - The ABBA Generation flac mp3 vinyl rip full album\nOrelhão De Avenida - Carlinhos Vergueiro - Contra Corrente, True School Anthem (Street) - J-Live - Them Thats Not / True School Anthem, Valley - Perfume Genius - No Shape, Conjugal Visit - The Waybacks - Loaded, Book And Its Cover - Ill Repute - What Happens Next / Oxnard Land Of No Toilets Valu Pak, Come Prima - Willy Alberti - Come Prima, Santana - Caravanserai, Busta Rhymes - Blackout, Liebesszene - Peter Sandloff - Deutsche Filmkomponisten, Folge 6, Warriors - Jizzm - Illasophic Vol. 1, String Quartet No. 1 (1915): Sixth Movement: Saltando Como Um Saci (Jumping Like A Jumping Bean) -\nGimme! Gimme! (A Man After Midnight) ABBA Buy This Song. FAVORITE (9 fans) ABBA. ABBA was a Swedish pop group formed in Stockholm in , comprising Agnetha Fältskog, Benny Andersson, Björn Ulvaeus and Anni-Frid Lyngstad. ABBA is an acronym of the first letters of the band members' first names and is sometimes stylized as the registered.\nMar 03, · Gimme! Gimme! Gimme! (A Man After Midnight) Artist ABBA; Writers Benny Andersson, Björn Ulvaeus; Licensed to YouTube by UMG (on behalf of Polar Music International AB); UMPI, ASCAP, EMI Music Publishing, UNIAO BRASILEIRA DE EDITORAS DE MUSICA - UBEM, UMPG Publishing, CMRRA, and 18 Music Rights Societies.\nTalk Tonight - Oasis - (Whats The Story) Morning Glory? - Complete Singles Collection\nMashura on Gimme! Gimme! Gimme! (A Man After Midnight) - A*Teens - The ABBA Generation


Praktyske taken en taken foar it tema 7 - Studios\nPraktyske taken en taken op it tema 7\n1. Hoefolle gram fan koper sulfoat CuSO 4 \_ 5H 2 O moat opnommen wurde om 600 g koper (II) sulfate oplossing te meitsjen mei in masse fraksje fan 16%?\n2. Meitsje de molêre konsintraasje fan in oplossing fan chloride sūne mei in mate fraksje fan 30% HCl en in tichtens fan 1.152 g / sm 3 .\n3. Potassiumhydroxide In kwaliteit fan substansje 6 mol waard yn wetter yn 464 g ferljochte. Kies de masse fraksje fan 'e dissolved substance yn' e oplossing.\n4. Oant 400 g natriumhydroxide oplossing mei in matefraksje fan NaOH 20% wurdt opslein yn 300 ml wetter. Kies de masse fraksje fan NaOH yn 'e resultate oplossing.\n5. Hoefolle gram fan chloride-barium BaCl 2 moat wurde om 500 ml fan in oplossing te meitsjen op in konsintraasje fan 0,25 mol / l?\n6. Kalkje de masse fraksje fan de oplossingstof yn in oplossing dy't troch 50 g sûker yn 450 g wetter oplost wurdt.\n7. Ferkearje de masse fraksje fan sâlt yn 'e oplossing dy't troch 60 g sâlt yn 540 g wetter wetterst.\n8. Oan 100 g 30% sûker oplossing wurde 300 g wetter tafoege. Wat is de masse fraksje fan 'e oplossende substans yn' e resultate oplossing?\n9. Kies de massa fan NaNO 3 nedich foar de tarieding fan 300 ml fan in 0,2 M oplossing.\n10. Hoefolle gram fan sodium karbonat is yn 500 ml 0,25 N oplossing befette?\n11. Natuerkarbonat mei waaks 35 g waard oplost yn 400 ml wetter. Kies:\na) normaalheid, b) molariteit, c) de titer fan 'e útfierbere oplossing.\n12. Hoe massa fan natriêre nitrat moatte yn 500 g wetter oplost wurde om 20% fan har oplossing te krijen?\n13. Determine de massa fan wetter wêr 't it nedich is om 120 g katoasulfat te ûntlutsen om in 20% oplossing te krijen.\n14. Meitsje de massa fan 10% en 30% fan 'e sâllefling nedich foar de tarieding fan 300 g fan 15% oplossing.\n15. Berekken molêre en normale konsintraasje fan 35% oplossing fan sulfat sûr, tichtens fan 1,15 g / sm 3 .\n16. Meitsje de masse fraksje fan sâltrochlorides yn in oplossing dy't troch 11,2 liter chloride yn 400 g wetter ûntsteld wurdt.\n17. Om 5% oplossing fan MgSO 4 te krijen , waarden 400 g MgSO 4 ' 7H 2 O rekken. Meitsje de massa fan de oplossing oplossing.\n18. Determine de masse fraksje fan CuSO 4 yn de oplossing troch it oplieden fan 50 g koper sulfoat CuSO 4 '5 H 2 O yn 450 g wetter.\n19. Yn hokker massa fan wetter moatte 25 g CuSO 4 ' 5H 2 O oplost wurde om in 8% oplossing fan CuSO 4 te krijen ?\n20. Hoefolle gram Na 2 SO 4 '10 H 2 O moat yn 800 g wetter oplost wurde om in 10% oplossing fan Na 2 SO 4 te krijen ?\n21. Yn hokker volume fan 0,1 N oplossing befettet 8 g CuSO 4 ?\n22. Oan ien liter fan 20% potassiumhydroxide oplossing mei in tichtens fan 1.186 g / sm 3 hat 2 liter wetter oanbean. Kies: a) it massaaks fan KOH yn 'e resultate oplossing, b) de molariteit, d) normaalheid; e) de titre fan 'e oplossing.\n23. Hoefolle gram fan natriumhydroxide moat tafoege wurde oan 200 ml fan syn 20% oplossing (r = 1,2 g / cm 3 ), sadat de masse fraksje fan natriumhydroxide yn 'e nije oplossing 40% is?\n24. Wat folle wetter moat tafoege wurde oan 100 ml 20% oplossing fan H 2 SO 4\n(r = 1,14 g / sm 3 ) om in 5% oplossing te krijen?\n25 To 1 ml wetter wurde tafoege oan 500 ml 32% HNO 3 (r = 1,20 g / cm 3 ). Besparje de masse fraksje fan HNO 3 yn 'e resultate oplossing.\n26. Kalkulearje de molêre konsintraasje fan de oplossing dy't troch it mingjen fan 400 ml 9 M en 600 ml fan 2 M-oplossing fan sâltwasserstoer\n27. Yn in 45 g wetter ûntstie 6,84 g sûker C 12 H 22 O 11 . Kalkje de molfraksjes fan sûker en wetter.\n28. Wat is de massa fan wetterstof chloride yn 0,25 liter fan 10,52% oplossing fan chloride sūne (r = 1,05 g / sm 3 ).\n29. Kalkje de masse fraksje fan sodium karbonat yn 3.07 N oplossing\n(r = 1,15 g / sm 3 ).\n30. Hokker fermogen fan 6 M oplossing fan chlorideasjinne moat wurde makke om 250 ml fan 0,5 M oplossing te meitsjen?\n1. Ferkearje de osmotyske druk fan 'e oplossing dy't 16 g sucrose C 12 H 22 O 11 yn 350 g wetter op 25 o C jout. De tichtens fan' e oplossing wurdt beskôge as ien.\n2. Nei 100 ml fan in watwinning fan 0,5 M wat fan glucose C 6 H 12 O 6 , 300 ml wetter wurde tafoege. Kies de osmotyske druk fan dizze oplossing by 20 ° C.\n3. By 25 ° C is de osmotyske druk fan wat wiskundige oplossing 1,4 MPa. Kies syn osmotyske druk op 0 ° C.\n4. By 25 ° C is de osmotyske druk fan 'e oplossing dy't 2,80 g hege molekulêre ferbining yn 200 ml oplossing befettet is 0,70 kPa. Besykje it molekulêre gewicht fan 'e compound.\n5. In oplossing fan 100 ml mei 2,30 g stof hawwe in osmotyske druk fan 618,5 kPa by 298 K. Besykje it molekulêre gewicht fan 'e substansje.\n6. Kalkje op 65 ° C de damp druk boppe de oplossing dy't 13,68 g sucrose C 12 H 22 O 11 yn 90 g wetter as de saturearre damp druk boppe it suvere wetter op deselde temperatuer is 25.0 kPa.\n7. By 315 K is de sânduration damp druk boppe it wetter 8,2 kPa. Hoefolle dampendruk sil op deselde temperatuer ôfnimme, as yn 540 g fan wetter 36 g glukose C 6 H 12 O 6 oplost?\n8. By 293 K is de sânduration damp druk boppe it wetter 2,34 kPa. Hoefolle gram fan Glycerol C 3 H 5 (OH) 3 moat yn 180 g wetter oplost wurde om de dampferdediging te ferleegjen troch 133,3 Pa?\n9. Hoefolle graden sille it siedende punt fan wetter stean, as 100 g fan wetter 12 g glukose C 6 H 12 O 6 ûntstean?\n10. Hokker temperatuer sil in oplossing krije mei 10 g sâlt yn 200 g wetter?\n11. By hokker temperatuer sil 40% oplossing fan ethanol C 2 H 5 OH yn wetter kristalisearre wurde?\n12. Hoefolle gram fan ethanol C 2 H 5 OH moat ik oan 500 g wetter oanmeitsje om in oplossing te krijen dy't fiele op -20 ° C?\n13. As it ferlienen fan 13,0 g in net-elektrozyt yn 400 g diethyl ether (C 2 H 5 ) 2 O ( E = 2.02), ferhege de siedende temperatuer om 0,453 K. Determine it molekulêre gewicht fan 'e dissolved substance.\n14. Wakker-alkohollike oplossing mei 15% alkohol (r = 0,97 g / cm 3 ) kristalisearret op -10.26 ° C. Kalkulearje it molekulargewicht fan alkohol en de osmotyske druk fan 'e oplossing by 293 K.\n15. De siedende punt fan 'e wisklike oplossing fan sucrose C 12 H 22 O 11 is 101.4 o C. Meitsje de molêre konsintraasje en de masse fraksje fan saccharose yn oplossing. Op hokker temperatuer frije dizze oplossing frije?\n16. Yn 100 g wetter befetsje 4.57 g sucrose C 12 H 22 O 11 . Kies:\na) osmotyske druk op 293 K; b) it siedpunt fan 'e oplossing; c) de kristallisearjende temperatuer fan 'e oplossing; d) de druk fan 'e sâtteare damp boppe de oplossing by 293 K. De sânduration damp druk boppe it wetter by 293 K is 2.337 kPa. De tichtens fan 'e oplossing wurdt beskôge as ien fan' e identiteiten.\n17. In oplossing besteande út 9,2 g glycerol C 3 H 5 (OH) 3 en 400 g acetone, siede op in temperatuer fan 56,38 ° C. Pure aceton krijt op 56,0 ° C. Kalkje de staphylococcus stiel foar acetone.\n18. Wat is de massa fan naphthalen dat yn 8 kg benzene befettet, as dizze oplossing frije is op 3.45 o C? Temperature fan it frijen fan benzene 5.40 o С.\n19. Om antifreeze te meitsjen foar 30 liter wetter, wurde 9 liter glycerol C 3 H 5 (OH) 3 oernommen . Wat is it frijepunt fan 'e antifrodyske makke? De tichteens fan glycerol is 1,26 g / sm 3 .\n20. Beslute it siedende punt fan 'e oplossing fan 1 g naphthalene C 10 H 8 yn 20 g eter as de siedende punt fan' e eter is 35,60 ° C. De ebullioskopyske konstante foar de ether is 2,02.\n1. De leaverberens fan kalziumkarbonat by 35 ° C is 6,9'10 -5 mol / l. Kies it produkt fan 'e lûkberens fan dizze sâlte.\n2. Ferkearje it produkt fan lebelens PbBr 2 op 25 ° C, as de solubiliteit fan sâlt op dizze temperatuer 1,32'10 -2 mol / liter is.\n3. Om 1,16 g PbJ op te lûken, wurde 2 liter wetter nedich. Kies it produkt fan 'e lûkberens fan dizze sâlte.\n4. Yn in 500 ml wetter mei 18 ° C wurdt 0,0166 g Ag 2 CrO 4 oplost. Kies it produkt fan 'e lûkberens fan dizze sâlte.\n5. Basearre op 'e wearde fan DR fan calcium carbonate (DR = 5'10 -9 ), berekkenje de massa fan CaCO 3 , dy't yn 100 ml fan' e satuïte oplossing befettet.\n6. Meitsje it gewicht fan it argentum yn 'e foarm fan Ionen yn 1 liter AgBr sêftige oplossing (DR = 6'10 -13 ).\n7. sil in sulphat argentum foarkomme, as itselde bedrach fan 0,5 M oplossing fan sulfat sûker wurde tafoege oan de 0,02 M AgNO 3- oplossing? (DR (Ag 2 SO 4 ) = 2'10 -5 ).\n8. Oan 50 ml 0,001 N HCl-oplossing wurde 450 ml fan 0,0001 N fan AgNO 3- oplossing tafoege. Wolle jo dat chloride argentum foarkomme?\n9. Kies de pH fan in 0,01 M NaOH-oplossing; 0.001 M NaOH oplossing.\n10. Ferklearje de pH: a) 10 -3 M oplossing fan chloride acid; b) 0.5-10 -2 M oplossing fan sulfoat sûker.\n11. Ferklearje de pH-wearde en [H + ] as pON = 8; 10; 4. Wat is dizze omjouwing?\n12. Meitsje de pH fan 'e pufferlieding te berikken troch it mingjen fan 50 ml fan in 0,1 M oplossing fan natriumacetat en 50 ml fan in 0,1 M oplossing fan acetate sûr.\n13. Meitsje de pH fan 'e pufferlieding te berikken troch it mingjen fan 100 ml fan in 0,1 M oplossing fan ammoniumchlorid en 100 ml fan in 0,1 M wiskundige ammoniaklêzing\n14. Meitsje de dissociation rate fan C 3 H 7 COOH yn 0,005 M oplossing, as de dissoziation konstante K dis = 1.5 × 10 -5 is .\n15. Meitsje it grûn fan dissisoasje fan cyanid HCN yn 0,01 M oplossing, as har dissoziaasje konstante K dis = 7,9 × 10 -10 .\n16. De mjitte fan dissoziaasje fan formatyas NSOON yn 0,2 n oplossing is 0,03. Kies de dissoziationkonstante fan sâlte.\n17. De mjitte fan dissoziation fan fluorydsoal yn 0.1 n oplossing is 0.08. Kies de dissoziationkonstante fan dizze saure.\n18. Yn 0,1 N oplossing is de mjitte fan dissoziaasje fan acetate sûder 1,32 × 10 -2 . Kies de dissoziationkonstante fan sâlte.\n19. Hokker konsintraasje fan 'e oplossing is de mjitte fan dissidinsje fan acetat sider СH 3 СООН is lyk oan 0,02 ( K dis = 1.8 × 10 -5 )?\n20. Wêr is de oplossingskonzentration, de mjitte fan dissoziaasje fan azteroids wurdt 0,04 ( K- rij = 5.1 × 10 -4 )?\n21. In oplossing mei 2.1 g KOH yn 250 g wetter ferfullet op -0.519 o C. Kalkje de isotonyske koeffizienten en de skynbere dissidence fan dy oplossing.\n22. In oplossing mei 0.53 g sodium karbonat yn 200 g wetter kristallisearret op -0,13 ° C. Kalkje de skynbere middel fan dissoziaasje fan 'e sâlt.\n23. By 0 ° C is de osmotyske druk fan in 0,05 M oplossing fan potassiumkarbonat 272,6 kPa. Kies de imaginêre graad fan dissoziaasje K 2 CO 3 yn oplossing.\n24. De dúdlike dissociaasje fan potassiumchloride yn in 0,1 M oplossing is 0.8. Hokker osmotyske druk sil dizze oplossing meitsje op 17 ° C?\n25. De dúdlike ôfdieling fan nitrogen argentum yn in 0,12 M oplossing is 0,6. Kies de konsintraasje fan I + Ag + i NO 3 - yn mol / l.\n26. Kalkje de hydrolysisgradaasje fan sellen NH 4 Cl I KCN yn har 0,1 M oplossings.\n27. De hydrolysisgraduaasje fan 'e sâlt fan alkalimetaal en monobasine sûker yn in 0,1 M oplossing is 0.0014%. Sykje de hydrolysis konstante foar dit sâltal.\n28. Meitsje de hydrolysisgradaasje fan natriumhypochlorit NaClO yn 0,001 n oplossing op 25 ° C.\n29. Kalkje de gradens fan hydrolyse en pH fan de 0.005 M oplossing fan kaliumsyanide.\n30. Meitsje de konstante fan hydrolyse, de hydrolysisgrad en de pH fan in 0,1 M oplossing fan natriumkarbonat, foarsafier't de hydrolyse allinich op 'e earste faze plakfynt.\nTema 8. Komplekkondoaren\n1. De wichtichste bepalingen fan 'e koördinaasje teory. Koncept oer atom-komplekende agint, ligand, koördinaasje nûmer, dentantnost.\n2. Primêre en sekundêre dissoziation fan komplekse kombinaasjes.\n3. Konstanten fan stabiliteit en ûnstabiliteit fan 'e komplekse ferbining, de ferbining tusken har.\n4. Chimeleande bonding yn komplekse kombinaasjes: de metoade fan valence bonds (VZ), har mooglikheden. Hybridisearjen fan de kanten fan 'e sintrale atom en de romtlike struktuer fan' e kompleksen.\n5. Hylke bonding yn komplekse ferbiningen: de teory fan kristlike fjild (TPP). Energie fan splitsing, hege- en leechdichte kompleksen.\n6. Hylke bondel yn komplekse kombinaasjes: de metoade foar molekulêre orbitalen, har foardielen yn fergeliking mei de metoaden fan VZ en TKP.\n7. Klassifikaasje fan komplekse kombinaasjes: troch type liganden, struktuer, oantal atomen-komplekende aginten.\n8. Nomenklatuer fan komplekse kombinaasjes.\n9. Types fan isomers fan komplekse kombinaasjes.\n10. Spatiale struktuer fan komplekse kombinaasjes. Cis en trans isomers.\nBesykje fragen oer it ûnderwerp\n1. Wat binne de reaksjes foar formaasje komplekse kombinaasjes?\na) neutralisearjen; b) kompleksfoarming; c) it ûntbrekken fan ûntbûn;\nd) formaasje fan in útstel; e) de formaasje fan komplekse stoffen.\n2. Selektearje ûnder de boppesteande reaksjes dyjingen dy't resultaat by de formaasje fan komplekse kombinaasjes:\na) NaOH + H 2 SO 4 = ...; c) SO 3 + H 2 O = ...;\nb) Al (OH) 3 + 3 NaOH = ...; g) AgCl + 2NH 3 = ...\n3. Op hokker faktoaren hinget ôf fan it koördinearjen nûmer fan 'e komplekse formaasje?\na) lade, de grutte fan 'e ion-komplekende agint, de natuer fan' e liganden, de betingsten foar de formaasje fan 'e kompleks;\nb) de lading, de grutte fan 'e ion-komplekende agent, de natuer fan' e liganden;\nc) de lading fan 'e ion-komplekende agint, de natuer fan' e liganden, de betingsten foar it ûntstean fan 'e kompleks;\nd) opslach, de grutte fan 'e komplekse ion, de betingsten foar de formaasje fan in kompleks.\n4. Finalisearje de ferklearring: neffens Werner's teory, it molekule fan 'e komplekse ferbining\nbestiet út ...\na) komplekende aginten en liganden;\nb) ynterne sfear, komplekende aginten en liganden;\nc) it eksterne en ynterne sfear;\nd) eksterne sfear en liganden.\n5. It koördinearjen nûmer is ...\na) tal kompleksere ionen en liganden;\nb) it tal ienen fan 'e komplekende agent;\nc) it oantal liganden;\nd) it tal sitten yn 'e koördinaasje-sphere dy't kin nimme\n6. Selektearje in searje dy't allinich komplekse kombinaasjes befetsje:\na) Al (OH) 3 , H 2 SO 4 , [Ag (NH 3 ) 2 ] Cl;\nb) Na 3 [Al (OH) 6 ], H 2 [PtCl 6 ], [Ag (NH 3 ) 2 ];\nc) Na 3 [Al (OH) 6 ], HClO 4 , [Ag (NH 3 ) 2 ];\ng) Zn (OH) 2 , H 2 [ZnCl 4 ], [Zn (NH 3 ) 4 ] SO 4 .\n7. Troch it ynteraksje dêr't subsydzjes komplekse kombinaasjes foarmje kinne?\na) sûkeroxygen mei basis;\nb) alkalis mei amfotere hydroxides;\nc) sûrden mei bases;\ng) sêgen mei siedoarnen;\ne) sâlt mei sâlt.\n8. Ferklearje de ladingen fan ion-komplekearjende agents yn 'e neikommende komplekse kombinaasjes: [Ag (NH 3 ) 2 ] Cl, Na [Al (OH) 4 ], H 2 [PtCl 6 ]. Yn it antwurd ynfiere jo it bedrach fan lieningen.\na) 4; b) 6; c) 8; g) 10; e) 12.\n9. Ferklearje de ladingen fan ion-komplekende aginten yn 'e neikommende komplekse kombinaasjes: [Cu (NH3) 4 ] SO4, Na3 [Cr (OH) 6 ], K2 [HgI4]. Yn it antwurd ynfiere jo it bedrach fan lieningen.\na) 6; b) 7; c) 8; g) 9; e) 10.\n10. Ferklearje de ladingen fan ion-komplekearjende agents yn de neikommende komplekse kombinaasjes: [Zn (NH3) 4 ] Cl2, Na4 [HfF8], K2 [PtBr6]. Yn it antwurd ynfiere jo it bedrach fan lieningen.\n11. Selektearje de rigel dy't de lykweardigens hat foar de primêre dissoziation fan 'e komplekse kombinaasje:\na) [Cu (NH 3 ) 4 ] Cl 2 = [Cu (NH 3 ) 4 ] 2+ + 2 Cl - ;\nb) [Cu (NH 3 ) 4 ] 2+ = Cu 2+ + 4 NH 3 ;\nc) [Cu (NH3) 4 ] 2+ = [Cu (NH3) 2 ] 2+ + 2NH3;\ng) [Cu (NH 3 ) 4 ] Cl 2 = Cu 2+ + 4NH 3 + 2 Cl - .\n12. Selektearje in snaar mei de lykweardigens foar de sekundêre dissociation fan 'e komplekse kombinaasje\na) [Zn (NH3) 4 ] Cl2 = [Zn (NH3) 4 ] + 2C1 - ;\nb) Na 3 [Al (OH) 6 ] = 3Na + [Al (OH) 6 ] 3- ;\nc) [Ag (NH 3 ) 2 ] + = Ag + 2NH 3 ;\ng) HCO 3 - = H + + CO 3 2- .\n13. Asjebleaft de generike namme fan de neamde komplekse kombinaasjes:\n[Zn (NH3) 4 ] Cl2, [Cu (NH3) 4 ] SO4, [Ag (NH3) 2 ] Cl\na) amine; b) saterde kompositeiten; c) chelaten;\nd) ammoniak; e) karbonyls; e) wetterkompleksjes.\n14. Gebiede de generike namme fan de neamde komplekse kombinaasjes:\nK [Cu (CN) 2 ], Na [BiI4], K2 [PtBr6], Na4 [ZrF8]\na) amine; b) saterde kompositeiten; c) chelaten; d) ammoniak;\ne) karbonyls; e) wetterkompleksjes.\n15. Soarget de generike namme fan de neamde komplekse kombinaasjes:\n[Cr (H 2 O) 6 ] SO 4 , [Al (H 2 O) 6 ] Cl 3 , [Co (H 2 O) 6 ] SO 4\n16. Name de komplekse compound [Co (H 2 O) 6 ] SO 4\na) kobalt (II) sulfate;\nb) tetraacqualobut (II) sulfate;\nc) Hexaamykobalt (II) sulfate;\ng) hexaacqualobut (II) sulfat.\n17. De liganden oanjaan oan 'e soarten komplekse kombinaasjes:\nLiganden: Type kompleks:\n1) wetter molekulen a) sêne kompleks;\n2) ammoniakmolulen b) Aqua kompleks;\n3) anions fan siedende residuen c) ammoniak;\n4) it koper (II) oxid molekul d) chelaas;\n5) anions fan aminokarboxylsoarten d) in amateur;\n18. Name de komplekse kombinaasje K 2 [PtBr 6 ]:\na) potassium platinum (IV) hexabromide;\nb) Kaliumhexabromoplatinate (IV);\nc) dysplasia hexabromoplatin (IV);\nd) potassium platinum (IV) bromate.\n19. Name de komplekse compound [Co (NH 3 ) 3 Cl 3 ]:\na) Trichlorotrimaminokobaltat (III);\nb) cobalt (III) trichlorotriamine;\nd) trichlorotriamine karbaplate.\n20. Yn hokker folchoarder binne liganden opnaam yn 'e namme fan multi-ligand comp\na) neutraal, anionysk, kationaal;\nb) anionyske, kationale, neutrale;\nc) anionisch, neutraal, kationaal;\nd) yn alfabetyske opdracht;\ne) yn opdracht fan ferheging fan tal liganden.\n21. Joujre dat eleminêre soarten ynterpretearre binne yn komplekse kombinaasjes:\na) hydratisearre, ionisaasje, koördinaasje, geometrysk, optysk;\nb) hydratisearre, ligand, koördinaasje, geometrysk, optysk;\nc) hydratisearre, ionisaasje, romtlik, geometrysk, optysk;\nd) hydratisearre, ionisaasje, koördinaasje, spegel, optyske.\n22. Meitsje de formule fan 'e komplekse komponint troch syn namme:\nPotassium dicyanoargentate (I):\na) K 2 [Ag (CN) 2 ]; b) K [Ag (CN) 2 ]; c) [K (CN) 2 ] Ag; g) Ca [Ag (CN) 2 ].\n23. Meitsje in formule fan 'e komplekse komponint troch syn namme:\nHydrogen hexachloroplatinate (IV):\na) H [PtCl 6 ]; b) H 2 [Pt 4 Cl 6 ]; c) Pt 4 [HCl 6 ]; d) H 2 [PtCl 6 ].\n24. Meitsje in formule fan 'e komplekse komponint troch syn namme:\na) [AlBr (H 2 O) 5 ] Cl 3 ; b) [AlBr (H 2 O) 6 ] Cl 3 ;\nc) [AlBr (H2O) 5 ] Cl; g) [Al 5 Br (H 2 O)] Cl 3 .\n22. Finalisearje de ferklearring: Geometrysk isomerisme fan komplekse kombinaasjes\nferbûn mei ...\na) rotaasje fan it fleantúch fan polearing fan ljocht;\nb) de oare lokaasje fan 'e liggen yn' e romte om it sintrale atom;\nc) de oergong fan liganden fan ien kompleksjende agent nei in oar;\ng) de ferskate distribúsje fan ionen yn 'e eksterne en ynterne sfear fan' e komplekse ferbining.\n23. Finalisearje de ferklearring: Ionisearring isomerisme (metamerisme) fan kompleks\nbôge befestige oan ...\nb) de ferskillende ferdieling fan ionen yn 'e eksterne en ynterne sfear fan' e komplekse ferbining;\nc) de ferskate lokaasje fan 'e liganden yn' e romte om it sintrale atom;\ng) de oergong fan liganden fan ien kompleksearjend agent nei in oar.\n24. 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