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New Paradigm for Solar Cell
Construction Demonstrated

by Staff
Science Daily, November 12, 2012



The study was led by professor Andrew M. Rappe and research specialist Ilya Grinberg of the Department of Chemistry in Penn's School of Arts and Sciences, along with chair Peter K. Davies of the Department of Materials Science and Engineering in the School of Engineering and Applied Science, and professor Jonathan E. Spanier, of Drexel's Department of Materials Science and Engineering.

It was published in the journal Nature.


"There's a small category of materials, however, that when you shine light on them, the electron takes off in one particular direction without having to cross from one material to another," Rappe said. "We call this the 'bulk' photovoltaic effect, rather than the 'interface' effect that happens in existing solar cells.

This phenomenon has been known since the 1970s, but we don't make solar cells this way because they have only been demonstrated with ultraviolet light, and most of the energy from the sun is in the visible and infrared spectrum."


"Think of photons coming from the sun as coins raining down on you, with the different frequencies of light being like pennies, nickels, dimes and so on. A quality of your light-absorbing material called its 'bandgap' determines the denominations you can catch," Rappe said. "The Shockley-Queisser limit says that whatever you catch is only as valuable as the lowest denomination your bandgap allows. If you pick a material with a bandgap that can catch dimes, you can catch dimes, quarters and silver dollars, but they'll all only be worth the energy equivalent of 10 cents when you catch them.

"If you set your limit too high, you might get more value per photon but catch fewer photons overall and come out worse than if you picked a lower denomination," he said. "Setting your bandgap to catch only silver dollars is like only being able to catch UV light. Setting it to catch quarters is like moving down into the visible spectrum. Your yield is better even though you're losing most of the energy from the UV you do get."


Starting more than five years ago, the team began theoretical work, plotting the properties of hypothetical new compounds that would have a mix of these traits. Each compound began with a "parent" material that would impart the final material with the polar aspect of the bulk photovoltaic effect. To the parent, a material that would lower the compound's bandgap would be added in different percentages. These two materials would be ground into fine powders, mixed together and then heated in an oven until they reacted together. The resulting crystal would ideally have the structure of the parent but with elements from the second material in key locations, enabling it to absorb visible light.

"The design challenge," Davies said, "was to identify materials that could retain their polar properties while simultaneously absorbing visible light. The theoretical calculations pointed to new families of materials where this often mutually exclusive combination of properties could in fact be stabilized."

This structure is something known as a perovskite crystal. Most light absorbing materials have a symmetrical crystal structure, meaning their atoms are arranged in repeating patterns up, down, left, right, front and back. This quality makes those materials non-polar; all directions "look" the same from the perspective of an electron, so there is no overall direction for them to flow.


"All of the good polar, or ferroelectric, materials have this crystal structure," Rappe said. "It seems very complicated, but it happens all of the time in nature when you have a material with two metals and oxygen. It's not something we had to architect ourselves."



Moreover, the ability to tune the final product's bandgap via the percentage of barium nickel niobate adds another potential advantage over interfacial solar cells. "The parent's bandgap is in the UV range," Spanier said, "but adding just 10 percent of the barium nickel niobate moves the bandgap into the visible range and close to the desired value for efficient solar energy conversion. So that's a viable material to begin with, and the bandgap also proceeds to vary through the visible range as we add more, which is another very useful trait."


"The family of materials we've made with the bulk photovoltaic effect goes through the entire solar spectrum," Rappe said. "So we could grow one material but gently change the composition as we're growing, resulting in a single material that performs like a multi-junction solar cell."

"This family of materials." Spanier said, "is all the more remarkable because it is composed of inexpensive, non-toxic and earth-abundant elements, unlike compound semiconductor materials currently used in efficient thin-film solar cell technology."


Journal Reference:
Ilya Grinberg, D. Vincent West, Maria Torres, Gaoyang Gou, David M. Stein, Liyan Wu, Guannan Chen, Eric M. Gallo, Andrew R. Akbashev, Peter K. Davies, Jonathan E. Spanier, Andrew M. Rappe. Perovskite oxides for visible-light-absorbing ferroelectric and photovoltaic materials. Nature, 2013; DOI: 10.1038/nature12622

New Paradigm for Solar Cell Construction Demonstrated
Science Daily, November 12, 2012

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