PokéBase - Pokémon Q&A
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If I have a Pokemon holding the Macho Brace, and another Pokemon in my party holding the EXP Share, and I defeat a Pokemon that gives some 1 point in EVs, who will get the EVs? How will it distributed?


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Anything that gains EXP points will gain EVs.

So both Pokemon will gain EVs, and the distribution is just like they had battled the Pokemon themself. So if my Mewtwo holding a Macho Brace defeats a Bellsprout, and my Mew is holding the EXP share, Mewtwo will gain 2 Attack EVs, and Mew will gain 1.

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even with I enter all my six pokes in batle all of then will gain ev?
As long as they all gain EXP, yep!