CROSS REFERENCES TO RELATED APPLICATIONS 
     This patent application is a divisional of U.S. patent application Ser. No. 13/190,191, filed Jul. 25, 2011, now U.S. Pat. No. 8,533,895, which claims the benefit of U.S. patent application Ser. No. 10/566,847, filed Jul. 13, 2004, issuing Jul. 26, 2011 as U.S. Pat. No. 7,984,526, which claims the benefit of, U.S. Provisional Patent Application Ser. No. 60/493,992 which was filed on Aug. 8, 2003, titled METHODS FOR REMOVING MATERIALS FROM A SUBSTRATE USING A MONOLITHIC POROUS PAD CAST ON A ROTATABLE BASE invented by Briant Enoch Benson; this patent application also claims the benefit of, U.S. Provisional Patent Application Ser. No. 60/493,755 which was filed on Aug. 8, 2003, titled METHODS AND MATERIALS FOR MAKING A MONOLITHIC POROUS PAD FORMED ONTO A ROTATABLE BASE invented by Briant Enoch Benson; this patent application also claims the benefit of U.S. Provisional Patent Application Ser. No. 60/493,993 which was filed on Aug. 8, 2003, titled DEVICE FOR REMOVING MATERIAL FROM A SUBSTRATE HAVING INTERCHANGEABLE FLUID AND MOUNTING FITTINGS invented by Briant Enoch Benson; this patent application also claims the benefit of U.S. Provisional Patent Application Ser. No. 60/557,298 which was filed on Mar. 29, 2004, titled A MONOLITHIC POROUS PAD FORMED ONTO A ROTATABLE BASE invented by Briant Enoch Benson. All of the above identified patent applications and patents are incorporated herein by reference in their entireties. 
    
    
     BACKGROUND 
     In the fabrication of semiconductor devices, there is a need to perform chemical mechanical polishing (CMP) operations and wafer cleaning. Typically, integrated circuit devices are in the form of multi-level structures. At the wafer level, transistor devices having diffusion regions are formed. In subsequent levels, metal interconnect lines are patterned and electrically connected to the transistor devices to define the desired functional device. As is well known, patterned conductive layers are insulated from other conductive layers by dielectric materials, such as silicon dioxide. As more metallization levels and associated dielectric layers are formed, the need to planarize the dielectric material grows. Without planarization, fabrication of further interconnect and dielectric layers becomes substantially more difficult due to the higher variations in the surface topography. In semiconductor manufacturing processes, metal interconnect patterns are formed in a dielectric material on a wafer, and then, chemical mechanical planarization, CMP, operations are performed to remove the excess metal. After any such CMP operation, it is necessary that the planarized wafer be cleaned to remove particulates and contaminants. 
     In the manufacture of electronic devices such as integrated circuits, the presence of particulate contamination, trace metals, and mobile ions on a wafer is a serious problem. Particulate contamination can cause a wide variety of problems such as localized corrosion, scratching, and “shorts” in the integrated circuit. Mobile ion and trace metal contaminants can also lead to reliability and functional problems in the integrated circuit. The combination of these factors results in lower device yields on a wafer, thereby increasing the cost of an average functional device on the wafer. Each wafer, being at different stages of fabrication, represents a significant investment in terms of raw materials, equipment fabrication time, and associated research and development. 
     Chemical-mechanical polishing (“CMP”) is a commonly used technique for planarizing a film on the wafer prior to subsequent processing of the wafer. CMP usually involves the introduction of a polishing slurry having 50-100 nanometer sized abrasive particles onto the surface of a polishing pad. The wafer with the layer of material, dielectric or metal, to be removed is placed against the surface of a polishing pad with a slurry. Rotating the wafer against the rotating polishing pad decrease the thickness of the layer through a combination of chemical and mechanical actions. The slurries typically are water based and can include fine abrasive particles such as silica, alumina, and other metal oxide abrasive materials. After polishing is complete, the processed wafers must be cleaned to completely remove residual slurry and other residue from the polishing process. The surface is the ready for other processing steps such as electrochemical deposition, etching, and photolithography. 
     To clean residual slurry material from the surface of the polished surface, especially particles less than 0.1 microns in diameter, cleaning brushes are commonly used. These cleaning brushes are usually cylindrical in shape and are rotated along a center axis of the brush. The cleaning brushes are also often made of a foam or porous polymeric material such as polyvinyl alcohol (“PVA”). The combination of rotational movement of the brush and force or pressure placed on the brush against the wafer as well as the application of cleaning fluids or deionized water causes residual slurry materials to be removed from the surface of the wafer. 
     These brushes have protrusion or nodes on their surface for contact and material removal from a substrate. Brushes are formed as sleeves and are slid over a core support which is used to deliver fluids to the brush and to rotate the brush. After extended use, the brush is replaced with a new brush sleeve and requires the polishing tool be stopped adding to lost productivity and downtime. Alignment of the brush protrusions along the brush core is important for consistent contact of the brush with the substrate. Asymmetric alignment and distortion of the spacing of the nodes on the sleeve is a problem with sleeve replacement. Newly installed brushes must be broken in, flushed, and gapped prior to cleaning product substrates. Often time dummy wafers are used to ensure the cleanliness, and operational stability including dimensional, rotational and contact of the brush with the dummy wafers. This non-value added step is costly for manufactures in time and dummy wafers. 
     To perform the cleaning operations in an automated manner, fabrication labs employ cleaning systems. The cleaning systems typically include one or more brush boxes in which wafers are scrubbed. Each brush box includes a pair of brushes, such that each brush scrubs a respective side of a wafer. To enhance the cleaning ability of such brush boxes, it is common practice to deliver cleaning fluids through the brush (TTB). TTB fluid delivery is accomplished by implementing brush cores that have a plurality of holes that allow fluids being fed into the brush core at a particular pressure to be released onto the substrate surface. The fluid is distributed from the brush core through the polymeric material and onto the substrate surface. Ideally, the chemicals flow through the bore and then flow out of the core at an equal rate from all of the brush core holes. It has been found that the chemicals delivered to the core are not flowing out of all of the holes at the same or substantially the same rate and that brush core holes near the chemical receiving end usually flow out chemicals at a substantially faster rate than holes at the opposite side of the chemical receiving end. 
     As semiconductor feature sizes decrease and device performance requirements continue increase, cleaning engineers are also challenged to improve their associated processes. To meet these demands, the same cleaning equipment is now being used to perform operations other than basic de-ionized (DI) water cleaning. Such operations include the application of sophisticated chemicals to remove particulates and/or to etch precise films of materials from the surfaces of a wafer. Many cleaning systems are now required to also apply reactive chemicals, such as hydrofluoric acid, uneven application will have a severe impact on the wafer being processed. For instance, if more HF is applied to one part of the wafer and less is applied to another part of the wafer, the surface of the processed wafer may exhibit variations in the amount of film removed across the wafer. 
     SUMMARY 
     Embodiments of the present invention include methods and materials for making a porous brush or pad that is cast or molded directly onto a rotatable base used to support the pad. The brush or pad can be used for coating at least a portion of a substrate with a fluid or it can be used for removing materials, particles, or chemicals from a substrate. The brush or pad includes a rotatable base or core that interlocks with a porous pad material. The base includes an inner surface and an outer surface and can have a plurality of channels in the base for interlocking the porous pad material with the base. The porous pad material covers at least a portion of the outer surface of the base and may be used for removing material from various substrates. The porous pad material has a monolithic structure and can fill one or more of the channels in the base thereby interlocking the porous pad material with the base. Preferably the channels filled with the porous pad material fluidly connect the inner surface with the outer surface of the base. 
     One embodiment of the present invention is a device for removing material from a substrate that includes a rotatable base supporting a porous pad material. The base includes an inner surface and an outer surface and has channels for distributing a fluid to the porous pad material from the inner surface of said base to the outer surface of the base. The porous pad material covers at least a portion of the outer surface of the base and with the fluid is used for removing materials like particle and thin films from substrates. Preferably the porous pad material interlocks with the channels of the base and more preferably it fluidly connects the inner and outer surfaces of said base. The rotatable base can have one or more fittings mated with it that interconnect the rotatable base with a source of fluid and a spindle or other fixture for rotating the base. The fittings, which may include fluid fittings and machine drive fittings are mated to the base by bonding. By using different fittings a single rotatable base may be adaptable to different material removal tools by using different sized or shaped fittings with the base. 
     Another embodiment the present invention is a device for removing material from a substrate that includes a rotatable base supporting a porous pad material having protrusions or nodes on its surface. The rotatable base includes an inner surface and an outer surface and has channels for distributing a fluid to a substrate through the protrusion bearing porous pad material. The fluid flows from the inner surface of the base to the outer surface of the base. The porous pad material covers at least a portion of the outer surface of the base, and with the fluid, can be used for removing materials like particle and thin films from substrates. The rotatable base has one or more fittings mated with it which interconnect the rotatable base with a source of fluid and a spindle or other fixture for rotating the base. Preferably the porous pad material interlocks with the channels of the base and more preferably it fluidly connects the inner and outer surfaces of the base. The fittings, which may include fluid fittings and machine drive fittings can be mated to the base by bonding. By using different fittings, a single rotatable base may be adaptable to different material coating and removal tools by using different sized or shaped fittings with the base. The rotatable base may be a brush for scrubbing semiconductor wafers. 
     Embodiments of the present invention are directed to methods of cleaning substrates by contacting them with a rotating porous pad material cast or molded onto a rotatable base core. The pad covering the rotatable base includes an inner surface and an outer surface and a plurality of channels in the base for interlocking the porous pad material with the base. The porous pad material covering at least a portion of the outer surface of the base can be used for removing material from a variety of substrates. In the process a material removal or cleaning fluid is deposited onto a surface of the substrate through the brush. Through rotation of the brush and action of the fluid, material can be removed from the substrate surface by rotating the porous pad material against the substrate. Preferably the channels in the base are filled with the porous pad material to interlock the porous pad with the base and fluidly interconnect the inner surface with the outer surface of the base to distribute the fluid to the pad surface. The method may further including the act of flushing a fluid through the porous pad cast onto the rotatable core to remove substrate material adhering to the porous pad and its protrusions or nodes. One or more surfaces of the substrate may have material removed from them by contacting each with a rotating porous pad molded onto a rotatable base along with a fluid. 
     Preferably the porous pad material molded onto the base includes protrusions like bristles or nodes or it may have surface recesses like grooves. Preferably the porous pad material covers the inner surface of the rotatable base core. The channels of the base preferably fluidly connect the inner surface of the core with the outer surface of the core and one or more of the channels are filled with the porous pad material which interlocks the base with the porous pad material and maintains the alignment of nodes on the porous pad during rotations. Fluid may be deposited onto the substrate through the core of the rotatable base by flowing fluid through the porous pad filled channels and out to the substrate surface. 
     Materials removed from the substrate by embodiment of the present invention may include thin film metal oxide films, silica films, semiconductor oxide films, particles of various composition, or chemical residues. Preferably the substrate is a wafer which includes copper or copper interconnects. Brushes of the present invention may be used to clean memory media and wafers regardless of texture or type sputtered metal on the wafer. 
     In another embodiment, the brush or pad includes a rotatable base for supporting a porous pad material cast or molded onto the base. The base includes an inner surface and an outer surface and has a plurality of channels fluidly interlocking the porous pad material with the base. The porous pad material covering at least a portion of the outer surface of the base and has surface protrusions or recesses. The porous pad material having the surface protrusions preferably fills one or more of through channels in the base to distribute fluid from the inner surface of the base to the outer surface of the base through the porous pad material. Preferably the porous pad material interlocking with the channels and covering the outer surface of the base forms a monolithic structure. 
     In another embodiment, the brush or pad includes a rotatable base for supporting a porous pad material cast or molded onto the base. The base includes an inner surface and an outer surface and a plurality of channels in the base for interlocking the porous pad material with the base. Preferably the channels fluidly connect the inner surface with the outer surface of the base. To aid in the distribution of fluid from the inner surface of the base to the porous pad covering the outer surface of the base, through channels may be positioned throughout the base from a center point of the base to an outer edge of the base that may be interconnected by surface channels. The porous pad material covers at least a portion of the outer surface of the base and the porous pad material fills one or more of the through channels and or surface channels in the base to distribute fluid from the inner surface of the base to the outer surface of the base through the porous pad material. Preferably the porous pad material in the through channels and covering the outer surface of the base form a monolithic structure. 
     One embodiment of the present invention is an article having a rotatable base with an adherent porous pad material covering at least a portion, and preferably all of the rotatable base surface including through holes in the base. The adherent porous pad material covering the rotatable base may include a first porous pad material covering at least a portion, and preferably all of the rotatable base surface that adheres to the rotatable base and permits fluid flow through the base and porous pad. The adherent porous pad material on the base may have a second adherent layer of porous pad material molded or cast onto the first adherent layer. Optionally one or more through holes in the base may also be filed with a the porous pad material. The adherent porous pad material a covering at least a portion of the outer base surface maintains its porosity after bonding to the base surface and permits fluid flow from the core of the rotatable base through holes or channels in the base to the outer porous pad surface layer which may be used for applying fluid to a substrate, removing films from a substrate, or cleaning a substrate. 
     In another embodiment of the present invention, the porous pad material is deposited by casting or molding into recessed channels or through holes in the base. The channels and through holes in the housing base interlock with the porous pad material and prevent lifting of the porous pad material from the base surface during use. The channels may have an optional adherent porous first layer onto which a second porous layer is cast. The interlocking of the porous pad material with the base also aids in maintaining the height and the position of the protrusions or nodes of the porous pad material along the base surface or its axis and provides more uniform contact of the nodes with the substrate surface. The interlocking of the porous pad material and the housing base also eliminates or substantially reduces the twisting of brush rollers that commonly occurs with brushes sleeves which are slipped onto a base housing or which are placed on two part base housings. The twisting of sleeve type brushes and rollers may lead to non-uniform and irreproducible substrate surface fluid contact, uneven material removal or cleaning as well as accelerated brush wear. Monolithically formed porous pad material interlocked with the rotatable base maintains node alignment straight, eliminates or reduces ripping of nodes during mounting, and permits much higher tolerance on node size and shape giving more uniform contact with the substrate to be treated. Preferably the channels filled with the porous pad material fluidly connect the inner and outer surfaces of the base. 
     Embodiments of the present invention include methods and materials for making a brush or pad that is cast or molded directly onto the core used to support the pad. The pad or brush can be used for removing materials, particles, or chemicals from a substrate. The brush or pad includes a rotatable base or core for supporting a porous pad material. The base include an inner surface and an outer surface and a plurality of channels in the base for interlocking the porous pad material with the base. The porous pad material covers at least a portion of the outer surface of the base and is used for removing material from various substrates. The porous pad material has a monolithic structure and fills one or more of the channels in the base and interlocks the porous pad material with the base. Preferably the channels fluidly connect the inner surface with the outer surface of the base. 
     The channels in the base to which the porous pad material is interlocked by casting or molding maintains the alignment of the porous pad material on the rotating base, more preferably the casting or molding of the pad maintains the integrity, alignment, and spatial distribution or nodules of the porous pad material on the rotating base. Channels which interconnect the inner and outer surfaces also aid in the distribution of fluid from the inner surface of the base to the outer surface of the base having the porous pad material in contact with the substrate. Preferably the porous pad material in the channels, the inner base surface, and that covering the outer surface of the base are monolithic in structure. The substrate can be any substrate that may need to undergo a scrubbing to complete a cleaning operation or a substrate that is planarized by an etching operation, or other preparation. For instance, the substrate can be a semiconductor wafer, a disk, optical lenses, a flat panel display. Preferably the substrate will benefit from a brush or pad that can deliver substantially uniform and controlled amounts of fluid to the substrate. Even more preferably the substrate will benefit from surface material removal or cleaning with a brush or pad that can deliver substantially uniform and controlled amounts of fluid to the substrate and maintain consistent and uniform contact of the protrusions on the pad with the substrate. 
     In another embodiment, a method is provided for making the brush or pad such that the porous pad material covering the base and the porous foam material filling the through channels of the base are monolithic. Preferably the method includes forming a monolithic porous pad material on the outside of the base which also interlocks with channels on the base. The method includes pouring a combination of un-polymerized porous base monomer and a catalyst into a mold including the base, filling one or more channels in the base, and then curing the combination to form the article. The article is released from the mold. In another embodiment, a method is provided for making the brush or pad such that the porous pad material covering the base and the porous foam material filling the through channels of the base are monolithic. Preferably the method includes forming a monolithic porous pad material on the outside of the base which also interlocks with channels of the base. The method includes pouring a combination of un-polymerized porous base monomer and a catalyst into a mold including the base, filling one or more channels in the base, and then curing the combination to form the article. The article is released from mold. Preferably the mold is treated with a release agent to aid in the release of the monolithic porous pad structure. 
     Embodiments of the present invention may be used to apply coatings to substrates or as brushes for removing particles, thin film, or chemical residues from a wide variety of substrates such as but not limited to semiconductor wafers, flat panel displays, hard disks, and optical devices such as lenses. Advantageously embodiments of the present invention permit great flexibility in the manufacturing and assembly of such brushes. This is because a single base with a porous pad can be used on an number of tools. In the present invention, brushes may be mounted on a variety of cleaning tools by simply changing the one or more fittings that are to be connected to the rotatable base so that the rotatable base and pad can perform their function of cleaning or removing material from the one or more surfaces of the substrates. 
     Advantageously, embodiments of the present invention may be used to provide a fluid to the surface of a substrate for a cleaning or material removal operation such as a chemical mechanical planarization or post CMP scrubbing processes. By interlocking the porous pad material with the base, the porous pad material in held in place relative to the base. Node misalignment and twisting in embodiments of the present invention substantially reduces or eliminated brush walking and twisting compared to slip on sleeve style brushes. An additional advantage of the present invention is that it may be used to distribute fluid to both roller and pad type base fixtures. The porous pad material in the channels may also be used to control the liquid flow from the fluid source to the substrate. This allows the number of perforations or through channels in the housing core to be decreased and their size or surface area increased without significantly increasing the overall amount of liquid used. This is particularly advantageous since larger perforations or through channels in the housing reduces localized nonuniform flushing of the porous pad. Further, by restricting the flow of liquid, the porous pad causes a uniform pressure buildup inside of the distributor. This in turn can be used to form through holes that ensure that both ends of the brush receive the same amount of liquid and are uniformly flushed which improves particulate removal from the brush and reduces or eliminates uneven wear of the brush. 
     An advantage of a brush cast onto a disposable core is that the core and brush are joined together eliminating the slippage, expansion, and loss of concentricity observed with brushes friction fit onto a core. The brush cast onto the core eliminates the need for special mounting stand and time associated with mounting friction brush sleeves onto cores. 
    
    
     
       DESCRIPTION OF THE DRAWINGS 
       In part, other aspects, features, benefits and advantages of the embodiments of the present invention will be apparent with regard to the following description, appended claims and accompanying drawings where: 
         FIG. 1A  illustrates a cross section along the length of a hollow cylindrical tube with through channels useful for a rotatable base in an embodiment of the present invention;  FIG. 1B  is an illustration of the hollow cylindrical tube with one or more through channels filled with a porous pad material;  FIG. 1C  illustrates a rotatable base with filled through channels including fluid fittings and tool mounting fitting; 
         FIG. 2  is a schematic illustration of a cross section along the length of a hollow cylindrical housing base in an embodiment of the present invention with through channels and the outer surface of the base including a porous pad material with optional protrusions on the pad surface; 
         FIG. 3A  is a schematic illustration of a cross section along the length of a hollow cylindrical housing base in an embodiment of the present invention with through channels, the inner surface, and the outer surface of the base including a filling or covering of a porous pad material without fluid fitting or a fitting for connection of the base to a cleaning tool;  FIG. 3B  is a schematic illustration of a cross section along the length of a hollow cylindrical housing base in an embodiment of the present invention with through channels, the inner surface, and the outer surface of the base including a filling or covering of a porous pad material with fluid fitting and a fitting for connection of the base to a cleaning tool; 
         FIG. 4  is a schematic diagram of a hollow cylindrical tube useful in as a base or core for embodiments of the present invention illustrating different through channels filled with a porous pad material; 
         FIG. 5A  is a schematic diagram of a rotatable base in the form of a disk shape housing in an embodiment of the present invention with an adherent porous pad layer covering the rotatable base and a second adherent porous pad material molded or cast onto the first adherent porous pad layer;  FIG. 5B  is a schematic illustration of a cross section along the diameter of a disk shaped housing base in an embodiment of the present invention with through channels, the inner surface and the outer surface of the rotatable base including a filling or covering of a porous pad material; 
         FIG. 6  is a schematic diagram of a cross section along the diameter of a rotatable hollow tube housing base in an embodiment of the present invention with hollow through channels filled with a porous material and outer surface of the base covered with a porous pad material having protrusions. 
         FIG. 7  is a schematic diagram of a cross section along the diameter of a rotatable hollow tube housing base in an embodiment of the present invention with hollow through channels filled with a porous material, the inner surface of the base covered with a porous pad material and the outer surface of the base covered with a porous pad material including protrusions; 
         FIG. 8A  is a schematic diagram of a rotatable hollow tube housing base in an embodiment of the present invention with an adherent porous pad layer covering the base and a second porous pad material adhering to the first porous pad layer that has been molded or cast onto the adherent first porous layer;  FIG. 8B  is a schematic diagram of a cross section along the diameter of a hollow tube housing base in an embodiment of the present invention with a rotatable hollow cylinder with through channels filled with a first porous pad material, the outer surface of the base covered with a first porous pad material and a second porous pad material including protrusions covering the first porous pad material; 
         FIG. 9  is a schematic diagram of an embodiment of the present invention cleaning one or more surfaces of a substrate; 
         FIG. 10A  illustrates a cross section of a brush pad with protrusions;  FIG. 10B  illustrates a cross section along the diameter of a hollow tube housing base in an embodiment of the present invention with hollow through channels filled with a porous material and the outer surface of the base covered with a first porous pad material.  FIG. 10C  illustrates a brush formed by combining the components in  FIG. 10A  and  FIG. 10B ; 
         FIG. 11A  illustrates a cross section of a brush pad with protrusions;  FIG. 11B  illustrates a cross section along the diameter of a hollow tube housing base in an embodiment of the present invention with hollow through channels filled with a porous material;  FIG. 11C  illustrates a brush formed by combining the components in  FIG. 11A  and  FIG. 11B ; 
         FIG. 12B  illustrates a cross section of a housing base tube having channel grooves in a rotatable base surface for interlocking with the porous base material and retaining the alignment and position of nodes on the surface of a porous pad material covering the base surface; 
         FIG. 12C  illustrates a cross section of a housing base tube having channel grooves in a rotatable base surface for interlocking with the porous base material and retaining the alignment and position of nodes on the surface of a porous pad material covering the base surface; 
         FIG. 13  shows a line drawing of a photograph of a cross section of a brush molded onto a rotatable base using methods and materials of the present invention; 
         FIG. 14  is a diagram of a mold that can be used to make a brush molded onto a rotatable base of the present invention; 
         FIG. 15A  is a non limiting illustration of an embodiment of the present invention having a porous pad material cast onto an adherent first porous material on a rotatable substrate having through holes;  FIG. 15B  is a non-limiting illustration of an embodiment of the present invention of a porous pad material cast onto an adherent first porous material on a rotatable nonporous substrate; 
         FIG. 16  is an illustration of a material removal pad of the present invention including a porous pad molded into channels of a rotatable core and having interchangeable fluid and tool drive mounting fitting on the core; 
         FIG. 17  is an illustration of a rotatable base core of the present invention having interchangeable fluid and mounting fitting on the core; 
         FIG. 18  is an illustration of a cross section of a material removal pad of the present invention including a porous pad molded into channels of a rotatable core; 
         FIG. 19A  is an illustration of an unassembled rotatable base core with interchangeable fluid and tool mounting fitting;  FIG. 19B  is an illustration of the fluid fitting and tool mounting fitting inserted into the base core;  FIG. 19C  is a detail (A) of the joint formed between the base core and the fluid fitting; 
         FIG. 20  is an illustration of a fluid fitting  1910  of  FIG. 19A  in detail; 
         FIG. 21A  is an illustration of the outside of a core ( 1920 ) of the  FIG. 19A ;  FIG. 21B  is a view of a cross section of the core ( 1920 ) of  FIG. 19A ; 
         FIG. 22  is a cross section of core in  FIG. 19A  along a rotational axis of the core illustrating placement of channels and through holes in the rotatable core; 
         FIG. 23  is an illustration of a tool mounting fitting ( 1930 ) of  FIG. 19A ; 
         FIG. 24  is a illustration of another embodiment of an unassembled core with interchangeable fluid and tool mounting fittings; 
         FIG. 25  is a detailed illustration the fluid fitting of  FIG. 24 ; 
         FIG. 26  is a detail illustration of the tool mounting fitting of  FIG. 24 . 
     
    
    
     DETAILED DESCRIPTION 
     Before the present compositions and methods are described, it is to be understood that this invention is not limited to the particular molecules, compositions, methodologies or protocols described, as these may vary. It is also to be understood that the terminology used in the description is for the purpose of describing the particular versions or embodiments only, and is not intended to limit the scope of the present invention which will be limited only by the appended claims. 
     It must also be noted that as used herein and in the appended claims, the singular forms “a”, “an”, and “the” include plural reference unless the context clearly dictates otherwise. Thus, for example, reference to a “channel” is a reference to one or more channels and equivalents thereof known to those skilled in the art, and so forth. Unless defined otherwise, all technical and scientific terms used herein have the same meanings as commonly understood by one of ordinary skill in the art. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of embodiments of the present invention, the preferred methods, devices, and materials are now described. All publications mentioned herein are incorporated by reference. Nothing herein is to be construed as an admission that the invention is not entitled to antedate such disclosure by virtue of prior invention. 
     Although the present invention is described in conjunction with the scrubbing of a semiconductor substrate or wafer, it will be appreciated that other substrates may be processed or coated by the methods and apparatuses of the present invention. Further, it will be appreciated that reference to a semiconductor substrate or wafer may include a bare or pure semiconductor substrate, with or without doping, a semiconductor substrate with epitaxial layers, a semiconductor substrate incorporating one or more device layers at any stage of processing, substrates including copper or copper alloy interconnects, other types of substrates incorporating one or more semiconductor layers such as substrates having semiconductor on insulator (SIO) devices, or substrates for processing other apparatuses and devices such as flat panel displays, MEMS devices, multichip modules, etc. 
     It will be clear to one of ordinary skill in the art that some of the steps in the cleaning system described herein may occur in another order and/or with various solutions depending upon the substrate or substrate layer being cleaned. For example, different cleaning solutions, such as water, water and isopropyl alcohol, citric acid, ammonium hydroxide, ammonium citrate, and hydrofluoric acid solution (or mixtures of solutions) may be used in one of the brush stations. Also, other systems may include one brush station, or two or more than two brush stations. Moreover, other systems may omit one or more of the above stations/steps and may include additional processing stations, such as a CMP station. 
     Sponges or brushes in the form of replaceable sleeves have problems with walking and twisting on their brush cores and have shorter brush life. Rotation rates for brushes generally range from about 800 to 1500 rpm with from about 0.8 to 2 pounds of drag. Higher rotation rates and drag are often preferred to clean an article at a faster rate, however this may lead to rapid degradation of nodes on the brush or pad. Cast on the core brushes described in embodiments of the present invention can be rotated at greater radial velocities because they cannot walk or twist due to interlocking of the base core with the porous pad material. Walking refers to stress induced migration of the brush to a different location on the core. Twisting refers to stress induced relocation of nodules out their original alignment. 
     Cleaning and material removal solutions which may be used with the method of the present invention include but are not limited to deionized water and mixture of chemicals in deionized water. The chemicals may include fluoride compound such as HF or NH.sub.4F; NH.sub.4OH, an organic acid, an ammonium salt of an organic acid, alcohols, an anionic surfactant; a basic, a neutral, or an acidic pH environment. For example hydrochloric acid (HCl) may be added to the solution to adjust pH and help dissolve surface coatings like copper oxide. One example of the many different ways in formulating the cleaning solution is combining 0.5% HF, 0.1% Citric Acid, and 0.4% NH.sub.4OH by weight mixed in deionized water. The pH level of the solution in this example is approximately 3. EDTA, oxalic acid, deionized (DI) water or corrosion inhibitors such as benzotriazole may also be used in such cleaning solutions. It should be noted however, that the present invention is not limited by formulations of the cleaning solution, and that each component in the solution may be replaced by different chemical that has similar properties. 
     A method of cleaning a surface of a semiconductor wafer after a chemical mechanical polishing (CMP) operation includes the steps of applying a cleaning or material removal chemical to the surface of the semiconductor wafer and preferably through a brush that is cast onto a base core. Preferably the porous pad material fills one or more through holes of the rotatable base and forms an interlocking monolithic structure with porous pad material on the surface of the base. Even more preferably the porous pad material fills one or more through holes of the rotatable base and forms an interlocking monolithic structure with porous pad material on the inner and the outer surface of the base. Brushes with interlocking porous pad and base structures but without through channels in the base may have cleaning and material removal chemicals applied to the surface of the substrate by a spray nozzle. Preferably the brush has a porous pad material forming a monolithic interlocking structure with the base. The semiconductor wafer may have copper interconnects wherein the cleaning chemical transforming the copper layer on the surface of the semiconductor wafer into a water soluble copper oxide layer. Scrubbing the surface of the semiconductor wafer having the cleaning chemical fluid with a brush that has a porous pad material cast onto a base and forms a monolithic interlocking structure with a base may be used to, but is not limited to, removal of from between about 100 angstroms and about 150 angstroms of the copper oxide layer from the surface of the semiconductor wafer. The treated wafer and brush may be further treated by rinsing the semiconductor wafer and the brush with deionized water to remove the water soluble copper oxide from the surface of the semiconductor wafer and the brush prior to cleaning or treating a second semiconductor wafer. The fluid application, the scrubbing, and the rinsing steps can be performed in a brush box. The treated substrate will have a copper oxide layer having a thickness between about 5 angstroms and about 30 angstroms on the surface of the semiconductor wafer. 
     A method of cleaning a surface of a semiconductor wafer after a chemical mechanical polishing (CMP) operation may further include controlling the amount of the copper oxide layer remaining on the surface of the semiconductor wafer by controlling an amount of H.sub.2O.sub.2 in the cleaning chemical that flows through the brush cast onto the core. 
     A brush cast onto a core base such that the porous pad material forming the brush is interlocked with channels in the base may be used to remove an ultra-thin chemical oxide layer, such as SiO.sub.2, from a substrate as part of a post CMP cleaning process. In this process, an acid such as hydrofluoric acid is delivered to the core of the cast on core brush where it flows through the porous pad material in the through channels of the base core to the surface of the brush. Alternatively the acid may be applied to the surface of the wafer using a sprayer. 
     Less than 20 angstroms of such oxides may be etched using very dilute HF and brushes interlocked with a rotatable base. Hydrofluoric acid with a concentration of about 0.005% HF. can be used to perform a controlled removal of less than approximately 15 angstroms of the oxide. This oxide removes contaminants, including particles and plated residues, on the surface of the oxide layer or within the oxide layer, without making the surface hydrophobic. A thin layer of oxide remains on the surface of the workpiece so that the surface remains hydrophilic. To clean thicker oxide layers, e.g., greater than approximately 30 angstroms, a controlled thin oxide etch may be used. For these applications, removal of metallic particle contamination (which may be incorporated into the oxide from the CMP polishing process) is important. The metallic particle contamination may diffuse into the microelectronic devices on the workpiece and cause them to fail. Very dilute concentrations of HF (such as 0.005% HF) may be sufficient to remove metallic contamination, depending upon the depth of penetration of the contamination into the oxide layer. For example, if the metallic contamination is more than 20 angstroms below the surface, a higher concentration of HF may be needed. The amount of oxide removed is determined by the concentration of HF delivered to the brush, the dispense flow rate, and time. For removing less than 15 angstroms of a native oxide layer, a 0.005% concentration of HF may have a slow etch rate, with etch times of 20-60 seconds being acceptable. The film etch time is important when using higher concentrations. The concentration of HF can be adjusted to provide an oxide layer removal rate which is consistent with a desired workpiece throughput or production rate. For back-end CMP processes, removal of up to 100 angstroms of oxide may be required to adequately remove the metallic contamination incorporated therein by the polishing process. To remove this amount of oxide in less than approximately 40 or 50 seconds, the concentration of HF is increased to 0.5-1.0%. 
       FIG. 1A  illustrates a cross section along the length of a hollow cylindrical tube base  100  with various exemplary through channels  130 ,  150 , and  180  for permitting fluid flow between the inner surface  190  of the tube with outside surface  120 . The through channels may be different in size as illustrated by  130  and  150 . The through holes may include a roughened surface or a non-limiting example of a notch  140  for increasing adhesion or interlocking of the a porous foam or pad material used to fill the through channels. An endcap  110  may be optionally used to close one end of the cylinder during molding and is also useful for mounting the finished housing tube to a tool. The endcap  110  will cause a source of feed fluid (not shown) to flow through the channels  130 ,  150 , and  180 . Optional insert  170  may be used to offset the inside diameter of the tube for subsequent insertion of a fluid fitting or a step or series of steps with diameter greater than the inner diameter of the base, not shown, may be machined into the base  100  for mating with fluid and machine drive fittings. Endcap  110  and insert  170  may be bonded, molded, or machined into the base  100  and preferably form a fluid tight seal. The endcap  110  and inner surface  190  define a volume for holding a fluid. 
       FIG. 1B  illustrates the hollow cylindrical tube  100  with one or more non-limiting examples of through channels  130 ,  150 ,  180  filled with a porous pad material  152 . The porous material  152  is shown just filling the through channels so that inner surface  190  and outer surface  120  remain substantially free of the porous material  152 . In  FIG. 1B , the insert  170  and endcap  110  are shown positioned inside the base. Fluid fitting  114  and machine tool mounting plate  112  are shown prior to being mounted to the base. 
       FIG. 1C  illustrates the base  100  with through channels  130 ,  150 , and  180  filled with a porous material  152 . The porous material  152  is shown just filling the through channels so that inner surface  190  and outer surface  120  remain substantially free of the porous material  152 . The fluid fitting  114  and machine tool drive mounting plate  112  are shown mounted to the base  100 . Fluid fittings permit flow of fluid from a source (not shown) into the core of the base; machine mounting fittings permit the rotatable base  100  to be connected to a rotating spindle or fixture for rotating the base in a cleaning or material removal process. Inlet for fluid  106  is provided for by fluid fitting  114 . The embodiment shown in  FIG. 1C  may be covered with a sleeve of a second porous pad material (not shown) cast on the base  100 , to form a brush roller. Such a brush roller may be installed in a CMP cleaning tool. In use as a cylindrical brush, a source of pressurized fluid would be connected to fluid inlet fitting  114 . Fluid would flow into the device through inlet  160 , pass through inlet  160  and into the core volume defined by endcap  110  and the inner surface  190  of base  100 . Fluid would flow out of the exemplary flow channels  130 ,  150 , and  180  filled with the porous pad material  152  and out to the second porous pad layer. The machine tool plate  112  would be connected to a rotating shaft or spindle of the tool to rotate the brush against the  FIG. 2  is a schematic illustration of a cross section along the length of a hollow cylindrical housing base  200  that has a porous pad material cast onto the base core. Exemplary through channels  230 ,  250 , and  280  are filled with a porous material  252  in a mold which also forms a layer  256  of the porous pad material on the outer base surface  220 . The porous pad material  252  and  256  interlock with the base through holes and optional surface channels (not shown) to maintain the position and spacing of the protrusions  254  on the pad surface. By interlocking the channels in base with the porous pad, the movement of the pad by walking or twisting is reduced or eliminated. The porous pad  252  interlock with the channels of the base by filling one or more of the channels and preferably form a monolithic structure with  256  and  254 . Preferably the channels or surface of the base have a shape to mechanically and physically prevent the porous pad cast or molded into the channels from being removed by pulling or twisting of the porous pad during rotation. Optional protrusions  254  are shown covering the porous layer  256 . Besides protrusions, the porous layer may have but is not limited to recessed grooves or a flat surface. In the  FIG. 2  the porous pad materials  252 ,  254 , and  256  are preferably all the same material and form a continuous monolithic structure from a molding process. Optional fluid fitting  214  and machine tool mounting plate  212  are shown connected to the base  200 . Base  200  inner surface  290  remains substantially free of the porous material. In use as a cylindrical brush, a source of pressurized fluid would be connected to fluid inlet fitting  214 . Fluid would flow into the device through inlet  260 , as illustrate by  202 , pass through inlet  260  and into the core volume defined by endcap  210  and the inner surface  290  of base  200 . Fluid would flow out of the flow channels filled with the porous pad material, for example illustrated by channel  280 , and out to the porous pad layer  256  to be deposited on the substrate. 
       FIG. 3B  is a schematic illustration of a cross section along the length of a hollow cylindrical housing base  300  with through exemplary channels  330 , 350 , and  380  as well as the inner surface  390  and outer surface  320  of the base filled or covered with the porous pad material. Through channels illustrated by  330 ,  350 , and  380  are filled with a porous material  352  in a mold which also forms layers  356  and  358  of the porous pad material on base surfaces  320  and inner surface  390 . The porous pad material interlocks with the through channels of the base  300 . Optional protrusions  354  are shown covering the porous layer  356 . Besides protrusions, the porous layer may have but is not limited to recessed grooves or a flat surface. In the  FIG. 3B  the materials  352 ,  354 ,  356 , and  358  are preferably all the same and form a continuous monolithic structure in a molding or casting process. The porous base material  352  and  356  that fills at least a portion of the exemplary channels  350  and  330  act to prevent lifting of the porous pad material  356  and  354  from the base surface during use. It also aids in maintaining the height and the position of the protrusions or nodes  354  along the base surface or its axis and provides more uniform contact with the substrate surface. Optional fluid fitting  314  and machine tool mounting plate  312  are shown connected to the base  300  in  FIG. 3B ;  FIG. 3A  illustrates an embodiment of  FIG. 3B  without fluid fitting and machine drive fitting. Porous pad material layer  358  inside the base has a thickness measured between pad inner surface  362  and base inner base surface  390 . Porous pad layer  356  has thickness measured between  366  and  364 . Protrusions  354  have a height measured between  368  and  366 . The thickness of the porous pad layers  354 ,  356 , and  358  may be varied by changing the shape and dimensions of the mold. In use as a cylindrical brush, a source of pressurized fluid would be connected to fluid inlet fitting  314 . Fluid would flow into the device through inlet  360  and into the core defined by endcap  310  and the inner surface  390  of base  300 . Fluid would flow out of the flow channels such as  330  filled with the porous material and then distributed out to the porous pad layer  356  and protrusions  354 .  FIG. 3A  does not have fluid or tool fittings  314  and  312  mounted to the base  300  and plate  310 . 
       FIG. 4  is a schematic diagram illustrating non-limiting through channels filled with a porous pad material useful in the practice of the invention. Base housing  400  is a cylinder with inlet  460  and outlet  482 , optionally outlet  482  is covered with an endcap (not shown). The inner surface  490  and outer surface  420  are fluidly connected by through channels  450  and  452  and or pores  480 ,  486  and  484 . In  FIG. 4  the different sized illustrative pores  480  and  484  are shown filled with the porous pad material while pore  486  is not filled. Through channel  452  is shown not filled and through channel  450  is shown filled with the porous pad material. Preferably the pores and through channels in the base  400  are filled with the porous pad material. Also shown is a distribution of through channels and pores along the base  400  to aid in the preferential distribution of fluid from the inside of the base to the outer surface of the base and into a porous pad material covering the base which is not shown. 
     The present invention may also be used as a pad for material removal or cleaning of a substrate.  FIG. 5A  illustrates a cross section along the diameter of a disk shaped housing base  508   a  having sides  506   a  and top  500   a  to form a volume  504   a . A hollow rod  516   a  connected to top  500   a  through an optional machine drive or fluid mounting plate which is not shown. Rod  516   a  is used to deliver fluid to the pad  556   a  and to rotate the device. Fluid from a pressurized source illustrated by  502   a  enters the device cavity  504   a  through the rod  516   a  and flows through inner porous pad layer  562   a  adhering to the base  508   a  with inner surface  590   a  and an outer surface  520   a . The fluid flows from  504   a  through channels  550   a , adhering porous pad layer  562   a , and second porous pad layer  556   a , and to porous protrusions  554   a . The first porous pad material  562   a  adheres to the base surface  520   a  and second porous pad layer  556   a  and bonds the porous pad material  556   a  with the base  508   a . The porous pad layer preferably covers through holes  550   a , but it may also fill one or more of the through holes  550   a . Optionally the porous pad material  562   a  and  556   a  form a single adherent porous pad material bonded to the base  508   a . Porous pad layer  556   a  covers outer surface  520   a  of base  508   a  and may have surface recess features  522   a . The porous materials  558   a ,  562   a  are preferably all the same material composition and form a continuous monolithic structure from a molding or casting process. 
     The present invention may also be used as a pad for material removal or cleaning of a substrate.  FIG. 5B  illustrates a cross section along the diameter of a disk shaped housing base  508   b  having sides  506   b  and top  500   b  to form a volume  504   b . A hollow rod  516   b  connected to top  500   b  through an optional machine drive or fluid mounting plate which is not shown. Rod  516   b  is used to deliver fluid to the pad  556   b  and to rotate the device. Fluid from a pressurized source illustrated by  502   b  enters the device cavity  504   b  through the rod  516   b  and flows through inner porous pad layer  558   b , into exemplary through channels  550   b , pad layer  556   b , and to porous protrusions  554   b . The porous pad material filling the through hole  550   b  interlocks the pad material with the base  508   b . Porous pad layer has top surface  562   b  and covers inner surface  590   b  of the base  508   b . Porous pad layer  556   b  covers outer surface  520   b  of base  508   b  and may have surface recess features  522   b . The porous materials  558   b ,  552   b ,  554   b , and  556   b  are preferably all the same material composition and form a continuous monolithic structure from a molding process. 
     Various modifications of the present invention may be made as would be know to those skilled in the art. For example,  FIG. 6  illustrates a cross section along the diameter of a hollow tube housing base  600  with inner surface  690  and outer surface  620 . Through channels  650  are shown filled with and interlocking a porous pad material which also forms porous pad layer  656  with protrusions  654  covering base outer surface  620 . The porous material in the channel  650  interlock the porous pad material  656  with the base  600 . The porous materials in the through channels and covering the base form a monolithic structure, porous pad material  656  is substantially absent from the inner surface  690  in the core  672  of the device. The core  672  of the device may be connected a rod from the cleaning or material removal tool to accept fluid from the tool and distribute it to the porous pad layer  656  on the surface through channels  650 . The base  600  may be connected via a machine drive fitting, not shown, to rotate the base and porous pad material against a substrate.  FIG. 7  shows a cross section along the diameter of a hollow tube housing base  700  with inner surface  790  and outer surface  720 . Through channels  750  are shown filled with a porous pad material that interlock the base  700  with the pad materials  756  and  758 . The porous pad material forms a porous layer  758  covering inner surface  790  of the base and an outer porous pad layer  756  with protrusions  754  covering base outer surface  720 . The porous materials in the through channels  750 , inside the core  772  and covering the base preferably form a monolithic structure. The core  772  of the device accepts fluid through a fluid fitting connected to the base  700 , not shown, from the tool and distributes it to the surface porous pad layer  756  through channels  750 . The base  700  may be connected via a machine drive fitting, not shown, to rotate the base and porous pad material against a substrate to be treated. 
       FIG. 8A  is a schematic diagram of an embodiment of the present invention having a first adherent porous pad material  856   a  covering the rotatable substrate  820   a  having core  872   a . The first porous pad material  856   a  may have a second layer of a porous pad material  859   a  cast or molded on to at least a portion and preferably all of the first layer of porous pad material  856   a . Base  800   a  has through channels  850   a  and outer surface  820   a  covered with an adherent first porous pad material  856   a . The porous pad material  856   a  adhering to the outer surface  820   a  may be chemically or mechanically bonded to the rotatable substrate  800   a  with surface  820   a  by molding a preformed pad of porous pad material to the base  800   a . The first porous pad material  856   a  covering the base  800   a  may be bonded by casting, solvent bonding, or molding the porous pad to the surface of the rotatable substrate. This first porous pad material can serve as an adhesion layer to hold or interlock the second porous pad layers such as  859   a  by chemical bonds, or mechanical interlocking bonds, or a combination of these between the first and second pad materials. The adherent porous pad material  856   a  covering the base  800   a , preferably covers the through holes  850   a  while maintains its porosity after bonding to the base surface  802   a . This porosity permits fluid flow from the core  872   a  through holes  850   a  and to the outer pad layer  859   a  as illustrated by  802   a . In optional embodiments the porous pad material may fill a portion of one or more of the through channels  850   a , not shown, to form an adherent and interlocking monolithic porous pad material  856   a  covering the base surface  802   a . The porous pad material layer  856   a  covering the outer surface  820   a  is preferably thinner than the second porous pad layer  859   a  and may or may not have protrusions. The outer surface of layer  856   a  may be covered with a second layer of porous pad material  859   a , shown with protrusions, by a second molding process or by sliding a second preformed porous pad material or cleaning brush over the layer  856   a . The second porous pad material may be a replaceable sleeve or may have a fluid conductance different from porous material layer  856   a  to better distribute fluid to a substrate to be treated by fluid  802   a.    
     In  FIG. 8B  a schematic diagram of an embodiment with a an adherent porous layer filling the base through channels is shown. Base  800   b  has through channels  850   b  filled and outer surface  820   b  covered with an interlocking monolithic porous pad material  856   b . The porous pad material layer  856   b  covering the outer surface  820   b  is thin and does not have protrusions. The outer surface of layer  856   b  may be covered with a second layer of porous pad material  859   b , shown with protrusions, by a second molding or casting process or by sliding a second preformed porous pad material or cleaning brush over the layer  856   b . The second porous pad material may be a replaceable sleeve or may have a fluid conductance different from porous material layer  856   b  to better distribute fluid to a substrate to be treated by fluid  802   b . The second porous pad material  859   b  may have the same or a different composition that first porous pad material  856   b.    
     The devices of the present invention may be used to remove material from one or more surfaces of a substrate  910  as illustrated in  FIG. 9 . In this non-limiting diagram, the devices are shown in cross section as a brush roller  920  over the top substrate surface  912  and brush roller  930  below the bottom substrate surface  914 . The brush  920 , similar to that detailed in  FIG. 7 , may receive pressurized fluid  902  from a perforated rod  992  or fluid fitting attached to the base which is connected to a fluid conduit from the cleaning tool (not shown). Fluid  902  flows through the porous pad material layer  958  surrounding the perforated rod  992  and through channels  950  filled with the porous pad material. The fluid is illustratively delivered to the substrate through the protrusions in the porous pad layer  956  which also removes particles and material from the substrate as it is rotated. Perforated rod  994  or a fluid fitting attached to the base delivers fluid  903  to the brush  930  which is similar to that depicted in  FIG. 7 . Fluid  903  flows through the porous pad material layer  958  surrounding the perforated rod  993  and through channels  950  filled with the porous pad material. The fluid is illustratively delivered to the substrate through the protrusions in the porous pad layer  956  which also removes particles and or material from the bottom of the substrate as it is rotated. 
       FIG. 10A  illustrates a cross section of a second porous brush pad  1059  with protrusions and having an inner surface  1080 .  FIG. 10B  illustrates a cross section along the diameter of a hollow tube housing base  1000 , with core  1072  and hollow through channels  1050  filled with a porous material  1058  in a monolithic structure. Housing base has inner surface  1090  and outer surface  1020 . The inner surface  1090  may or may not have a layer of porous pad material. The outer surface  1020  of the base may be covered with a first porous pad material layer  1058  with outer surface  1062 . The first porous pad material may be bonded by casting, solvent bonding, or molding of the porous layer  1058  to the base surface  1020  by chemical bonds, mechanical bonds or interlocking, or a combination of these bonds. The inner surface  1080  of second porous brush pad  1059  in  FIG. 10A  may be cast, molded, or slid over the outer surface  1062  of first porous pad layer  1058  to form a composite brush device  1002  as shown in  FIG. 10C . Preferably the second porous brush pad  1059  is cast onto the first porous pad layer  1058  and is chemically bonded, mechanically bonded, or a combination of these bonded to the first porous layer. Optionally the porous pad layer  1058  does not interlock with through channels  1050  (not shown). The first porous pad material and the second porous pad material may be a single layer, preferably they are formed from the same material. 
       FIG. 11A  illustrates a cross section of a second porous brush pad  1159  with protrusions and having inner surface  1180 .  FIG. 11B  illustrates a cross section along the diameter of a hollow tube housing base  1100  including one or more hollow through channels filled with a porous pad material  1152 .  FIG. 11C  illustrates a brush formed by the components in  FIG. 11A  and  FIG. 11B . Device  1102  has porous pad material  1158  filling and interlocking with channels  1150  to form a monolithic structure with base  1110 . Second porous brush pad  1159  covers the base  1100  and contacts channels filled with the porous pad material. 
     One method of retaining the porous pad material on the surface of the housing base is to form recessed channels, posts, or hollows in the surface of the surface of the housing. The recessed holes, posts, or channels preferably have a larger opening at their bottom than at theirtop. In  FIG. 12  the base  1200  has exemplary recessed channels  1232  and  1234 . The upper surface portions  1236  and  1238  are part of the base outer surface into which the recessed channel  1234  was cut. Porous base material  1256  cast onto the base  1200  fills at least a portion of the surface recess down to the surface  1220  of the base to interlock the porous pad material with the base  1200 . This prevents lifting of the porous pad material  1256  from the base surface during use and aids in maintaining the height and the position of the protrusions or nodes  1254  along the base  1200  surface or rotational axis. The base  1200  may also be connected to a machine drive fitting, not shown. In use as a brush, the embodiment if  FIG. 12  may have chemicals or otherfluids dispensed on the substrate to be treated by external sprayers as would be know to those skilled in the art. Channels similar to  1234  and  1232  may be formed in bases having through holes and porous pad material fluidly connecting the inner and outer surfaces of the base. 
       FIG. 13  is a line drawing of a photograph of a cross section of a brush molded onto a rotatable base of the present invention.  FIG. 13  shows a cross section along the length of a hollow cylindrical housing base  1300  with exemplary through channels  1380  as well as the inner surface  1390  and outersurface  1320  of the base filled or covered with the porous pad material. Through channels illustrated by  1380  are shown filled with a porous material  1352  in a mold which also forms layers  1356  and  1358  of the porous pad material on base surfaces  1320  and  1390 . The porous pad material interlocks with the through channels  1380  of the base  1300 . Node protrusions  1354  are shown covering the porous layer  1356 . The materials  1352 ,  1354 ,  1356 , and  1358  are all the same and form a continuous monolithic structure. The porous base material filling the exemplary channels  1352  interlocks  1365  and  1358  and acts to prevent lifting of the porous pad material  1356  and  1354  from the base surface during use especially at high rotation rates. Interlocking also aids in maintaining the height and the position of the protrusions or nodes  1354  along the base surface or its axis and provides more uniform contact of the nodes  1354  with a substrate surface. Fluid fitting  1314  and cleaning machine tool endcap  1312  are shown connected to the base  1300 . Porous pad material layer  1358  inside the base has a thickness measured between pad inner surface  1362  and base inner base surface  1390 . The thickness of the porous pad layers  1354 ,  1356 , and  1358  may be varied by changing the shape and dimensions of the mold. In use as a cylindrical brush, a source of pressurized fluid would be connected to fluid inlet fitting  1314 . Fluid would flow into the device through inlet  1360  of a fluid fitting and into the core  1372  defined by the inner surface  1390  of base  1300 . Fluid would flow through porous pad layer  1358 , out of the flow channels such as  1350  filled with the porous material  1352  and then distributed out to the porous pad layer  1356  and nodes  1354 . 
       FIG. 14  illustrates a mold which may be used to make a brush molded onto a rotatable base of the present invention. The mold includes and end cap  1401  with o-rings  1406  sealing the endcap  1401  to the mold sleeve  1402 . Mold sleeve  1402  is used to create protrusions or recesses in the porous pad and may be surrounded by a shrink wrap film  1403  to retain un-polymerized porous pad monomer and catalyst filling the mold sleeve  1402  and in the core assembly  1404  shown with through channels. A top filler cap  1407  is used to seal the top of the mold sleeve andretain mold core  1405  within the center of the core. Barbed fluid fittings  1408  are provided to the top filler cap  1407 . 
       FIG. 15A  illustrates an embodiment of the present invention where a cast or molded porous pad layer  1520  having optional protrusions  1524  is interlocked to a rotatable base  1505  through a porous adhesion layer  1514 . The rotatable base may have a plurality of channels  1510  for the flow of a fluid  1504  from fluid inlet and rotating shaft  1502  coupled to the base  1506 . The fluid  1504  may flow through porous adhesion layer  1514 , and through the porous pad  1520  having optional protrusions.  FIG. 15B  illustrates an embodiment of the present invention where a cast or molded porous pad  1558  having optional protrusion  1560  is interlocked with a nonporous substrate  1550  through a porous adhesion layer  1554 . The non porous substrate may be coupled to a rotating vacuum chuck from a cleaning or polishing tool. 
       FIG. 16  is an illustration of a material removal pad of the present invention including a porous pad  1610  with surface protrusions  1612  molded. The porous pad  1610  is molded into channels of a rotatable core and having interchangeable fluid inlet fitting  1620  and tool drive mounting fitting  1600  attached to the core for connection to a rotatable shaft or fixture on a tool for rotating the device. 
       FIG. 17  is an illustration of the core  1710  of diameter  1730  having interchangeable fluid fitting  1720  attached to the core and tool drive mounting fitting  1700  attached to the core for connection to a rotatable shaft or fixture on a tool for rotating the device. The core is shown with channels  1760  through the core or base  1710 . The channels would be filled with the porous pad material from casting to interlock the pad material with the base  1710 . The length of the channels  1740 , their spacing from each other  1724  and their height  1750  may be varied depending upon the desired flow rate and distribution of fluid through the porous pad material in the channels. 
       FIG. 18  is an illustration of a cross section of a material removal pad of the present invention including a porous pad  1824  molded into channels, not shown, of a rotatable core  1834  having outside diameter  1830 . The protrusions  1844  on the porous pad have a diameter  1840  and a height  1800  from a surface of the pad  1820 . The outside diameter of the pad  1810  is measured from the outside of the protrusions  1844 . 
       FIG. 19A  is an illustration of an unassembled bare base core  1920  including channels  1924  with interchangeable fluid fitting  1910  and tool drive mounting fitting  1930 . The channels  1924  are preferably filled with a porous pad material to interlock it with the base  1920 .  FIG. 19B  is an illustration of the fluid fitting and tool mounting fitting inserted into the inside of the coreand having a final assembled length of  1940 . Although shown with the fittings  1910  and  1930  being inserted into the inside of the core, similar fittings in this embodiment or other embodiments of the present invention could be adapted by those skilled in the art for mounting onto the outer surface of the core.  FIG. 19C  is a Detail A in  FIG. 19B  and shows the joint formed between the core  1920  and the fluid fitting  1910 . The fluid and machine drive fittings may be attached, mated, or fixed to the core by methods including but not limited to a solvent bond, an ultrasonic weld, radiant heating, or by machined threads on outside surface  1950  of the fittings and the inside surface  1960  of the core. 
       FIG. 20  is an illustration of a fluid fitting  1910  of  FIG. 19A  in detail. The fitting  2010  has a conduit  2040  which extend through the piece for fluid flow into the core  1920  of  FIG. 19  from a material removal tool. The inner diameter  2080  may be used for accepting a fluid conduit from the tool. The fitting  2010  may have an o-ring or compression fitting, not shown, for retaining the fluid conduit with the fitting  2010 . The size and configuration of the openings  2060 ,  2080 , and  2040  may be varied and is not limited by the present description as would be known to those skilled in the art of making fluid fittings. One advantage of the present invention is that the porous pad cast onto the core may be fit with a wide variety of fittings  2010  to adapt the core to a variety of fluid sources, conduits, and or retaining mechanisms used with any polishing, scrubbing, or cleaning machine. 
       FIG. 21A  is a detailed illustration of the outside of the core  1920  of the  FIG. 19A . In  FIG. 21A  the core or base housing  2120  includes a number of slit or oval shaped channels  2124  through the core that are separated  2108  from each other along the housing  2120 . The slits would be filled with the porous pad material. The width  2116  of the slits may as well as their separation  2108  may be varied without limitation.  FIG. 21B  is a view of a cross section of the core  2120  whose diameter  2104  may be varied depending upon the application and requirements of the tool. The view shows base  2120  inner surface  2154  and outer surface  2150 , the porous pad material may contact both the outer and inner surfaces. The length  2136  of the slits may also be varied to permit greater fluid flow through the channels after being filled with a porous pad material. One of the slits at the bottom of the core is shown in cross section  2126  and is preferably filled with a porous pad material in a finished device to interlock the porous pad to the base  2120 . The inside surface of the core may be machined or molded to include one or more steps or stop for the fluid and tool fittings. The inner diameters of two step  2120  and  2128  are shown for illustrative purposes only. The depths  2144  and  2140  of the steps are also shown for illustrative purposes only. 
       FIG. 22  is a cross section of core in  FIG. 19A  illustrating placement of channels  2202  and  2204  for interlocking with a porous pad material through the core relative to one another by an angle  2200  which may be varied. The wall thickness  2110  of the core may be varied depending upon considerations such as but not limited to the strength of the core material, the desired volume of fluid held by the core, and the fluid pressure drop across the slit. Steps  2120  and  2130  on the inside of the core may also be varied in their diameter by choice of wall thickness  2110  of the core. 
       FIG. 23  is an illustration of a tool drive mounting fitting  1930  of  FIG. 19A . The tool mounting fitting  2316  has a keyed opening  2336  with a recess  2320  and optional sidewall taper  2330  defined by and angle which mates to a rotating element of a tool. The element, not shown, connects to the fitting  2316  which has been bonded or secured to the core and rotates the core and porous pad. The size and configuration of the keyed opening  2336  may be varied and is not limited by the present description as would be known to those skilled in the art of making. One advantage of the present invention is that the porous pad cast onto the core may be fit with a wide variety of fittings  2316  to adapt the core to any substrate coating machine&#39;s rotating fixture or spindle or to any polishing, scrubbing, or cleaning machine&#39;s rotating fixture or spindle. 
     Both the fluid fittings and the tool mounting fittings of the present invention may be configured for a zero clearance fitting by mating opposing surfaces with a gasket or o-ring. 
       FIG. 24  is a view of another example of an unassembled core  2400  for supporting a porous pad, not shown, that is molded to interlock the pad with channels  2424  through the core. The channels may be filled with a porous pad material for interlocking the pad material with the base  2400 . The core has an end  2420  into which the reduced end  2410  of the interchangeable fluid receiving fitting  2414  is inserted and end  2440  into which the reduced end  2430  of tool drive mounting fitting  2434  is inserted. The fluid fitting  2414  and machine drive fitting  2434  may be attached, mated, or fixed to the core  2400  by methods including but not limited to a solvent bond, an ultrasonic weld, radiant bonding, or by machined threads on outside surface of the fittings and the inside surface of the core. 
       FIG. 25  is a detailed illustration the fluid fitting  2414  of  FIG. 24 . Fluid fitting  2510  has a conduit  2500  which extend through the piece  2510  for fluid flow into the core  2400  of  FIG. 24  from a source of fluid from the material removal tool. The inner diameter  2520  may be used for accepting a fluid conduit from the tool. The fitting  2510  may also have for example but not limited to an o-ring or compression fitting, not shown, for retaining the fluid conduit with the fitting  2510 . The size and configuration of the openings  2500  and  2520  may be varied and is not limited by the present description as would be known to those skilled in the art of making fluid fittings. One advantage of the present invention is that the porous pad cast onto the core  2400  of  FIG. 24  may be fit with a wide variety of fittings  2410  to adapt the core to a fluid source, conduit, and or retaining mechanism used with any polishing, scrubbing, or cleaning machine. The fluid fitting has a tapered end  2414  whose diameter  2524  allows it to be inserted and bonded to the core  2400 . The size  2534  for the top of the fitting  2510  and the tapered end size  2550  may be varied with the length and height requirement of any tool to which the assembled device is designed for. 
       FIG. 26  is a detail illustration of the tool mounting fitting  2434  of  FIG. 24 . The tool drive mounting fitting  2600  has one or more keyed openings  2620  with a recess depth  2634  and opening  2610  with recess depth  2630  for mating to a rotating element or fixture of a tool. The keyed openings may be placed at an angle  2624  around the drive mount fitting  2600  and offset from center  2604 . The rotating element of the tool, not shown, connects to the fitting  2600  which has been bonded or secured to the core and rotates the core and porous pad. The fitting  2600  is inserted into to the inside of the core at its end with diameter  2638  and secured, by bonding, threaded seal or other sealing technique, to the inside of the base  2400 . The reduced diameter portion  2638  of the fitting with length  2640 . These dimensions may be varied depending upon the overall size requirements for the tool and the pad as well as the strength of the seal required. The size and configuration of the keyed openings  2620  and  2610  may be varied and is not limited by the present description as would be known to those skilled in the art of making. One advantage of the present invention is that the porous pad cast onto the core may be fit with a wide variety of fittings  2600  to adapt the core to any coating, polishing, scrubbing, or cleaning machine&#39;s rotating fixture. 
     Embodiments of the present invention may be used as a brush in an automated wafer cleaning station to clean wafer substrates. In some embodiments brushes from a single sized rotatable base can be for used in a number of different automated wafer cleaning stations to clean wafer substrates by interchange of fittings on the ends of the base. The cleaning station may be controlled in an automated way by a cleaning controller station. Other substrates such as but not limited to wafers, flat panel displays, optical devices, and hard disks could be cleaned or polished using similar station with modifications in substrate handling equipment and chemicals as would be known to those skilled in the art without undue experimentation. The wafer cleaning station may include a sender station, a cleaning stage, a spin-rinse and dry (SRD) station, and a receiver station. In a cleaning process, semiconductor wafers may initially be placed into the sender station. The sender station then delivers a wafer (one-at-a-time) to the cleaning stage. The cleaning stage may be divided into a first cleaning stage and a second cleaning stage, although having just one cleaning stage will also work. After passing through the cleaning stage, the wafer is passed through an exit spray in order to remove the cleaning fluids and any contaminants. The SRD station dries the wafer and then it may be delivered to the receiver station for temporary storage. 
     A brush mounting system includes a rigid brush core or mandrel on which a brush is mounted. The mandrel in turn, is mounted between brush mounting assemblies. One brush mounting assembly may be a conventional, motor-driven brush mounting assembly having a cylindrical spindle or other rotating fixture. The brush mounting assembly can be mounted to a wall of a wafer scrubbing device via a mounting member such as mounting plate. A bearing may be secured to the mounting plate and the spindle is rotatably mounted on the bearing. The portion of the other mounting assembly which can be connected to the rigid core has rotary motion transmitted to it by the rigid core and to supply cleaning liquid to the brush through the mounting assembly that is not motor driven. 
     Both the sender station and the receiving station are preferably adapted to receive a cassette containing a number of wafers. The first and second cleaning stages preferably include a set of PVA brushes of the present invention that are very soft and porous. These brushes are mounted brushes to the tool and are located horizontally from one another. The brushes include a base or brush core covered with a monolithic porous pad material that interlocks the porous pad material with the core. The brushes may be mounted to first ends of shafts for rotating the brushes. Rotary unions are mounted to second ends of these rotating shafts. The rotating shafts have central cavities formed therein which allow liquid to flow from the rotary unions through the shafts and into the inside of the brush base. The shafts have perforations in the regions where the brushes are mounted which allows liquid to be distributed from shafts to the inner surface of the brush base or core, through the porous pad material filling the through channels of the core and out to the surface of the brush. 
     A single brush may be used for material removal or cleaning of a single substrate surface. Alternatively, a pair of brushes may be used for scrubbing a top surface and a bottom surface, respectively, of a wafer or other substrate. Typically, the wafer is caused to rotate in a particular direction while the brushes rotate around an axis of rotation while the surface of the brushes are in contact with the surfaces of the wafer as illustrated in  FIG. 9 . The brushes are mounted on brush cores or a base material. The brush cores are configured to have at one end, a fluid inlet which connects to tubing or fluid conduit from the tool. The tubing will thus supply the desired fluids to the core within the brush base. The brush core with its plurality of holes or channels filled with porous pad material allows the fluids provided into the core to uniformly exit the brush core through the porous pad or brush material therefore evenly supplying the desired fluid to the brush or pad surface. The base with its plurality of channels filled with the porous pad material interlocks the porous pad material to the base and prevents or reduces walking or twisting of the brush nodes. 
     Wafers may be scrubbed in a horizontal or a vertical orientation. The brushes are configured to rotate in a desired direction such that both sides of the wafer are evenly scrubbed, using an equal and opposite pressure on each side of the wafer. For more information on vertical wafer scrubbing, reference may be made to U.S. Pat. No. 5,875,507, entitled “Wafer Cleaning Apparatus,” which is hereby incorporated reference. 
     The base housing of the present invention may be a cylinder, tube, or mandrel, and alternately may be a disk or shortened cylinder. The housing base preferably has an axis of rotational symmetry.  FIG. 4  and  FIG. 5A  illustrate non-limiting alternative embodiments of a rotatable base or fixture useful in the present invention. Any base shape that can be covered with a porous pad material, interlock with the porous pad material, and make proper contact with a substrate to be cleaned or polished may be used in the present invention. As shown in  FIG. 1 , the base has an inner surface  190  and an outer surface  120 . These surfaces are preferably cleaned to remove surface contamination such as oils and ionic contaminants prior to molding and coating the base. 
     A mold may be used to cast a smooth pad surface or a pad surface as shown in  FIG. 10B  or one with protrusions, the protrusions having a variety of shapes including but not limited to bristles and nodules as illustrated in  FIG. 6 . The mold may have a coating of perfluorinated material such as polytetrafluoroethylene applied to its surface to aid in release of the pad from the mold, the mold itself may be made from polytetrafluoroethylene, or the mold may be made in one or more segments. A release agent such as paraffin wax in THF may be applied to portions of the surface of the base or the base material may be chemically treated prior to molding. The porous pad material formed in the mold on the base is removed from the mold. 
     The inner and outer surfaces of the base may be smooth, knurled, or roughen with a hatch pattern of parallel or intersecting shallow surface channels to enhance porous pad material adhesion and interlocking with the base, and to promote fluid distribution. The surface channels may have a various shapes, such as but not limited to notched square or halve round to interlock the porous pad, and may or may not interconnect the inner and outer base surfaces.  FIG. 12  illustrates a non-limiting example of surface channels useful for interlocking a porous pad material to a substrate where the channels do not interconnect the inner and outer surfaces of the rotatable base. The surface channels retain the molded porous pad material and prevent it from being pulled or stretched out of the channel and away from the base. Such surface channels may include but are not limited to linear channels of various geometries along the axis of a tube, spiral channels, or circular surface channels at different radii across a platen base. It should be understood that the actual shape or geometry of the surface channels can be varied and may be eliminated altogether. The base and surface channels may also be provided with a variety of holes, pores, through channels or slits fluidly connecting the inner surface of the base with the outer surface of the base as illustrated in  FIG. 4 . The base may be any chemically inert polymeric material, including copolymers, materials useful in CMP cleaning processes, or CMP material removal processes. The base preferably includes chlorinated or halogenated polymers such as but not limited to CPVC, PVC, PVDF, PFA, and ECTFE. The base material has a thickness to make it rigid and maintain its shape during rotation and pressing against a substrate. Additionally the thickness should provide support to inserted fittings. The wall thickness may be greater than about 0.05 inches and preferably ranges from about 0.05 inches to greater than about 0.75 inches, though others may also be useful. In one embodiment, the holes or through channels are formed closer together near the ends of the brush than in the center of the brush. As a result, a greater amount of liquid is provided to the ends of the brush than to the center. This is a particular advantage in wafer cleaning operations where a greater effective wafer surface area near the ends of the brush must be cleaned. 
     The porous pad covering the outer surface of the base fills one or more of the surface channels, pores, holes, through channels, and or slits and interlocks the porous pad material with the base housing. The porous pad is cast onto the base. This interlocking maintains the alignment of the protrusions on the porous pad surface and provides consistent contact with substrates. By interlocking the channels in base with the porous pad, the movement of the pad by walking or twisting is reduced or eliminated. The porous pad may interlock with the channels of the base by filling one or more of the channels. Preferably the channels or surface of the base have a shape to mechanically and physically prevent porous pad cast or molded into the channels from being removed by pulling or twisting of the porous pad during rotation. The porous nature of the brush or pad will absorb and evenly distribute the fluids throughout the brush or pad. The porous brush or pad can absorb and distribute fluids to substrates by flow, wicking, or capillary action throughout the brush or pad. If desirable through channels may be left unfilled by the porous pad material during the molding process by filling them with an insoluble solid or packing them with a plastic plug and then removing the plug after molding. 
     In a preferred embodiment, the core for a cylindrical base used in a roller or brush may have a outside diameters ranging between about 0.50 inch and about 5 inches. For disk shaped bases the diameter may range to 12 or more inches. By covering a portion of the inner surface with the porous pad or brush material, the actual volume of the core may be reduced. The layer of porous material covering the inner surface of the base may be less than about 15 mm. 
     Endcaps such as but not limited to  214  illustrated in  FIGS. 2 and 212  also illustrated in  FIG. 2  may be connected to the base to provide for connection of the rotatable base to a cleaning tool, a pressurized source of fluid, a fixture for rotating the base from a tool, or a combination of these. As with the base itself, the endcaps may be molded to the housing, may be machined into a stock piece of base material, or made separately and bonded to the base. These non-limiting examples illustrate the variety of way the base housing of the present invention may be connected or mated to an existing tool for receiving fluid and rotating to perform a material removal function. A variety of fittings for connection to a wide variety of tools may be coupled to the base. Endcaps or other fitting may be attached or mated to the core. Such fittings include but not limited to fluid fittings  1910  and  2414  and machine drive fittings  1930  and  2434  shown by the non-limiting examples in  FIG. 19A  and  FIG. 24  respectively. The endcaps may be made separately and bonded to the base using chemical, radiant, or ultrasonic bonding techniques. These non-limiting examples illustrate the variety of way the base housing of the present invention may be connected or mated to an existing tool for receiving fluid and rotating the base coated with a porous pad material interlocked with the base to perform a material removal function. A variety of fittings for connection to a wide variety of tools may be coupled to the base. 
     Because the volume within the bore is rapidly filled, the bore will be pressurized rapidly and the fluid will be ready to quickly outflow through the plurality of through channels or holes filled with the porous pad material and out to the surface of the porous pad material covering the core. The plurality of holes or through channels may have a diameter ranging between about 0.005 inch to about 0.50 inch. A porous sintered tube stock of ceramic or polymeric construction with micron size holes may also be used as a base. A combination of different diameter through holes may be used and distributed across the mandrel or base. Larger diameter holes or surface area through channels can distribute fluid from the core to the porous pad surface over a wider area and result in a more even distribution of fluid throughout the entire length of the porous pad covering the brush. Varying the number of holes or slits in the base may also be used to increase the surface area for fluid flow through the base. 
     The interlocking of the base and the porous pad in a device of the present invention can be modified for use in coating a substrate with a fluid or for material removal from any number of substrate types, for example, semiconductor wafers, hard drive discs, flat panel displays, and the like. Additionally, the brush core or brush base can be modified in its length or diameter for substrate scrubbing and material removal applications of any size, for example, 100 mm wafers, 200 mm wafers, 300 mm wafers, larger wafers, small hard disks, etc. For 300 mm diameter or large wafers the length of the rotatable base may be greater than about 25 cm. It should also benoted that any number of fluids can be delivered through the brush or pad, for example, DI water, ammonia containing chemical mixtures, HF containing chemical mixtures, surfactant containing chemical mixtures, and many other variations. 
     The plurality of surface channels or through channels are formed in the base. The channels can be positioned from a center point of the base to an outer edge of the base in a symmetric or asymmetric pattern for distributing fluid to the outer surface of the porous pad material. The channels may be the same size or different sized across the base. Preferably the channels may be positioned across the base to deliver a greater volume of fluid to the outer edge of the base than to the center of the base. The fluid within the pores of the pad material may be from a source of pressurized fluid that is in fluid communication with the porous material in the channels of said base through the inner surface of said base. 
     Fluid delivery is accomplished by implementing brush or pad cores that have a plurality of holes that allow fluids to be fed into the brush or pad core at a particular pressure to be released into an outer brush or pad surface. During use, liquid flows from inside of the base through one or more perforations or through channels in the base filled with the porous base material. After flowing through the porous base material in the perforations, the fluid is distributed throughout the porous pad material covering the outside the base where it is used with the substrate to be treated. Besides fluid inlet pressure, the flow of liquid from the inner surface of the base to the housing can be controlled by appropriately selecting the dimensions of the longitudinal slits, holes or pores in the base through which the liquid must flow. Generally, increasing the cross-sectional area increases the flow of liquid through the particular slit or hole. Thus, the flow of liquid from the shaft to the brush or pad housing is readily controlled by selecting the cross-sectional area of the through holes of the distributor. Variation in the surface area of the perforations or through channels in the base may be made along the length or diameter of the base. This is illustrated schematically in  FIG. 1A  where through channels  130  and  180  are different size, and this is also illustrated schematically in  FIG. 4  where through holes  484  and  480  differ in size and also differ from through channels  450 . The wall thickness of the base will also determine the flow of liquid from the inner surface to the outer surface with a thicker base permitting less flow than a thicker base. Lastly, the porosity and surface energy of the porous base material contribute to the conductance of fluid. A higher porosity and a surface energy like the fluid are preferable to increase fluid flow and maintain surface wetting. 
     As shown in  FIG. 12 , the device for removing materials, particles, or contaminants from substrates includes a rotatable base for supporting a porous pad material. The base include an inner surface and an outer surface and a plurality of channels in the base for interlocking the porous pad material with the base. A porous pad material covers at least a portion of the outer surface of the base and is used for removing material from substrates. The porous pad material fills one or more of the channels in the base and interlocks the porous pad material with the base. As illustrated in  FIG. 2  the channels fluidly connect the inner surface with the outer surface of the base. The through channels  250  in the base distribute fluid from the inner surface of the base to the outer surface of the base through the porous pad material and also interlock the porous base material with the base. The through channels may be notched, grooved or roughen to aid in retaining or adhering and interlocking the porous material. Preferably porous pad material also covers at least a portion of the outer surface of the base for removing material from substrates. The device in  FIG. 16  for removing materials, particles, or contaminants from substrates includes a rotatable base for supporting a porous pad material. The base include an inner surface and an outer surface and a plurality of channels in the base for interlocking the porous pad material with the base. A porous pad material covers at least a portion of the outer surface of the base and is used for removing material from substrates. The porous pad material fills one or more of the channels in the base and interlocks the porous pad material with the base. As illustrated in  FIG. 21B  the channels  2126  fluidly connect the inner surface with the outer surface of the base. The through channels  2126  in the base distribute fluid from the inner surface of the base to the outer surface of the base through the porous pad material (not shown). The through channels may be notched, grooved or roughen to aid in retaining or adhering the porous material. Preferably porous pad material also covers at least a portion of the outer surface of the base for removing material from substrates. 
     The porous pad material may cover a base in the shape of a roller where at least a portion of the outer surface of a sidewall of a cylinder that is used to support the porous pad material is covered. Alternatively, the porous pad material may be a base in the shape of a pad or disk as shown in  FIG. 5A  and  FIG. 5B  where the porous pad material covers at least a portion of the outer surface of the endcap of a cylinder and the rotatable base is mounted to a single fitting which is used for both machine drive and fluid flow to the center of the base. 
     The porous pad material covers at least a portion of the outer surface of the base. The porous pad material may be bonded to one or more surfaces of the rotatable base to form an adherent layer by chemical, mechanical, or a combination of these bonds. After forming an adherent layer with the rotatable base housing surface, the porous pad material permits fluid flow through the porous pad material. Subsequent layers of porous pad material may be molded or cast onto the first porous pad material bonded to the base. The additional porous pad layer may be chemically, mechanically, or a utilizing a combination of both, bonded to the first porous layer while maintaining porosity to fluid flow from fluid received from flow channels in the base. Optionally the porous pad material may fill one or more of the fluid flow channels in the base. 
     The porous pad material covers at least a portion of the outer surface of the base and the porous pad material fills one or more of the through channels in the base. Preferably the porous pad material filling the through channels and covering the base surface are continuously formed into a monolithic structure that interlocks the porous pad material with the base. More preferably the porous pad material fills the through channels or the base and covers both the outer surface and the inner surface of the base in a continuously formed monolithic structure of the porous base material. The porous base material covering the outer surface of the base or housing may have a thickness greater than about 1 mm and is preferably from about 1 to about 20 mm. 
     The devices of the present invention can also include a fluid in the porous pad material which may be pressurized. Fluids may include water and aqueous chemistries such as but not limited to ammonium hydroxide or hydrofluoric acid. The source of pressurized fluid is in fluid communication with the porous material in the channels of device base through the inner surface and core of the base. 
     The porous pad material covering the base preferably includes surface protrusions or recesses for removing particles or materials from a substrate or for distributing fluid across a substrate. The porous pad material with protrusions fills one or more of the channels in the base and interlocks the porous pad material with the base. The channels in the base maintain the alignment, height, and or distribution of protrusions on the surface of the porous pad material. Preferably the channels fluidly connect the inner surface with the outer surface of the base. The through channels in the base distribute fluid from the inner surface of the base to the outer surface of the base through the porous pad material. 
     The roller and pad devices of the present invention may be made by the acts which include pouring a combination of un-polymerized sponge monomer and a catalyst for polymerizing the monomer into a mold. The mold includes a housing or base with preformed channels that are filled with the porous pad material to interlock the porous pad material with the housing. The combination of un-polymerized sponge monomer and a catalyst in the mold are cured and the housing with porous pad material filling the channels in the housing released from the mold. The final product is a brush or pad that is cast onto the base. Preferably the mold also includes an outer mold for forming a surface texture of the porous pad material covering the housing. The outer mold is used to control the shape, height, and thickness of the outer porous pad material. The protrusions may be but are not limited to square shaped or rectangular shaped cylinders. The protrusion or node height may be less than about 5 cm, and their diameter less than about 2 cm. Continuous surface protrusions may also be formed with lengths similar to the brush or pad and widths of about 2 cm or less. More preferably the mold includes an inner mold for controlling the thickness of the inner layer of the porous pad material coating the inner surface of the housing. 
     Preferably the porous pad material interlocked with the base includes polyvinylalcohol and the housing includes polyvinylchloride. Preferably the porous pad material of the present invention includes less than part per million levels of harmful impurities such as metallic ions like calcium and iron and chloride ions. The porous polymeric pad member is substantially free from loose portions (e.g., un-cross-linked) of the porous polymeric member greater than about 1 micron in size, or greater than about 0.5 micron in size, or greater than about 0.1 micron in size. 
     As shown in  FIG. 3B  and  FIG. 5B , the devices can range in size and shape, depending upon the application. According to an embodiment, the device can be shaped as brush rollers, which have protrusions on their surface, or brush rollers that have smooth surfaces. These brush rollers have shapes and sizes to meet the particular cleaning application or material removal from devices such as semiconductor wafers, hard disks, and other substrates. The device can also be in the form disks, puck brushes, and plugs. 
     The cast on brushes of the present invention may be made using a suitable material that is film, porous, elastic, and has certain abrasion resistiveness. In most embodiments, the main raw starting material for the device is polyvinyl alcohol, but can be others. As merely an example, polyvinyl alcohol is used to form a polyvinyl acetal porous elastic material. The porous material varies in characteristic depending upon cleanliness, type of pore forming agent or process, type of aldehyde employed for the conversion of a polyvinyl alcohol to a polyvinyl acetal, and other factors. Preferably the PVA sponge material may be prepared from acid catalyst and an aldehyde mixed with a water solution of polyvinyl alcohol produced from polyvinyl acetate homopolymer or polyvinyl acetate containing copolymers less than 25% by weight or alloyed with water soluble polymers to no greater than 10% by weight of solids. Other factors which affect the properties of the porous material also include the relative proportions of reactants, reaction temperature and time, and the general condition and starting materials in the manufacturing process. Cleanliness of the manufacturing process is also important in the manufacture of these devices. 
     The outer brush or pad surface is made out of a very porous and soft material so that direct contact with the delicate surface of a substrate does not cause scratches or other damage. Preferably, the outer brush surface is made out of a material that includes polyvinyl alcohol (PVA) foam. Although, other moldable materials such as but not limited to nylon, polyurethane, or a combination of polyurethane and PVA or other copolymers that interlock with channels in the base and that do not scratch substrate surfaces and provide suitable material removal for the process may be used including U.S. Pat. No. 4,083,906 Schindler (polyethylene glycolpolyacrylamide); U.S. Pat. No. 5,311,634 Andros, Nicholas (surfactant air foam systems and core cast); U.S. Pat. No. 5,554,659 Rosenblatt, Solomon (Surfactant air foam); U.S. Pat. No. 2,609,347 Wilson, Christopher (Early surfactant foam systems); and U.S. Pat. No. 3,663,470 Nishimura et al (Early starch based sponges), the contents of which are incorporated herein by reference in their entirety. 
     Molding a textured brush or pad onto a core eliminates the need for removing newly cast brushes from a mandrel reducing some losses of brushes damaged during this process. Cleaning of sponges on cores to rid them of excess reagents and fugitive particles is improved during wash cycles because they agitate with greater aggression. 
     Cleaning effectiveness and material removal efficiency of the brushes and pads of the present invention may also depend upon a porosity and pore size of the porous pad material. Porous pad material should provide flexibility to the pad material but not have too much porosity that the pad material looses its strength. The porosity can be more than about 85%. In devices where porosity is less than 85% for polyvinyl acetal porous elastic materials, the pad may have poor flexibility. The porosity may less than about 95%, since a greater porosity value may provide poor strength. Other characteristics include a desirable average pore size or opening. The pore size opening in some embodiments ranges from about 10 micron to about 200 microns. In devices where the average pore opening is less than 10 micron, the porous elastic material may have poor elasticity and/or flow properties, thus making the performance of the cleaning roll unsatisfactory. Alternatively, the average pore opening of more than 200 microns can be unsuitable for a cleaning roll because of inconsistent pore configuration. Of course, the selected pore size and porosity depend upon the application and materials used to form the porous pad material. 
     The polyvinyl acetal porous elastic material usable for the present invention can be produced in a known manner, for example, by dissolving at least one polyvinyl alcohol having an average degree of polymerization of 300 MW to 3,000 MW and a degree of saponification of not less than 80% in water to form a 5% to 30% aqueous solution, adding a pore forming agent to the solution, and subjecting the solution to reaction with an aldehyde such as formaldehyde or acetaldehyde until the material becomes water-insoluble. In this case the polymer is 50 to 70 mole % of acetal units. In some embodiments, where the polymer has less than 50 mole % of acetal units, the retained polyvinyl alcohol may ooze out from the product upon use and undesirably contaminate the article to be cleaned. Where the polymer has more than 70 mole % of acetal units, the device may have poor elasticity and flexibility in other embodiments. 
     Although the above devices are generally described in selected shapes and sizes, alternative configurations can also be used. As merely an example, the polymeric product can have a gear-like configuration, which has numerous parallel grooves formed at an angle to the roll. Additionally, protrusions or projections on the surface of the foam product can include a variety of shapes, e.g., circular, ellipsoidal, rectangular, diamond, cylindrical pyramidal or the like. Preferably the protrusion has a square or rectangular shape profile. The spacing between adjacent protrusions may be greater than about 1 mm and preferably range from about 1 mm to about 30 mm or more. 
     Other techniques can also be used to manufacture porous polymeric devices used for surface treatment applications. These techniques include, among others, an air injected foam or sponge product as well as others. 
     Typically, the polishing pad includes brushes that perform the mechanical aspect of the CMP process. Brushes can be in the form of a pad or in the form of a roller. The roller can also be used to clean the wafer, and commonly includes a plurality of bristles, or protrusions around the outer cylindrical surface of the roller. Roller brushes may have rectangular protrusions set at a fixed pitch across the entire body of the roller. An example of one such roller brush in cross section is shown in  FIG. 12 . In applications where a square or rectangular protrusion such as shown in  FIG. 12  collects or proliferates contamination (e.g., slurry build-up) around the outer edge of the protrusion, which can also cause scratches to the underlying substrate, the protrusions are preferably rounded or spherical in profile as shown in  FIG. 12B  and  FIG. 12C , respectively. 
     Various aspect and advantages of the present invention may be understood by reference to the following non-limiting examples. 
     Example 1 
     A quantity of Airvol V-107 was purchased from Air Products Inc. The polyvinylalcohol was dissolved as follows: 180 g polyvinylalcohol V-107 and 600 grams of tap water. The mixture was mixed and heated to about 100.degree. C. until all the polyvinyl alcohol dissolved. 
     From this mixture, small test batches were made as follows: 175 grams. Polyvinylalcohol solution 30%; 48 grams formaldehyde 37%; 27 grams sulfuric acid 36%; and 13.5 grams corn starch. These ingredients were mixed in the order starch, H.sub.2SO.sub.4, formaldehyde, and last the 30% PVA solution. This new mixture was free of entrained air. The solution was of low viscosity, opaque, and at room temperature. All of this material was poured into a polyvinylchloride mold and heated to 70.degree. C. for three hours. Inspection of the sponge formed in the mold revealed excess bonding to the PVC mold surface. Some sponge material was treated with H.sub.2O.sub.2/NaHCO.sub.3 and investigated. 
     The sponge was well developed, white, soft, and conformed well to the mold with good wicking action. PVC surfaces may be pre-treated with a mold release agent as 10% solution of paraffin wax in THF. 
     Example 2 
     Another part of this invention is a method for preparing a PVC brush mold so that the inventive cleaning brush can be removed efficiently the mold without tearing the bristles from the exterior surface of the brush. It has been found that prior to injecting a PVC brush mold with PVA, that applying a preferred mixture of tetrahydrofuran (THF) and paraffin to the PVC mold creates a coating on which PVA does not appreciably stick. Upon completion of manufacturing, using a PVC mold prepared by the method described, the brush can be easily removed from the mold by hand. 
     Without wishing to be bound by theory, the paraffin and THF mixture, when applied in proper proportions is believed to act upon the PVC material by forming an alloy layer comprised of some or all of the elements PVC, THF, and paraffin. This alloy layer is in the form of a visible sheen which can be physically scratched off of the mold until the pure PVC located below the alloy layer, is exposed. The alloy layer is durable and can remain on the mold through a plurality of manufacturing cycles. When the alloy layer becomes removed from the PVC mold, it can be re-coated with the paraffin and THF mixture, to regenerate the non-stick qualities of the mold. 
     A preferred mixture of paraffin and THF which has been found to achieve the proper nonstick coating characteristics is to add about 10 grams of paraffin to 1 liter of THF (10 g/l). This preferred mixture results in good fluid characteristics for flowing easily into the mold and readily achieves the creation of the alloy layer. However, an effective range of paraffin to THF has been found to be approximately 5 g/l to 20 g/l. Below approximately 5 g/l, the THF volatilizes too quickly for it to act effectively upon the PVC and create the allow layer, while above approximately 20 g/l the paraffin crystallizes and the mixture is not fluid enough to be useful for coating a PVC brush mold. 
     As a first step in manufacturing the inventive cleaning brush, a PVC mold is provided. The mold is comprised of a PVC pipe, a core and end caps for fitting on the PVC pipe. The PVC pipe can be a standard cylindrical PVC pipe with a plurality of properly sized holes, for forming bristles, drilled through the pipe walls. The density of the bristle holes are approximately 70 per square inch, to match the bristle density of the finished brush. The end caps are provided for fitting on each end of the pipe, thereby providing a means for preventing the outflow of PVA material from each end, when the mold is filled. A core is provided for fitting in a centering position within the hollow cylindrical interior of the PVC pipe, the core for creating the hollow inside diameter of the finished brush. Next, the PVA contacting surfaces of the mold are coated with the paraffin and THF mixture and the alloy layer is allowed to form. When a dry sheen appears on the PV A contacting surfaces, the alloy layer is formed and the mold is ready to be used in production. A plastic wrap is next applied around the mold to keep the PVA from flowing out of the bristle holes. Next, an end cap is placed on the lower end of the pipe and the mold is filled with the PVA mixture. 
     The PVA mixture is comprised of formaldehyde or para-formaldehyde, acid catalyst, PVA, and starch. The starch is a pore former, which creates the porous quality of the finished brush. Upon filling the mold with the PVA mixture the second end cap is placed on the upper end of the pipe. Next, the mold is vertically spun along its long axis at a sufficient velocity to allow the PVA mixture to flow into the bristle holes and to force air bubbles from the PVA. After spinning the upper cap is removed. The forcing of air bubbles from the PVA mixture causes the level of PVA to drop inside of the mold. The mold is next topped-off with an additional amount of PVA mixture sufficient to fill the mold to an appropriate level for fully forming the inventive brush. The mold can be spun again to get rid of any further minor quantity of air bubbles, if desired. Next the mold is placed in an oven to cure overnight, about 16-24 hours, at about 125 Fahrenheit. When finally cured, at least one endcap and the core are removed to access the finished brush. The brush can then be removed from the pipe by grasping an end of the brush by hand and working it free from the pipe. 
     Example 3 
     This prophetic example describes cleaning a wafer having a layer of copper metal following a chemical mechanical planarization process. The wafer may be introduced into a first brush box of the cleaning system. In the first brush box cleaning chemical can be applied to the wafer through the brushes which are formed of a cast on core porous pad material interlocking to the base core of the brush. The cleaning chemical applied through the brushes in the first brush box controllably transforms copper material on the substrate surface into a water soluble form. The copper material is transformed into a water soluble form in order to remove a controlled amount of copper from the surface of the wafer. The wafer can be moved from the first brush box to the second brush box. In the second brush box a second cleaning chemical may be applied to the surface of the wafer through the brushes of the second brush box in order to clean the wafer surface and clean the brushes of copper. The second cleaning chemical may contain the same chemical composition as the cleaning chemical in the first brush box. The purpose of the second cleaning chemical applied through the brushes is to clean the brushes of copper and other materials that may have been cleaned from the wafer surface. The second cleaning chemical may be applied through the brushes for between about 3 seconds and about 10 seconds. Next the wafer can be rinsed with deionized (DI) water by flowing water through the brushes of the second brush box to remove the second cleaning chemical from the wafer surface and the brushes. The wafer surface is rinsed preferably for between about 20 seconds and about 40 seconds. After the operations in the second brush box, the wafer may be transferred to a spin, rinse, and dry (SRD) station after which the wafer may then be stored in an output station for subsequent processing. 
     Example 4 
     In this prophetic example, the brush with cast on a core porous pad material interlocking with the brush substrate is used with an etchant to remove a controlled layer of an oxide surface and to maintain a hydrophilic surface. 
     The CMP process can be performed in a scrubber that scrubs both sides of a workpiece simultaneously. In the cleaning process hydrofluoric acid (BF) solution can be delivered to the core of a brush having a porous PVA pad layer that interlocks with the brush core. After delivering the hydrofluoric acid (HF) solution to the brush core, the HF solution can be applied to the workpiece through the channels filled with the porous pad material of the brush. This can be followed by chemical mechanical scrubbing of the workpiece with the brush. The solution may be applied concurrently with the brush scrubbing of the workpiece. 
     The concentration of the BF solution can be in the range of approximately 0.005%-1.0% BF, depending upon the amount of oxide to be removed. The solution preferably includes a mixture of approximately 0.005 percent HF in water. The HF solution can be applied to the wafer for a predetermined amount of time, for example, 20-40, or 25-35 or about 35 seconds. 
     Example 5 
     In this prophetic example, a brush with porous pad material interlocking with the brush substrate is used in a cleaning step in the manufacturing process an integrated circuit such as a microprocessor or a dynamic random access memory device. 
     Methods for making an electronic device such a microprocessor or a dynamic random access memory device are well known to those skilled in the art. These devices include metal interconnect and dielectric layers which are applied to active devices on the wafer surface to form electrical contact with external electronic circuitry and devices. These dielectric and metal layers are formed using standard lithography, material deposition, and chemical mechanical planarization techniques. After chemical mechanical planarization, the wafer is cleaned to remove residual slurry and chemicals by contacting the wafer including electronic devices and interconnects with a molded on core PVA brush. This brush has a plurality of channels in the brush base for interlocking the porous PVA brush pad material with the brush base and for distributing cleaning fluid to the surface of the wafer with the electronic devices. Once the wafer has been cleaned it can undergo further processing steps to complete its fabrication including sealing and dicing the wafer to package the individual integrated circuit devices. 
     Example 6 
     This prophetic example illustrates how a cast on core brush may be made and bonded to fluid and machine drive fittings. As a first step in manufacturing the inventive cleaning brush, a PVC mold is provided. The mold is comprised of a PVC pipe, a core and end caps for fitting on the PVC pipe. The PVC pipe can be a standard cylindrical PVC pipe with a plurality of properly sized holes, for forming bristles, drilled through the pipe walls. The density of the bristle holes are approximately 70 per square inch, to match the bristle density of the finished brush. The end caps are provided for fitting on each end of the pipe, thereby providing a means for preventing the outflow of PVA material from each end, when the mold is filled. A core is provided for fitting in a centering position within the hollow cylindrical interior of the PVC pipe, the core for creating the hollow inside diameter of the finished brush. A plastic wrap is next applied around the mold to keep the PVA from flowing out of the bristle holes. Next, an end cap is placed on the lower end of the pipe and the mold is filled with the PVA mixture. 
     The PVA mixture is comprised of formaldehyde or para-formaldehyde, acid catalyst, PVA, and starch. The starch is a pore former, which creates the porous quality of the finished brush. Upon filling the mold with the PVA mixture the second end cap is placed on the upper end of the pipe. Next, the mold is vertically spun along its long axis at a sufficient velocity to allow the PVA mixture to flow into the bristle holes and to force air bubbles from the PVA. After spinning the upper cap is removed. The forcing of air bubbles from the PVA mixture causes the level of PVA to drop inside of the mold. The mold is next topped-off with an additional amount of PVA mixture sufficient to fill the mold to an appropriate level for fully forming the inventive brush. The mold can be spun again to get rid of any further minor quantity of air bubbles, if desired. Next the mold is placed in an oven to cure overnight, about 16-24 hours, at about 125 Fahrenheit. When finally cured, at least one endcap and the core are removed to access the finished brush. The brush can then be removed from the pipe by grasping an end of the brush by hand and working it free from the pipe. A fluid fitting as shown in  FIG. 4  and a machine drive fitting as shown in  FIG. 4  made from PVC stock material may be solvent bonded to the PVC core. 
     Although the present invention has been described with reference to various embodiments, persons skilled in the art will recognize that changes may be made in form and detail without departing from the spirit and scope of the invention. For example, the wafer can be a generally circular silicon wafer, glass wafer, ceramic wafer, oxide wafer, tungsten wafer although other types of wafers can be used. Further, although various values, materials and dimensions have been provided, it is understood that these values, materials and dimensions are only illustrative and not limiting and that other values, materials and dimension can be used. For example, instead of slots having rectangular cross-sections, slots having other cross-sectional shapes such as semicircular slot can be used. Further, although various liquids have been set forth, it is understood that substantially any liquid or chemical can be used with a wafer cleaner and brush assembly in accordance with the present invention. For example, various alcohols, surfactants, ammonia based solutions, buffer solutions, high pH solutions and low pH solutions can be used. Thus, the invention is limited only by the following claims.
The present invention includes methods and materials for cleaning materials, particles, or chemicals from a substrate with a brush or pad. The method comprising: engaging a surface of a rotating wafer with an outer circumferential surface of a rotating cylindrical foam roller, the cylindrical foam roller having a plurality of circumferentially and outwardly extending spaced apart nodules extending from the outer surface, each nodule defining a height extending from the outer surface of the cylindrical foam roller to a substrate engagement surface of the nodule, the substrate engagement surface of one or more of the nodules having a rounded configuration; and positioning the cylindrical foam roller on the substrate such that the one or more nodules are positioned to have only the rounded substrate engagement surface contact the substrate such that no linear surface of the one or more nodules contacts the substrate.