Magnesium hydride films deposited on flexible substrates: Structure, morphology and hydrogen sorption properties
1.8 micrometer-thick magnesium hydride films were synthesized in a single-step process by reactive plasma-assisted sputtering. The MgH2 thin films, which were deposited on two types of flexible surfaces (namely graphite and polyimide foils) were found to adhere on both substrates. In all cases, XRD analysis revealed an as-deposited thin film consisting of alpha-MgH2, a tetragonal, rutile-type crystal structure (space group \#136). The hydrogen sorption capacities of the uncapped films were studied over successive desorption/absorption cycles performed at 350 {\textdegree}C. The first desorption always shows a slow kinetics that can be explained by a superficial oxidation of the films. However, once the passivating layer is removed, the following dehydrogenations occur faster. Multiple cycling of the film deposited on polyimide resulted in delamination of the film and its conversion into loose powder. As for MgH2 deposited on the flexible graphite substrate, a fully reversible capacity was observed over 28 cycles with no delamination of the film. Upon cycling, the microstructure of the film has evolved from homogeneous fibrous to an untextured morphology with a higher degree of crystallinity.