Wave Model for Atomic Systems
In the first chapter from Volume I, we have shown that the normal curves C of the wave surface of a system described by the Schrödinger equation, can be used to calculate the constants of motion of the system. We show that the motions of the electrons can be separated, and the projection of the C curve from the R 3 N space of coordinates on the space x a , y a , z a of the electron e a , denoted by C a , can be calculated with the aid of the central field approximation. Our method is similar to the central field method, applied in the frame of the atomic and molecular orbitals model. The energy of the system is calculated with the aid of the Bohr quantization relation, which is valid for the C a curves. The accuracy of our calculations is comparable to the accuracy of the Hartree–Fock method.