section_path: Composition
section_name: Composition
paragraph_text: Composition
  
  Coal consists mainly of a black mixture of diverse organic compounds and polymers. Of course, several kinds of coals exist, with variable dark colors and variable compositions. Young coals (brown coal, lignite) are not black. The two main black coals are bituminous, which is more abundant, and anthracite. The % carbon in coal follows the order anthracite > bituminous > lignite > brown coal. The fuel value of coal varies in the same order. Some anthracite deposits contain pure carbon in the form of graphite.
  
  For bituminous coal, the elemental composition on a dry, ash-free basis of 84.4% carbon, 5.4% hydrogen, 6.7% oxygen, 1.7% nitrogen, and 1.8% sulfur, on a weight basis. This composition reflects partly the composition of the precursor plants. The second main fraction of coal is ash, an undesirable, noncombustable mixture of inorganic minerals. The composition of ash is often discussed in terms of oxides obtained after combustion in air:
  
  Of particular interest is the sulfur content of coal, which can vary from less than 1% to as much as 4%. Most of the sulfur and most of the nitrogen is incorporated into the organic fraction in the form of organosulfur compounds and organonitrogen compounds. This sulfur and nitrogen are strongly bound within the hydrocarbon matrix. These elements are released as SO and NO upon combustion. They cannot be removed, economically at least, otherwise. Some coals contain inorganic sulfur, mainly in the form of iron pyrite (FeS). Being a dense mineral, it can be removed from coal by mechanical means, e.g. by froth flotation. Some sulfate occurs in coal, especially weathered samples. It is not volatilized and can be removed by washing.
  
  Minor components include:
  
  As minerals, Hg, As, and Se are not problematic to the environment, especially since they are only trace components. They become however mobile (volatile or water-soluble) when these minerals are combusted.