section_path: History/On Earth
section_name: On Earth
paragraph_text: On Earth
  
  One factor in estimating when water appeared on Earth is that water is continually being lost to space. H O molecules in the atmosphere are broken up by photolysis, and the resulting free hydrogen atoms can sometimes escape Earth's gravitational pull. When the Earth was younger and less massive, water would have been lost to space more easily. Lighter elements like hydrogen and helium are expected to leak from the atmosphere continually, but isotopic ratios of heavier noble gases in the modern atmosphere suggest that even the heavier elements in the early atmosphere were subject to significant losses. In particular, xenon is useful for calculations of water loss over time. Not only is it a noble gas (and therefore is not removed from the atmosphere through chemical reactions with other elements), but comparisons between the abundances of its nine stable isotopes in the modern atmosphere reveal that the Earth lost at least one ocean of water early in its history, between the Hadean and Archean eons.
  
  Any water on Earth during the latter part of its accretion would have been disrupted by the Moon-forming impact (~4.5 billion years ago), which likely vaporized much of Earth's crust and upper mantle and created a rock-vapor atmosphere around the young planet. The rock vapor would have condensed within two thousand years, leaving behind hot volatiles which probably resulted in a majority carbon dioxide atmosphere with hydrogen and water vapor. Afterward, liquid water oceans may have existed despite the surface temperature of 230 °C (446 °F) due to the increased atmospheric pressure of the CO atmosphere. As the cooling continued, most CO was removed from the atmosphere by subduction and dissolution in ocean water, but levels oscillated wildly as new surface and mantle cycles appeared.
  
  Geological evidence also helps constrain the time frame for liquid water existing on Earth. A sample of pillow basalt (a type of rock formed during an underwater eruption) was recovered from the Isua Greenstone Belt and provides evidence that water existed on Earth 3.8 billion years ago. In the Nuvvuagittuq Greenstone Belt, Quebec, Canada, rocks dated at 3.8 billion years old by one study and 4.28 billion years old by another show evidence of the presence of water at these ages. If oceans existed earlier than this, any geological evidence has yet to be discovered (which may be because such potential evidence has been destroyed by geological processes like crustal recycling). More recently, in August 2020, researchers reported that sufficient water to fill the oceans may have always been on the Earth since the beginning of the planet's formation.