Old man Yama's fit is kinda basic but he's the head captain so it makes sense he would be the default but the purple ribbon in the beard and the way he always sits like a boss really brings his rating up. Soi Fon also looks kinda basic with her captain's coat on, the yellow sash adds a nice pop of colour, but when she takes that off and has her whole back exposed that fit goes hard. Gin's fit is also basic but with his demeanour he kinda pulls it off but it's still just mid Unohana with the long front braid and that belt really shows a unique style that works for her and it totally distorts her body shape so you don't know that she has some serious cannons under there. Aizen's captain fit was as basic as they come, he baically looked like a high school maths teacher although he did prove the troupe of becoming hot when you remove your glasses and let your hair down. Byakuya's fit seems kinda basic but accessorising with the scarf and those hair pins really make him stand out and then later on when he gets the coat with the high collar and the gold edges, my boy really upgrades his fit after Aizen's defeat. Komamura's armour goes hard and  even after he removed the helmet the wooden pauldrons and gauntlets really give him and intimidating presence, although he is also 9 foot tall. Kyoraku stands out the most mostly because he wears a bright pink kimono, that along with the hat gives him a nice laid back style that is perfect for him and that nice light blue belt that fades down in to white was a great choice. Tosen's fit goes harder than it has any right to; the purple belt, the orange scarf that twirls up and the visor, when he betrayed the SS they lost half their style points. Toshiro is kinda basic but his hair is always on point and that sash with the clasp to hold his sword on his back really pushes him up in the style rankings and when he later turns that sash in to a scarf that was an upgrade.Kenpachi's fit goes hard, his hair looks kind goofy but the rest of his fit more than makes up for it, the exposed chest showing off some bandages and the rough cut sleeveless coat is an immaculate choice. Mayuri's fits always go crazy, this man could probably cure cancer and invent time travel but he's spending that time curating the most ostentatious fits known to man and I'm down for it. Not much to say about Ukitake, his fit is real basic and doesn't really change much at all.