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lee adams
Na
Na
1,3-cyclohexanedione









































1,3-cyclohexanedione is an organic compound with the formula (ch)(co). it is one of three isomeric cyclohexanediones. it is a colorless compound that occurs naturally. it is the substrate for cyclohexanedione hydrolase. the compound exists mainly as the enol tautomer.









































section::::synthesis, structure, and reactivity.









































1,3-cyclohexanedione is produced by semi-hydrogenation of resorcinol:









































1,3-cyclohexanedione exists in solution as the enol. it reacts under acid catalysis with alcohols to 3-alkoxyenones.









































its pk is 5.26. treatment of the sodium salt of the enolate with methyl iodide gives 2-methyl-1,3-cyclohexanedione, which despite the name, also exists predominantly as the enol.









































section::::derivatives.
1,3-cyclohexanedione