While Hahn was in North America, his attention was drawn to a mica-like mineral from Manitoba that contained rubidium. Some years before he had studied the radioactive decay of rubidium-87, and had estimated its half life at 2 x 10 years. It occurred to Hahn that by comparing the quantity of strontium in the mineral (which had once been rubidium) with that of the remaining rubidium, he could measure the age of the mineral, assuming that his original calculation of the half life was reasonably accurate. This would be a superior dating method to studying the decay of uranium, because some of the uranium turns into helium, which then escapes, resulting in rocks appearing to be younger than they really were. Jacob Papish helped Hahn obtain several kilograms of the mineral.
From 1,012 grams of the mineral, Strassmann and Ernst Walling extracted 253.4 milligrams of strontium carbonate, all of which was the strontium-87 isotope, indicating that it had all been produced from radioactive decay of rubidium-87. The age of the mineral had been estimated at 1,975 million years from uranium minerals in the same deposit, which implied that the half life of rubidium-87 was 2.3 x 10 years: quite close to Hahn's original calculation. Rubidium–strontium dating became a widely used technique for dating rocks in the 1950s, when mass spectrometry became common.