There are many types of coupled transition such as are observed in vibration–rotation spectra. The excited-state wave function is the product of two wave functions such as vibrational and rotational. The general principle is that the symmetry of the excited state is obtained as the direct product of the symmetries of the component wave functions. In rovibronic transitions, the excited states involve three wave functions.
The infrared spectrum of hydrogen chloride gas shows rotational fine structure superimposed on the vibrational spectrum. This is typical of the infrared spectra of heteronuclear diatomic molecules. It shows the so-called P and R branches. The Q branch, located at the vibration frequency, is absent. Symmetric top molecules display the Q branch. This follows from the application of selection rules.
Resonance Raman spectroscopy involves a kind of vibronic coupling. It results in much-increased intensity of fundamental and overtone transitions as the vibrations "steal" intensity from an allowed electronic transition. In spite of appearances, the selection rules are the same as in Raman spectroscopy.