Kaminsky's discovery of well-defined, high activity homogeneous catalysts led to many innovations in the design of novel cyclopentadienyl ligands. These innovations include ansa-metallocenes, C-symmetric fluorenyl-Cp ligands, constrained geometry catalysts, Some Kaminsky-inspired catalysts use of chiral metallocenes that have bridged cyclopentadienyl rings. These innovations made possible highly stereoselective (or stereoregular) polymerization of α-olefins, some of which have been commercialized.