The choice of infrared wavelengths used for the measurement largely defines the detector's suitability for a particular applications. Not only must the target gas (or gases) have a suitable absorption spectrum, the wavelengths must lie within a spectral window so the air in the beam path is itself transparent. These wavelength regions have been used:
* 3.4 μm region. All hydrocarbons and their derivatives absorb strongly, due to the C-H stretch mode of molecular vibration. It is commonly used in infrared point detectors where path lengths are necessarily short, and for open-path detectors requiring parts-per-million sensitivity. A disadvantage for many applications is that methane absorbs relatively weakly compared to heavier hydrocarbons, leading to large inconsistencies of calibration. For open-path detection of flammable concentrations the absorption for non-methane hydrocarbons is so strong that the measurement saturates, a significant gas cloud appearing black. This wavelength region is beyond the transmission range of borosilicate glass, so windows and lenses must be made of more expensive materials and tend to be small in aperture.
* 2.3 μm region. All hydrocarbons and their derivatives have absorption coefficients appropriate for open path detection at flammable concentrations. A useful advantage in practical applications is that the detector's response to many different gases and vapours is relatively uniform when expressed in terms of the lower flammable limit. Borosilicate glass retains useful transmission in this wavelength region, allowing large aperture optics to be produced at moderate cost.
* 1.6 μm region. A wide range of gases absorb in the near-infrared. Typically the absorption coefficients are relatively weak, but light molecules show narrow, individually resolved spectral lines rather than broad bands. This results in relatively large values of the gradient and curvature of the absorption with respect to wavelength, enabling semiconductor laser-based systems to distinguish gas molecules very specifically; for instance hydrogen sulfide, or methane to the exclusion of heavier hydrocarbons.