The beginning of the 1990s saw Brill accorded the Archaeological Institute of Americas Pomerance Award for scientific contributions to archaeology; however the decade mostly reflects Brills continuing dedication to Asian glasses and the study of the Silk Road (Archaeological Institute of America 2009). In Scientific Research in Early Chinese Glass, Brill reflected that in comparison to the knowledge of glassmaking in the West, ‘little is known about Chinese glass and about the role it played in the overall unfolding of glass history on a worldwide basis’ (1991, vii). One reason for this is that glass was never produced in the East in such great quantities as it was in the West but also that archaeological Chinese glasses are often prone to problems (Brill 1991). The difficulties of analysing Chinese glasses were reflected later in the publication where, following the chemical investigation of 71 samples, Brill found that identifying the ‘basic formulation’, or ‘any of the primary batch materials’ of the glasses was still almost impossible (Brill et al. 1991). Brill had greater success in differentiating between Chinese glass samples when using lead isotope analysis, a method that has proven effective in the first instance of identifying Chinese glass as the leads used here are different from those anywhere else in the world (Brill, Barnes et al. 1991). Brill found his Chinese samples to fall into two distinct groups, possessing on one hand the highest, and on the other the lowest, lead isotope ratios he had ever encountered (Brill, Barnes et al. 1991). As such, he was able to show that despite the striking similarity in the glasses’  chemical composition and appearance, the ores from which their leads were sourced must have been from very geologically-different mines (Brill, Barnes et al. 1991).
Brill conducted further investigations of ancient Asian glasses for the Nara Symposium on the Silk Roads maritime route in 1991, ‘to demonstrate [...] that chemical analyses can be useful for learning how glass was traded along the Desert, Steppe, and Maritime Routes of the Silk Road’ (1993a, 71), as well as providing a more technical discussion on glass and glassmaking in China for the Glass Art Societys Toledo Conference in 1993 (Brill 1993b). Further lead isotope analysis, this time on Chinese and central Asian pigments, was conducted with a larger team for the Getty's Conservation of Ancient Sites on the Silk Road, which saw Brill et al. launching studies that held incredible potential for understanding ‘chronological or stylistic differences among Buddhist cave paintings’, or ‘distinguish[ing] between original and repainted parts of individual works’ (1993, 371).