The photosynthesis process in chloroplasts begins when an electron of P680 of PSII attains a higher-energy level. This energy is used to reduce a chain of electron acceptors that have subsequently higher redox potentials. This chain of electron acceptors is known as an electron transport chain. When this chain reaches PSI, an electron is again excited, creating a high redox-potential. The electron transport chain of photosynthesis is often put in a diagram called the Z-scheme, because the redox diagram from P680 to P700 resembles the letter Z.
The final product of PSII is plastoquinol, a mobile electron carrier in the membrane. Plastoquinol transfers the electron from PSII to the proton pump, cytochrome b6f. The ultimate electron donor of PSII is water. Cytochrome bf transfers the electron chain to PSI through plastocyanin molecules. PSI can continue the electron transfer in two different ways. It can transfer the electrons either to plastoquinol again, creating a cyclic electron flow, or to an enzyme called FNR (Ferredoxin—NADP(+) reductase), creating a non-cyclic electron flow. PSI releases FNR into the stroma, where it reduces  to NADPH.
Activities of the electron transport chain, especially from cytochrome bf, lead to pumping of protons from the stroma to the lumen. The resulting transmembrane proton gradient is used to make ATP via ATP synthase.
The overall process of the photosynthetic electron transport chain in chloroplasts is: