The pressure–volume conjugate pair is concerned with the transfer of mechanical energy as the result of work.
* An isobaric process occurs at constant pressure. An example would be to have a movable piston in a cylinder, so that the pressure inside the cylinder is always at atmospheric pressure, although it is separated from the atmosphere. In other words, the system is dynamically connected, by a movable boundary, to a constant-pressure reservoir.
* An isochoric process is one in which the volume is held constant, with the result that the mechanical PV work done by the system will be zero. On the other hand, work can be done isochorically on the system, for example by a shaft that drives a rotary paddle located inside the system. It follows that, for the simple system of one deformation variable, any heat energy transferred to the system externally will be absorbed as internal energy. An isochoric process  is also known as an isometric process or an isovolumetric process. An example would be to place a closed tin can of material into a fire. To a first approximation, the can will not expand, and the only change will be that the contents gain internal energy, evidenced by increase in temperature and pressure. Mathematically, . The system is dynamically insulated, by a rigid boundary, from the environment.