The starting material for calcium looping is limestone, which is environmentally benign and widely available, accounting for over 10% (by volume) of all sedimentary rock. Limestone is already mined and cheaply obtainable. The mining process has no major known adverse environmental effects, beyond the unavoidable intrusiveness of any mining operation. However, as the following calculation shows, despite integration with cement industry, waste from Ca-looping can still be a problem.
From the environmental and health standpoint, Ca-looping compares favorably with amine scrubbing. Amine scrubbing is known to generate air pollutants, including amines and ammonia, which can react to form carcinogenic nitrosamines. Calcium looping, on the other hand, does not produce harmful pollutants. In addition, not only does it capture CO, but it also removes the pollutant SO from the flue gas.  This is both an advantage and disadvantage, as the air quality improves, but the captured SO has a detrimental effect on the cement that is generated from the calcium looping wastes.