Contaminant trace metals such as zinc, lead, and copper are found in stormwater runoff from impervious surfaces (e.g. roadways and sidewalks). Treatment systems such as rain gardens and stormwater planters utilize a bioretention layer to remove heavy metals in stormwater runoff. Dissolved forms of heavy metals may bind to sediment particles in the roadway that are then captured by the bioretention system. Additionally, heavy metals may adsorb to soil particles in the bioretention media as the runoff filters through. In laboratory experiments, bioretention cells removed 94%, 88%, 95%, and >95% of zinc, copper, lead, and cadmium, respectively from water with metal concentrations typical of stormwater runoff. While this is a great benefit for water quality improvement, bioretention systems have a finite capacity for heavy metal removal. This will ultimately control the lifetime of bioretention systems, especially in areas with high heavy metal loads.
Metal removal by bioretention cells in cold climates was similar or slightly lower than that in warmer environments. Plants are less active in colder seasons, suggesting that most of the heavy metals remain in the bioretention media rather than being taken up by plant roots. Therefore, removal and replacement of the bioretention layer will become necessary in areas with heavy metal pollutants in stormwater runoff to extend the life of the treatment system.