Addition of tricyclohexylphosphine to the carbene complex (PPh)(Cl)Ru=C(CHCOMe) results in olefin extrusion and yields an air stable anionic carbido complex. This species displaces a dimethyl sulfide ligand from PdCl(SMe) to give the μ-carbido bimetallic complex (PCy)ClRu≡C-PdCl(SMe). Spark towards a novel type of bonding was proposed following empirical observations wherein the carbido-palladium interaction could be readily disturbed. Reversible coordination ensues upon exposure of the bimetallic complex to carbon monoxide. Additionally, no coordination occurs if the anionic carbido complex contains bulky ligands such as HIMes. This indicates that the thermodynamic sink towards making the C-M bond is not very favorable, suggesting a weak interaction. Although not intuitive, characterization of this type of bonding can be inferred if C NMR shifts are observed to be far downfield, and C-M bond lengths are similar to those of complexes proven to contain carbon-based σ-donor ligands such as [(EtHIm)PdCl(μ-Cl)]