Again under Thomsons leadership, Rutherford worked on the conductive effects of X-rays on gases, which led to the discovery of the electron, the results first presented by Thomson in 1897. Hearing of Henri Becquerels experience with uranium, Rutherford started to explore its radioactivity, discovering two types that differed from X-rays in their penetrating power. Continuing his research in Canada, in 1899 he coined the terms "alpha ray" and "beta ray" to describe these two distinct types of radiation.
In 1898, Rutherford was accepted to the chair of Macdonald Professor of physics position at McGill University in Montreal, Canada, on Thomson's recommendation. From 1900 to 1903, he was joined at McGill by the young chemist Frederick Soddy (Nobel Prize in Chemistry, 1921) for whom he set the problem of identifying the noble gas emitted by the radioactive element thorium, a substance which was itself radioactive and would coat other substances. Once he had eliminated all the normal chemical reactions, Soddy suggested that it must be one of the inert gases, which they named thoron. This substance was later found to be Rn, an isotope of radon. They also found another substance they called Thorium X, later identified as Rn, and continued to find traces of helium. They also worked with samples of "Uranium X" (protactinium), from William Crookes, and radium, from Marie Curie. Rutherford further investigated thoron in conjunction with R.B. Owens and found that a sample of radioactive material of any size invariably took the same amount of time for half the sample to decay (in this case, 11 minutes), a phenomenon for which he coined the term "half-life". Rutherford and Soddy published their paper "Law of Radioactive Change" to account for all their experiments. Until then, atoms were assumed to be the indestructible basis of all matter; and although Curie had suggested that radioactivity was an atomic phenomenon, the idea of the atoms of radioactive substances breaking up was a radically new idea. Rutherford and Soddy demonstrated that radioactivity involved the spontaneous disintegration of atoms into other, as yet, unidentified matter.
In 1903, Rutherford considered a type of radiation, discovered (but not named) by French chemist Paul Villard in 1900, as an emission from radium, and realised that this observation must represent something different from his own alpha and beta rays, due to its very much greater penetrating power. Rutherford therefore gave this third type of radiation the name of gamma ray. All three of Rutherfords terms are in standard use today – other types of radioactive decay have since been discovered, but Rutherfords three types are among the most common. In 1904, Rutherford suggested that radioactivity provides a source of energy sufficient to explain the existence of the Sun for the many millions of years required for the slow biological evolution on Earth proposed by biologists such as Charles Darwin. The physicist Lord Kelvin had argued earlier for a much younger Earth, based on the insufficiency of known energy sources, but Rutherford pointed out, at a lecture attended by Kelvin, that radioactivity could solve this problem. Later that year, he was elected as a member to the American Philosophical Society, and in 1907 he returned to Britain to take the chair of physics at the Victoria University of Manchester.
In Manchester, Rutherford continued his work with alpha radiation. In conjunction with Hans Geiger, he developed zinc sulfide scintillation screens and ionisation chambers to count alpha particles. By dividing the total charge they produced by the number counted, Rutherford decided that the charge on the alpha particle was two. In late 1907, Ernest Rutherford and Thomas Royds allowed alphas to penetrate a very thin window into an evacuated tube. As they sparked the tube into discharge, the spectrum obtained from it changed, as the alphas accumulated in the tube. Eventually, the clear spectrum of helium gas appeared, proving that alphas were at least ionised helium atoms, and probably helium nuclei. Ernest Rutherford was awarded the 1908 Nobel Prize in Chemistry "for his investigations into the disintegration of the elements, and the chemistry of radioactive substances".