MOFs have been explored for electrolysis to enhance the rate and selectivity of reactions. Owing to their high surface area they can provide large number of interaction site for the reaction, conductivity of the material allows charge transfer during the electrocatalytic process. Two Cobalt based MOFs Co-BHT (Benzenehexathiol) and Co-HTTP (Hexathioltriphenylene) have been investigated for hydrogen evolution reaction (HER). In this report, overpotential values for Co-BHT and Co-HTTP are found to be 340 mV and 530 mV respectively at pH 1.3. The tafel slopes are between 149 and 189 mV dec at pH 4.2. Ultrathin sheets of Co-HAB MOF have been found to be catalytically active for oxygen evolution reaction (OER). Overpotential for this MOF was 310 mV at 10 mA cm in 1M KOH. Authors claimed that the ultrathin sheets were better than nanoparticles/thick sheets/bulk Co-HAB MOF because of favourable electrode kinetics. A 2-D conductive MOF has also been employed as an electrocatalyst for oxygen reduction reaction (ORR). Ni(HITP) MOF film on glassy carbon electrode in their study showed a potential of 820 mV at 50 μA in 0.1 M potassium hydroxide (KOH).