While the mechanical behavior of ceramics is often dominated by flaws, i.e. porosity, instead of grain size, grain-size strengthening is also observed in high-density ceramic specimens. Additionally, nanocrystalline ceramics have been shown to sinter more rapidly than bulk ceramics, leading to higher densities and improved mechanical properties, although extended exposure to the high pressures and elevated temperatures required to sinter the part to full density can result in coarsening of the nanostructure.
The large volume fraction of grain boundaries associated with nanocrystalline materials causes interesting behavior in ceramic systems, such as superplasticity in otherwise brittle ceramics. The large volume fraction of grain boundaries allows for a significant diffusional flow of atoms via Coble creep, analogous to the grain boundary sliding deformation mechanism in nanocrystalline metals. Because the diffusional creep rate scales as  and linearly with the grain boundary diffusivity, refining the grain size from 10 &mu;m to 10 nm can increase the diffusional creep rate by approximately 11 orders of magnitude. This superplasticity could prove invaluable for the processing of ceramic components, as the material may be converted back into a conventional, coarse-grained material via additional thermal treatment after forming.