Related to the title concept are the ideas of a van der Waals volume, V, and a van der Waals surface area, abbreviated variously as A, vdWSA, VSA, and WSA. 
A van der Waals surface area is an abstract conception of the surface area of atoms or molecules from a mathematical estimation, either computing it from first principles or by integrating over a corresponding van der Waals volume. 
In simplest case, for a spherical monatomic gas, it is simply the computed surface area of a sphere of radius equal to the van der Waals radius of the gaseous atom:
The van der Waals volume, a type of atomic or molecular volume, is a property directly related to the van der Waals radius, and is defined as the volume occupied by an individual atom, or in a combined sense, by all atoms of a molecule. 
It may be calculated for atoms if the van der Waals radius is known, and for molecules if its atoms radii and the inter-atomic distances and angles are known. 
As above, in simplest case, for a spherical monatomic gas, V is simply the computed volume of a sphere of radius equal to the van der Waals radius of the gaseous atom:
For a molecule, V is the volume enclosed by the van der Waals surface; hence, computation of  V presumes ability to describe and compute a van der Waals surface. van der Waals volumes of molecules are always smaller than the sum of the van der Waals volumes of their constituent atoms, due to the fact that the interatomic distances resulting from chemical bond are less than the sum of the atomic van der Waals radii. 
In this sense, a van der Waals surface of a homonuclear diatomic molecule can be viewed as an pictorial overlap of the two spherical van der Waals surfaces of the individual atoms, likewise for larger molecules like methane, ammonia, etc. (see images).
van der Waals radii and volumes may be determined from the mechanical properties of gases (the original method, determining the van der Waals constant), from the critical point (e.g., of a fluid), from crystallographic measurements of the spacing between pairs of unbonded atoms in crystals, or from measurements of electrical or optical properties (i.e., polarizability or molar refractivity). 
In all cases, measurements are made on macroscopic samples and results are expressed as molar quantities. van der Waals volumes of a single atom or molecules are arrived at by dividing the macroscopically determined volumes by the Avogadro constant. 
The various methods give radius values which are similar, but not identical—generally within 1–2 Å (100–200 pm). 
Useful tabulated values of van der Waals radii are obtained by taking a weighted mean of a number of different experimental values, and, for this reason, different tables will be seen to present different values for the van der Waals radius of the same atom. 
As well, it has been argued that the van der Waals radius is not a fixed property of an atom in all circumstances, rather, that it will vary with the chemical environment of the atom.