Silicon isotope biogeochemistry is the study of environmental processes using the relative abundance of Si isotopes. As the relative abundance of Si stable isotopes varies among different natural materials, the differences in abundance can be used to trace the source of Si, and to study biological, geological, and chemical processes. The study of stable isotope biogeochemistry of Si aims to quantify the different Si fluxes in the global biogeochemical silicon cycle, to understand the role of biogenic silica within the global Si cycle, and to investigate the applications and limitations of the sedimentary Si record as an environmental and palaeoceanographic proxy.