Cast iron farm tools and weapons were widespread in China by the 5th century BC, employing workforces of over 200 men in iron smelters from the 3rd century onward. The earliest known blast furnaces are attributed to the Han dynasty in the 1st century AD. These early furnaces had clay walls and used phosphorus-containing minerals as a flux. Chinese blast furnaces ranged from around two to ten meters in height, depending on the region. The largest ones were found in modern Sichuan and Guangdong, while the 'dwarf" blast furnaces were found in Dabieshan. In construction, they are both around the same level of technological sophistication 
There is no evidence of the bloomery in China after the appearance of the blast furnace and cast iron. In China, blast furnaces produced cast iron, which was then either converted into finished implements in a cupola furnace, or turned into wrought iron in a fining hearth. If iron ores are heated with carbon to 1420–1470 K, a molten liquid is formed, an alloy of about 96.5% iron and 3.5% carbon. This product is strong, can be cast into intricate shapes, but is too brittle to be worked, unless the product is decarburized to remove most of the carbon. The vast majority of Chinese iron manufacture, from the late Zhou dynasty onward, was of cast iron. However forged swords began to be made in the Warring-States-period: "Earliest iron and steel Jian also appear, made by the earliest and most basic forging and folding techniques." Iron would become, by around 300 BCE, the preferred metal for tools and weapons in China.
The primary advantage of the early blast furnace was in large scale production and making iron implements more readily available to peasants. Cast iron is more brittle than wrought iron or steel, which required additional fining and then cementation or co-fusion to produce, but for menial activities such as farming it sufficed. By using the blast furnace, it was possible to produce larger quantities of tools such as ploughshares more efficiently than the bloomery. In areas where quality was important, such as warfare, wrought iron and steel were preferred. Nearly all Han period weapons are made of wrought iron or steel, with the exception of axe-heads, of which many are made of cast iron.
The effectiveness of the Chinese human and horse powered blast furnaces was enhanced during this period by the engineer Du Shi (c. AD 31), who applied the power of waterwheels to piston-bellows in forging cast iron. Early water-driven reciprocators for operating blast furnaces were built according to the structure of horse powered reciprocators that already existed. That is, the circular motion of the wheel, be it horse driven or water driven, was transferred by the combination of a belt drive, a crank-and-connecting-rod, other connecting rods, and various shafts, into the reciprocal motion necessary to operate a push bellow.
Donald Wagner suggests that early blast furnace and cast iron production evolved from furnaces used to melt bronze. Certainly, though, iron was essential to military success by the time the State of Qin had unified China (221 BC). Usage of the blast and cupola furnace remained widespread during the Song and Tang dynasties. By the 11th century, the Song dynasty Chinese iron industry made a switch of resources from charcoal to coke in casting iron and steel, sparing thousands of acres of woodland from felling. This may have happened as early as the 4th century AD.
Blast furnaces were also later used to produce gunpowder weapons such as cast iron bomb shells and cast iron cannons during the Song dynasty.