Mixtures of different solvents can have interesting features like anomalous conductivity (electrolytic) of particular lyonium ions and lyate ions generated by molecular autoionization of protic and aprotic solvents due to Grotthuss mechanism of ion hopping depending on the mixing ratios. Examples may include hydronium and hydroxide ions in water and water alcohol mixtures, alkoxonium and alkoxide ions in the same mixtures, ammonium and amide ions in liquid and supercritical ammonia, alkylammonium and alkylamide ions in ammines mixtures, etc....