The chromium atom is surrounded by six nitrogen atoms in an octahedral geometry. The NH ligands are mutually trans and the Cr–NCS groups are linear. The salt crystallizes with one molecule of water.
It was first reported in 1863. NH[Cr(NCS)(NH)] is prepared by treatment of molten NHSCN (melting point around 145–150 °C) with (NH)CrO.
This salt was once widely used to precipitate primary and secondary amines as their ammonium salts. Included in the amines that effectively form crystalline precipitates are those derived from the amino acids, including proline and hydroxyproline. It also reacts with Hg compounds, giving a red color or a red precipitate.