Photoluminescence processes can be classified by various parameters such as the energy of the exciting photon with respect to the emission.
Resonant excitation describes a situation in which photons of a particular wavelength are absorbed and equivalent photons are very rapidly re-emitted. This is often referred to as resonance fluorescence. For materials in solution or in the gas phase, this process involves electrons but no significant internal energy transitions involving molecular features of the chemical substance between absorption and emission. In crystalline inorganic semiconductors where an electronic band structure is formed, secondary emission can be more complicated as events may contain both coherent contributions such as resonant Rayleigh scattering where a fixed phase relation with the driving light field is maintained (i.e. energetically elastic processes where no losses are involved), and incoherent contributions (or inelastic modes where some energy channels into an auxiliary loss mode),
The latter originate, e.g., from the radiative recombination of excitons, Coulomb-bound electron-hole pair states in solids. Resonance fluorescence may also show significant quantum optical correlations.
More processes may occur when a substance undergoes internal energy transitions before re-emitting the energy from the absorption event. Electrons change energy states by either resonantly gaining energy from absorption of a photon or losing energy by emitting photons. In chemistry-related disciplines, one often distinguishes  between  fluorescence and phosphorescence. The former is  typically a fast process, yet some amount of the original energy is dissipated so that re-emitted light photons will have lower energy than did the absorbed excitation photons. The re-emitted photon in this case is said to be red shifted, referring to the reduced energy it carries following this loss (as the Jablonski diagram shows). For phosphorescence, electrons which absorbed photons, undergo intersystem crossing where they enter into a state with altered spin multiplicity (see term symbol), usually a triplet state.  Once the excited electron is transferred into this triplet state, electron transition (relaxation) back to the lower singlet state energies is quantum mechanically forbidden, meaning that it happens much more slowly than other transitions.  The result is a slow process of radiative transition back to the singlet state, sometimes lasting minutes or hours. This is the basis for "glow in the dark" substances.
Photoluminescence is an important technique for measuring the purity and crystalline quality of semiconductors such as GaN and InP and for quantification of the amount of disorder present in a system.
Time-resolved photoluminescence (TRPL) is a method where the sample is excited with a light pulse and then the decay in photoluminescence with respect to time is measured.  This technique is useful for measuring the minority carrier lifetime of III-V semiconductors like gallium arsenide (GaAs).