Calcareous soils are relatively alkaline, in other words they have a high pH. This is because of the very weak acidity of carbonic acid. Note that this is not the only reason for a high soil pH. They are characterized by the presence of calcium carbonate in the parent material and may have a calcic horizon, a layer of secondary accumulation of carbonates (usually calcium or Mg) in excess of 15% calcium carbonate equivalent and at least 5% more carbonate than an underlying layer.