In imaging spectroscopy (also hyperspectral imaging or spectral imaging) each pixel of an image acquires many bands of light intensity data from the spectrum, instead of just the three bands of the RGB color model. More precisely, it is the simultaneous acquisition of spatially coregistered images in many spectrally contiguous bands.
Some spectral images contain only a few image planes of a spectral data cube, while others are better thought of as full spectra at every location in the image.  For example, solar physicists use the spectroheliograph to make images of the Sun built up by scanning the slit of a spectrograph, to study the behavior of surface features on the Sun; such a spectroheliogram may have a spectral resolution of over 100,000 () and be used to measure local motion (via the Doppler shift) and even the magnetic field (via the Zeeman splitting or Hanle effect) at each location in the image plane.  The multispectral images collected by the Opportunity rover, in contrast, have only four wavelength bands and hence are only a little more than 3-color images.
One application is spectral geophysical imaging, which allows quantitative and qualitative characterization of the surface and of the atmosphere, using radiometric measurements.  These measurements can then be used for unambiguous direct and indirect identification of surface materials and atmospheric trace gases, the measurement of their relative concentrations, subsequently the assignment of the proportional contribution of mixed pixel signals (e.g., the spectral unmixing problem), the derivation of their spatial distribution (mapping problem), and finally their study over time (multi-temporal analysis). The Moon Mineralogy Mapper on Chandrayaan-1 was a geophysical imaging spectrometer.