Polarizational bremsstrahlung (sometimes referred to as "atomic bremsstrahlung") is the radiation emitted by the target's atomic electrons as the target atom is polarized by the Coulomb field of the incident charged particle. Polarizational bremsstrahlung contributions to the total bremsstrahlung spectrum have been observed in experiments involving relatively massive incident particles, resonance processes, and free atoms. However, there is still some debate as to whether or not there are significant polarizational bremsstrahlung contributions in experiments involving fast electrons incident on solid targets.
It is worth noting that the term "polarizational" is not meant to imply that the emitted bremsstrahlung is polarized. Also, the angular distribution of polarizational bremsstrahlung is theoretically quite different than ordinary bremsstrahlung.