Still another type of photochemical reaction is the di--methane rearrangement. Two further early examples were the rearrangement of 1,1,5,5-tetraphenyl-3,3-dimethyl-1,4-pentadiene (the "Mariano" molecule) and the rearrangement of barrelene to semibullvalene. We note that, in contrast to the cyclohexadienone reactions which used n-* excited states, the di--methane rearrangements utilize -* excited states.