The earliest evidence for iron-making is a small number of iron fragments with the appropriate amounts of carbon admixture found in the Proto-Hittite layers at Kaman-Kalehöyük and dated to 2200–2000 BCE. Souckova-Siegolová (2001) shows that iron implements were made in Central Anatolia in very limited quantities around 1800 BCE and were in general use by elites, though not by commoners, during the New Hittite Empire (~1400–1200 BCE).
Archaeologists have found indications of iron working in Ancient Egypt, somewhere between the Third Intermediate Period and 23rd Dynasty (ca. 1100–750 BCE). Significantly though, they have found no evidence of iron ore smelting in any (pre-modern) period. In addition, very early instances of carbon steel were in production around 2000 years ago (around the first-century CE.) in northwest Tanzania, based on complex preheating principles. These discoveries are significant for the history of metallurgy.
Most early processes in Europe and Africa involved smelting iron ore in a bloomery, where the temperature is kept low enough so that the iron does not melt. This produces a spongy mass of iron called a bloom, which then must be consolidated with a hammer to produce wrought iron. The earliest evidence to date for the bloomery smelting of iron is found at Tell Hammeh, Jordan ([http://www.ironsmelting.net/www/smelting/]), and dates to 930 BCE (C14 dating).