The Two-dimensional (2-D) polymers formed by topochemical polymerization are popular topics in material chemistry. By synthesizing and polymerizing monomers with functionality greater than 2, the 2-D networks instead of linear polymers can be obtained. [4+4] and [4+2] involving anthracene units are popular choices for 2D-polymer synthesis. 2-D covalent networks with high crystallinity can be produced in this way in high conversion. Recently, schluter et al. synthesized a 2D polymer via 2+2 topochemical cycloaddition reaction.[https://pubs.acs.org/doi/10.1021/jacs.6b11857]