The atmophile elements are H, C, N and the noble gases.
Atmophile elements (also called "volatile elements") are defined as those that remain mostly on or above the surface because they are, or occur in, liquids and/or gases at temperatures and pressures found on the surface. The noble gases do not form stable compounds and occur as monatomic gases, while nitrogen, although it does not have a stable configuration for its individual atoms, forms a diatomic molecule so strong that all oxides of nitrogen are thermodynamically unstable with respect to nitrogen and oxygen. Consequently, with the development of free oxygen through photosynthesis, ammonia was oxidised to molecular nitrogen which has come to form four-fifths of the Earths atmosphere. Carbon is also classed as an atmophile because it forms very strong multiple bonds with oxygen in carbon monoxide (slowly oxidised in the atmosphere) and carbon dioxide. The latter is the fourth-largest constituent of the Earths atmosphere, while carbon monoxide occurs naturally in volcanoes and has a residence time in the atmosphere of a few months.
Hydrogen, which occurs in the compound water, is also classed as an atmophile. Water is classified as a volatile, because most of it is liquid or gas, even though it does exist as a solid compound on the surface. Water can also be incorporated into other minerals as water of crystallization (e.g. gypsum) or as hydroxyl groups (e.g. talc), giving hydrogen some lithophile character.
Because all atmophile elements are either gases or form volatile hydrides, atmophile elements are strongly depleted on earth as a whole relative to their solar abundances owing to losses from the atmosphere during the formation of the Earth. The heavier noble gases (krypton, xenon) are the rarest stable elements on Earth.