Paper
Much of the early paper made from wood pulp contained significant amounts of alum, a variety of aluminium sulfate salts that is significantly acidic. Alum was added to paper to assist in sizing, making it somewhat water resistant so that inks did not "run" or spread uncontrollably. Early papermakers did not realize that the alum they added liberally to cure almost every problem encountered in making their product would eventually be detrimental. The cellulose fibres that make up paper are hydrolyzed by acid, and the presence of alum would eventually degrade the fibres until the paper disintegrated in a process that has come to be known as "slow fire". Documents written on rag paper were significantly more stable. The use of non-acidic additives to make paper is becoming more prevalent, and the stability of these papers is less of an issue.
What acidic salts were commonly found in the early types of paper produced?
Alum
Alum was added to paper to assist in sizing, making it somewhat water resistant so that inks did not "run" or spread uncontrollably.
paper