Below is the list of tables from the database along with their columns and datatype. Need to generate an accurate SQL query for the question.
Only use the columns present in the respective table. Only use the columns which are required to generate the SQL query. Only use table joins if required and not otherwise.

### Tables ###
TABLE: CREATE TABLE table_name_83 ( round_of_16 VARCHAR, ranking_round_rank VARCHAR )

### Question ###
What is the Round of 16 value for the nation with a value of 5 for Ranking Round Rank?

### Accurate SQL ###

SELECT round_of_16 FROM table_name_83 WHERE ranking_round_rank = 5